EGCSA Handbook 2012

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CJNO Switchboards and frequency drives, gas monitoring - probe, dryer, monitor



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Delivery and commissioning timeline TASKS / PHASES DELIVERABLES Concept study Layout - conceptual Equipment specification - pr Installation requirements - ge Budget Contract 1 Letter of intent Detailed study Layout verification - ship ins Installation specification Equipment specification - B Yard quotes Equipment quotes Contract 2 Purchase and installation Preplanning Equipment ordering and log Plan drafting and approval Installation scope - prefabric Installation Equipment ready installed an Final documentation Commissioning Successful tests during voyag SUM TIMECOCn

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REFERENCES 1 . Seawater scrubbing - reduction of SOx emissions 16. Hamworthy Krystallon - Seawater Scrubbing, from ship exhausts. Karle and Turner. The Alliance For Global Sustainability Gothenburg 2007. Introducing the technology to owners, operators and shipyards. 2. SOx scrubbing of marine exhaust gases. Henriksson. http://www.hamworthy.com/PageFiles/ 1 774 Wartsila Technical Journal, 02 - 2007. Hamworthy Krystallon Scrubber Concept.pdf 3. Marine Engineering Practice Series, Volume 3 Part 20 17. http://www.lenntech.com/library/adsorption - Exhaust Emissions from Combustion Machinery. Wright. adsorption.htm Publisher: IMarEST, 2000. ISBN 1-902536- 1 7-7. 18. Revised MARPOL Annex VI, Regulations for the 4. Effects on Seawater Scrubbing. Final Report. Behrends, Hufnagl, Liebezeit. BP Marine/Research Centre prevention of air pollution from ships and NOx Terramare, 2005. Technical Code 2008. International Maritime Organization, 2009. 5. MEPC 59/6/5: Proposal to Designate an Emission Control Area for Nitrogen Oxides, Sulphur Oxides Print edition ISBN 9789280142433. and Particulate Matter. United States and Canada. 19. MEPC 1 26(53): Procedure for approval of ballast water International Maritime Organization, 2009. management systems that make use of active substances 6. MEPC INF/. 1 3: Proposal to Designate an Emission (G9). International Maritime Organization, 2005. Control Area for Nitrogen Oxides, Sulphur Oxides 20. Alfa Laval PureSOx Exhaust Gas Cleaning Brochure - and Particulate Matter. United States and Canada. Multiple inlet systems - International Maritime Organization, 2009. http:/ /www.aalborg-industries.com/scrubber references_media.php 7. Proposal to Designate an Emission Control Area for Nitrogen Oxides, Sulphur Oxides and Particulate 21. DuPont BELCO® Marine Scrubbing Systems Brochure Matter. Technical Support Document. U.S. EPA. - http://www2.dupont.com/sustainable-solutions/ en-us/dss/article/belco-marine-gas-scrubbing.html 8. A Theoretical Environmental Impact Assessment of the Use of a Seawater Scrubber to Reduce SOx and 22. The Flakt-Hydro Process - flue gas desulphurisation by NOx Emissions from Ships. Behrends and Liebezeit. use of seawater. Process principles & recent power plant Research Centre Terramare, 2003. applications in Indonesia and China. A. Ellestad et al 9. X-ray Absorption Fine Structure (XAFS) Spectroscopic ABB Environmental/ABB Power 1998. Characterization of Emissions from Combustion of Fossil Fuels. Huggins and Huffman. Publisher: 23. List of installations - Alstom Seawater FGD The Society of Materials Engineering for Resources of Japan, 2002. http://hdl.handle.net/ ! 0295/738 http:/ / www. no.alstom .com / home / business_activities ecs/trklklhygft/so2/_files/file_44598_541 1 2.pdf 10. MEPC 60/22: Report of the Marine Environment 24. Longannet Power Station EMAS Statement 2005-06. Protection Committee on its Sixtieth Session. International Maritime Organization, 12 April 2010. http: / / www.scotash.com / pdfs/emas0506.pdf 11. http://www.seafriends.org.nz/oceano/seawater.htm 25. Longannet Power Station EMAS Statement 2008. 1 2. Sea Water Scrubbing - Does it contribute to increased http:/ / www.scottishpower.com /uploads global CO2 emissions? Hamworthy Krystallon, 2007. http://www.hamworthy.com/PageFiles/ 1 774 Iongannetemas2008 .pdf response-to-CO2-emissions-from-sea-water-scrubbing 14nov2007.pdf 26. http://www.scottishpower.com/Casestudies_828.asp 13. MEPC 58/23 Annex 16: Report of the Marine 27. http://periodic.lanl.gov/ 1 5.shtml Environment Protection Committee on its fifty-eighth 28. Air Pollution Control Technology Handbook. Karl B. session. International Maritime Organization, 2008. Schnelle and Charles A. Brown. Publisher CRC Press 2002. Print ISBN: 978-0-8493-9588-8.eBook ISBN: 14. Corbett, J.J. and P. Fischbeck, Emissions from ships. 978- 1 -4200-3643-5. Science, 1997. 278 (5339): 823-824. 29. Sulphur Scrubbers. Henriksson, Wartsila Finland Oy, Green Solutions Seminar 26th September 2007. 15. http://www.waterencyclopedia.com/Mi-Oc/ 30. Application Note to the Field, Common Fluid - Pumping Ocean-Chemica1-Processes.htmI Sodium Hydroxide with Liquiflo Gear Pumps. January 1 8, 2001; Revised Aug. 2008. 31. http://www.eng-tips.com/faqs.cfm?fid=1096136

32. OxyChem Caustic Soda Handbook. Occidental 46. Diesel and Gas Turbine Worldwide, December 2009. Chemical Corporation 2009. http: / / www.dieselpub.com /33. http://toxics.usgs.gov/definitions/alkalinity.html 47. Marine Emission Control Technologies by Wartsila34. Chemical Oceanography 2nd edition. Frank Millero. Marine. Goran Hellen, Wartsila Finland Oy, Green Publisher CRC Press 1996. ISBN 0-8493-2280-4. Solutions Seminar 26th September 2007.35. http://www.engineeringtoolbox.com/ph-d_483.html 48. AQMD Method 100.1: Instrumental Analyser Procedures for Continuous Gaseous Emission Sampling.36. Lee, K.; L. T. Tong, F. J. Millero, C. L. Sabine, A. South Coast Air Quality Management District, 1989. http: / /www.aqmd.gov/tao/ methods/stm/stm- 100- 1 .pdf G. Dickson, C. Goyet, G.-H. Park, R. Wanninkhof, R. EPA Method 7: Determination of Nitrogen Oxide A. Feely, and R. M. Key. 2006. Global relationships Emissions from Stationary Sources. U.S. EPA. of total alkalinity with salinity and temperature in surface http: / www.epa .gov/ ttn / emc / promgate/ m-07. pdf waters of the world's oceans. Geophys Research Letters 49. Sulfur Dioxide, S02 Air Quality 1980 - 2010. U.S. 33, LI 9605, doi:10.1029/2006GL027207. EPA. http://www.epa.gov/air/airtrends/sulfur.html37. Final Regulatory Support Document: Control of Emissions 50. Measuring Acid Rain. U.S. EPA. http://www.epa.gov from New Marine Compression-Ignition Engines at or acidrain/measure/index.html Above 30 Liters per Cylinder. U.S. EPA 2003. 51. Acid Rain - Effects felt through the food chain. National38. The mechanics of fuel sulphur influence on exhaust Geographic, http://environment.nationalgeographic emissions from diesel engines. Kozak and Merkisz. com/environment/global-warming/acid-rain-overview/ Institute of Internal Combustion Engines and Transport, Poznan University of Technology 2005. 52. Acid Rain in the Alpine Zone - Acidity on High. Appalachian Mountain Club, http://www.outdoors39. Flue Gas Desulphurisation Technology Evaluation, Dry org /conservation /airwater /airwater-acid-rain .cfm Lime versus Wet Limestone FGD. Prepared for the National Lime Association by Sargent and Lundy, March 53. Proposal for a Directive of the European Parliament and of the Council amending Directive 1 999/32/EC as 2007. regards the sulphur content of marine fuels.40. BLG 12/6/23: Review of MARPOL Annex VI and 54. EU policy on ship emissions, http://ec.europa.eu the NOx Technical Code. United States. International environment/air/transport/ships.htm http://ec.europa eu/environment/air/transport/pdf/sulphur_standard Maritime Organization, 2007. shipping.pdf41. ISO 8178 (part 1 ): Reciprocating internal combustion 55. Demonstration and feasibility of BOC LoTOx engines - Exhaust emission measurement. International system for NOx control on flue gas from coal-fired Organization for Standardization, 2006. combustor. 2000 Conference on Selective Catalytic and Non Catalytic Reduction for NOx Control. http: / / www. iso .org/ http: / / www.netl.doe.gov/publicationsproceedings/OO/ scrOO/ANDERSON.PDF42. DIN 51402: Testing of flue gases of oil burning systems; visual and photometric determination of the 56. Using Non-Thermal Plasma to Control Air Pollutants. smoke number. Deutsches Institut fur Normung e.V., 1986. http://din.de / http://www.beuth.de/ U.S. EPA-456/R-05-001, February 2005. http:/ www.epa.gov/ttn/catc/dirl /fnonthrm.pdf43. EPA Method 5/AQMD Method 5.2: Determination 57. Bunkerworld- Couple Systems' dry scrubber of Particulate Matter emissions from stationary sources. showing 'stunning results'. 2nd April 2010. U.S. EPA/South Coast Air Quality Management District, http: / / www. bunkerworld .com / _ / 1989. http://www.epa.gov/ttn/emc promgate/m-05.pdf / http://www.aqmd.gov/tao 58. MEPC 61/7/3: Proposal to Designate an Emission methods/stm/stm-005-2.pdf Control Area for the Commonwealth of Puerto Rico and44. IEA Clean Coal Centre, Databases, Clean Coal the United States Virgin Islands for Nitrogen Oxides, Technologies, Particulate Emissions Control Sulphur Oxides and Particulate Matter. United States. International Maritime Organization, June 2010. Technologies, Electrostatic precipitators (ESP), http:/ www.iea-coal .org . uk /site / 2010/ database-section 59. Proposal to Designate an Emission Control Area ccts/electrostatic-precipitators-esp? for Nitrogen Oxides, Sulfur Oxides and Particulate Matter Technical Support Document & Table of Contents45. ISO 9096: Stationary source emissions - Manual ( 2 documents). U.S. EPA, August 2010. determination of mass concentration of particulate matter. International Organization for Standardization, 2003. http://www.iso.org/ 137

60. MEPC 61 /INF.9: Designation of an Emission 72. Two-stroke engine emission reduction technology: Control Area for Nitrogen Oxides, Sulphur Oxides and state-of-the-art. Pedersen, Andreasen, Mayer, MAN Particulate Matter. United States. International Maritime Diesel & Turbo SE, Denmark. Paper No.85 CIMAC Organization, June 2010. Congress 2010, Bergen. 61. Electronic Code of Federal Regulations e-CFR Title 73. Economical aspects of EGR systems. MAN Diesel & Turbo SE, Denmark, http://www.mandieselturbo.com/ 40 Protection of Environment Part 94 - Control of Emissions from Marine Compression-Ignition Engines 74. Developments in Engine Technology for Green Ship Designs. Clausen MAN Diesel & Turbo. 15-16 October - http://www.gpoaccess.gov/ecfr/index.htmI 2010. 62. Electronic Code of Federal Regulations e-CFR Title 75. First Tier-Ill EGR engine order landed. 40 Protection of Environment Part 1042 Control http://www.mandieselturbo.com/ 1016608/Press of Emissions from New and In-Use Marine Press-Releases/Trade-Press-Releases/Marine-Power Compression Ignition Engines and Vessels - Low-Speed/First-Tier-lll-EGR-Engine-Order-Landed.html http: / / www.gpoaccess.gov/ecfr /index.htmI 76. World's First SCR NOx Removal System Installed on 63. Electronic Code of Federal Regulations e-CFR Title 40 Coal Bulker Built by Oshima Shipbuilding - Aiming to Meet the IMO's Tier III NOx Emission Controls. NYK Protection of Environment Part 1043 Control of NOx, SOx and PM Emissions from Marine Engines and Line et al. June 2011. Vessels subject to the AAARPOL Protocol - 77. Wartsila NOx Reducer -SCR System. Wartsila Finland http: / / www.gpoaccess.gov/ecfr /index.htmI Oy. August 201 1 64. Notice of public hearing to consider amendments 78. Bunkerworld - Contract signed for largest ever' marine to the regulations for fuel sulfur and other operational scrubbing system. 1 3th February 2012. http://www requirements for Ocean-Going Vessels within California bunkerworld.com/ waters and 24 nautical miles of the California baseline, 79. Enforcement of AAARPOL Annex VI Memorandum of 23 June 201 1 . http://www.arb.ca.gov regact/201 1 / ogvl 1 /ogvl 1 .htm Understanding (MOU) Information Sheet. U.S. EPA. 65. U.S. Department of Transportation Exhaust Gas June 27, 2011. http://www.epa.gov/oecaerth/civil caa/annexvi-mou.html Cleaning Systems Selection Guide, prepared for Ship Operations Cooperative Program (SOCP), Ellicott City, 80. Interim Guidance on the Non-Availability of Compliant MD, File No. 10047.01, 22 February 2011, Rev. A. Fuel Oil for the North American Emission Control Area. 66. Atmospheric Chemistry and Physics. Seinfeld and U.S. EPA. June 26, 2012. Pandis. Publisher Wiley-Blackwell; 2nd Edition (8 Sep 81. Public Test Report, Exhaust Gas Scrubber Installed on 2006). ISBN-13: 978-0471720188. MT Suula. Wartsila Finland Oy. 20 June 2010. 67. Anthropogenic sulfur dioxide emissions: 82. Maersk Line tests new exhaust gas cleaning system. 19 September 2011. http://www.maerskline.com 1 850-2005. Smith, van Aardenne, Klimont, Andres, link/?page=news&path=/news/news201 10919 Volke, Delgado Arias. Atmospheric Chemistry and Physics, 9 February 2011. The \"BELCO®\" Marine Scrubber in fabrication for installation on the Maersk-Taurus. 68. Bunkerworld - California regulator confirms http://www.pmsaship.com/pdfs/Garrett Billemeyer - Belco, Panel 4.pdf amendments to OGV fuel rules. 2nd September 2011. 83. Port of Los Angeles and Cal State Long Beach http: / / bunkerworld .com / team up to test technology to reduce ship emissions. 69. Johnson Matthey Catalysts Temperature Ranges. Sept. 28, 2011. http: / / www. powerplantcatalysts.com /en/ scr-technology/scr-temperature-ranges/ http://www.portoflosangeles.org/newsroom/201 1 releases/news_09281 1 _CSULB_Scrubber.asp 70. California Air Resources Board - Ocean-Going Vessels fuel rule. Title 1 3 California Code of Bunkerworld - Exhaust gas scrubbers show 'great Regulations (CCR), section 2299.2. Fuel Sulfur long-term promise'. 29th September 2011. http:/ and Other Operational Requirements for Ocean-going Vessels within California Waters and 24 Nautical Miles www.bunkerworld.com/ of the California baseline, http://www.arb.ca.gov 84. Wartsila FHamworthy to install world's largest ports/marinevess/ogv.htm multi-stream scrubber. 23.04.2012. 71. International Association for Catalytic Control of Ship http:/ / www. hamworthy. com /en /News-and-Events Emissions to Air. Maritime Grade Urea Solution based News/Wartsila-Hamworthy-to-install-worlds-largest- on work by the European Chemical Industry Council multi-tream-scrubber-/ (CEFIC). http://www.iaccsea.com/138

85. The Chemical Aspect of NOx Scrubbing. Robert 97. Comparison of PAH in the soot made by propane, Chironna and Boris Altshuler, http://www.croll.com air_library/technicalarticles_articlel .php gasoline and diesel using the CAST technique, 8th ETH Conference on Combustion Generated Particles Zurich,86. Triology Laboratory Fluorometer - Nitrate Analysis. 16th - 1 8th August 2004. Dr. Lianpeng Jing, Jing Ltd Turner Designs, http://www.turnerdesigns.com/t2 98. Cleaner shipping fuels to save lives. European Parliament doc/appnotes/S-0091.pdf Plenary Session, Environment - 1 1 -09-2012 - 1 2:55 http:/ / www.europarl .europa . eu / news / en / pressroom87. Eyring, V.; Kohler, H.W.; van Aardenne, J.; Lauer, A. content/201 20907IPR50818/html/Cleaner-shipping Emissions from international shipping: 1 . The last 50 fuels-to-save-lives years. J. Geophys. Res., D: Atmos. 2005, 1 10 (D17), 99. BLG 15/WP.8. Black carbon - background and draft D 17305 . outline of possible regulatory approaches. International Maritime Organization, February 2011.88. Endresen, O.; Soergaard, E.; Sundet, J. K.; 100. MEPC 59/INF. 15. Study pertaining to Ship Emissions Dalsoeren, S. B.; Isaksen, I. S. A.; Berglen, T. F.; Gravir, G., Emission from international sea transportation Impact on Climate Change and Air Quality - Particulate and environmental impact. J. Geophys. Res., D: Atmos. emissions from commercial shipping: chemical, physical 2003, 108, (D17.) and optical properties. Journal of Geophysical Research89. Annex to: The Communication on Thematic Strategy on Air Pollution and The Directive on \"Ambient Air Quality Vol. 1 14, Lack et al. International Maritime and Cleaner Air for Europe\", Impact Assessment. Organization, April 2009. Commission of the European Communities. Brussels, 21 101. BLG 16/ 16. Final report to the Maritime Safety 9.2005 http://ec.europa.eu/environment/archives cafe/pdf/ia_report_en050921_final.pdf Committee and the Marine Environment Protection Committee. International Maritime Organization,90. Wiederkehr, P.,Yoon, S-J., 1998. Air Quality Indicators, February 2012 in: Fenger, J.,Hertel, O., Palmgren, F. (Eds.), Urban Air Pollution, European Aspects. Kluwer Academic Publisher Dordecht, p. 403-41891. Firket M., 1931. The cause of the symptoms found in the Meuse Valley during the fog of December 1930. Bulletin Academy Royal Medical Belqium 1931; 11683-74192. Ministry of Health. Mortality and morbidity of the London fog of December 1952. Reports on Public Health and Medical Subjects, No. 95 London: HMSO, 1954.93. Wilkins ET. Air pollution and the London fog of December 1952. Journal of the Royal Sanitary Institute1954;74: 1-21.94. Air Pollution. Fenger, J., Tjell, C.J., Royal Society of Chemistry ( 1 3 Mar 2009). ISBN-10: 1 847558658 ISBN-13: 978-184755865795. Global Climate Change Linkages: Acid Rain, Air Quality, and Stratospheric Ozone. White, J.C., Wagner, W.R., Beal, C.N., Springer (31 Dec 1989). ISBN-10: 0444015159 ISBN- 1 3: 978-044401515096. Testimony for \"Clearing the Smoke: Black Carbon Pollution\", House Committee on Energy Independence and Global Warming. United States House of Representatives, The Honorable Edward Markey, Chair, March 16, 2010. Tami C. Bond, Associate Professor University of Illinois at Urbana-Champaign 139

GLOSSARY OF TERMS, FORMULAE & ABBREVIATIONS pg/1 Micro ( 1 O )6' grams per litre AVC Advanced Vortex Chamber - acronym used to describe part of pm Micro 11 O' 6) meter bar the Clean Marine cyclonic exhaust bar absolute gas cleaning unit pmol/l Micro 11 O'6) moles per litre % m/m BAT A unit of pressure approximately % v/v Percentage by mass e.g. the Biofuel equal to the atmospheric pressure % w/v percentage mass of fuel that on Earth at sea level; 100 kilopascals is sulphur Biomass ABS Bioassay The sum of gauge pressure and Percentage by volume e.g. the BOM atmospheric (barometric) pressure Absorbed/absorption percentage volume of exhaust in bar gas that is CO2 Borates Adiabatic Best Available Technique Adsorbed/adsorption Weight/volume percentage e.g. Buffering capacity or Technology Albedo a 50% w/v concentration is 50g Algae BV Gaseous or liquid fuels derived of solute in 100ml of final from biological sources including Alkalinity aqueous solution C materials produced by plants, Am3/h Ca animals or micro-organisms American Bureau of Shipping; Ca(OH)2 Ammonia a Classification Society - see The total mass of living matter in Ammonium Calcite AQMD http://www.eagle.org/ a given unit area ARB CARB (In the case of light) the process CAS RN Determination of the strength or of retention without reflection or biological activity of a substance transmission on passing through Catalyst a medium Bill of Materials - a numbered list of parts and components needed A thermodynamic process in to build a product which there is no heat transfer into or out of the system. An ionic compound of boron and oxygen To be attracted and held or bonded to a surface The capacity of solutes in an aqueous system to neutralize acid; The fraction of solar energy also known as alkalinity (short-wave radiation) reflected from the Earth back into space Bureau Veritas; a Classification Society - see A diverse group of plant like http: / /www.bureauveritas.com organisms ranging from microscopic single cells The chemical symbol for carbon to large seaweeds The chemical symbol for calcium The capacity of solutes in an aqueous system to neutralize acid; The chemical formula for also known as buffering capacity calcium hydroxide Actual cubic metres per hour; A term for calcium carbonate, the volumetric flow rate at the a constituent of sedimentary rock stated process temperature such as limestone and pressure California Air Resources Board - A compound of nitrogen and hydrogen with the formula NH, see http:/ /www.arb.ca.gov/ An ionic compound derived Chemical Abstracts Service from ammonia with the chemical Registry Number; unique identifiers formula NH4+ for chemical compounds South Coast Air Quality A substance that initiates or Management District (California) — accelerates a chemical reaction without itself being consumed see http://www.aqmd.gov/ in the process Air Resources Board - see CARB140

Caustic soda The common name for sodium ECA Emission Control Area hydroxide; NaOH EGCCEMS Exhaust Gas Cleaning Continuous Emissions EGC Record BookCertified Value Monitoring System A record of the EGC unit in-service EGCSCO The SO2/CO2 ratio specified EGCSA operating parameters, component EGRC02 by the manufacturer that the EGC EMAS adjustments, maintenance andCoagulant unit is certified as meeting when service records as appropriate operating on a continuous basis EPACOD on the manufacturers specified EPA-PAHs Exhaust Gas Cleaning System maximum fuel sulphur content ETM- AColloid ETM- B Exhaust Gas Cleaning Systems The chemical formula for EU Association - seeCompression ratio carbon monoxideCORMIX Eutrophication http: / /www.egcsa.com / The chemical formula forDIN carbon dioxide Exothermic Exhaust gas recirculation; a NOxDNV control techniqueDWE A chemical compound added FGDEC to water to enable suspended Eco-Management and Audit particles to be gathered together Flocculant Scheme, a voluntary European for filtration Fluorescence Union initiative designed to Chemical Oxygen Demand; improve companies' a measure of the oxygen required to oxidize all compounds, environmental performance both organic and inorganic, in water. (U.S.| Environmental Protection Agency - see A type of mixture in which one substance is dispersed evenly http : / /www.epa . gov/ throughout another Those Polycyclic Aromatic For the purposes of this publication Hydrocarbons defined by the the ratio of compression pressure U.S. EPA as priority pollutants to scavenge air pressure in a EGC system - Technical Manual for Scheme A 2-stroke slow speed engine cylinder EGC system - Technical Manual A U.S. EPA-supported mixing for Scheme B zone model and decision support system for environmental impact European Union; an economic and assessment of continuous point political union of 27 member states source discharges - see http://www.cormix.info/ - see http://europa.eu/index_en.htm Deutsches Institut fur Normung e.V; A process by which an excess the German Institute for of nutrients (e.g. nitrogen and phosphorus) cause excessive Standardization - see http://din.de growth of plants and algae (blooms) resulting in reduced Det Norske Veritas; a Classification visibility of the water and Society - see http://www.dnv.com/ decreased oxygen supply Direct Water Injection; a NOx A process that releases energy control technique - water is most usually in the form of heat injected into the engine cylinder to lower local combustion temperatures Flue Gas Desulphurisation European Commission; the EC A chemical compound added to proposes EU legislation and water to combine suspended checks it is properly applied particles together for filtration across the EU - see The emission of electromagnetic http://ec.europa.eu/index_en.htm radiation/light by a substance that has absorbed radiation of a different wavelength 141

Free radical An atom that has at least one HMI Human Machine Interface; unpaired electron in an orbital and typically PC based interactive is therefore highly reactive (unlike H2SO4 graphics representing a process an ion there is no overall electrical system - enables monitoring charge as protons & electrons are Hydrated lime and control. equal in number) Hydronium (H30+) The chemical formula for Fuel oil combustion unit Any engine, boiler, gas turbine, IAPP sulphuric acid or other fuel oil fired equipment, IBC excluding shipboard incinerators A common name for calcium IMarEST hydroxide; Ca(OH)2, also known FTIR Fourier transform infrared IMO as slaked lime spectroscopy; a technique used Ion to measure the concentration of Hydronium; - a water molecule Ionisation with an extra hydrogen ion. gaseous emissions ISO Acids are compounds that LR yield hydrogen ions (H+) or FWE Fuel Water Emulsion, a NOx LSFO hydronium ions |H30+| when control technique, which lowers dissolved in water. local combustion temperatures Luminescence International Air Pollution g/kW h Grams per kilowatt hour Prevention certificate Grams per litre g/> Intermediate Bulk Container; container for transport and storage g/mol Grams per mole; the molecular of fluids and bulk materials - often weight or molar mass of seen as a1000 litre plastic cube a substance in a metal cage. Geodesic The shortest line between two The Institute of Marine Engineering, points on a mathematically Science & Technology - see defined surface http: / / www. imarest .org / GESAMP Joint Group of Experts on the Scientific Aspects of Marine International Maritime Organization - Environmental Protection - see see http:/ /www.imo.org/ http://www.gesamp.org An atom or molecule or group that has lost or gained one or more GL Germanischer Lloyd; a electrons and so is electrically Classification Society - see charged (positive or negative] http://www.gl-group.com/ The process of being dissociated GW Gigawatt; 1 x 109 watts into ions H The chemical symbol for hydrogen International Organization for Standardization - see HAM Humid Air Motor; a NOx control technique for 4 stroke engines- http : / /www. iso.org / water is sprayed into the engine's charge air to reduce oxygen content Lloyd's Register; a Classification and increase heat capacity. Society - see http://www.lr.org/ HC Hydrocarbon emissions Low Sulphur Fuel Oil; typically a residual fuel with a sulphur (in a gaseous state at 190°C), content suitable for use in an primarily derived from the incomplete ECA until 2015 combustion of fuel The emission of electromagnetic HCO3- The chemical formula for radiation, including visible light bicarbonate after an atom, ion or molecule becomes elevated to an excited HFO Heavy fuel oil; a generic term electronic state; sometimes referred for residual fuel. Typically HFO to as cold light. Chemiluminesence has a high sulphur content and is exhibited as a result of chemical is not suitable for use in an ECA reaction without heat (also see LSFO).142

Lye The common name (U.S.) for Non-thermal plasma Plasma that occurs at room sodium hydroxide; NaOH - temperature when moleculesMARPOL see also caustic soda. O are exposed to a strong electrical field (rather than extremely highMDO The International Convention for 03MEPC the Prevention of Pollution from temperature] Ships, 1973, as modified by OMMm3/MW h the Protocol of 1978 relating P The chemical symbol for oxygenmg/l thereto (MARPOL 73/78] Pa PAH OzoneMGO Marine Diesel Oil P&ID Onboard Monitoring Manualmicron Marine Environment Protection PH Committee; e.g. MEPC 60 was The chemical symbol forMSDS Phenanthrene phosphorusMt the sixtieth session of this IMON group and MEPC Resolution Phosphate Pascal; the SI unit of pressureNa 1 84(59] was adopted at the PhotosynthesisNaOH fifty-ninth session Polycyclic Aromatic HydrocarbonNDIR Phytoplankton Cubic meters per megawatt hour Piping and instrumentation drawingNDUV Plasma - shows components and flow of a Milligrams per litrenm PM process system Marine Gas Oil ppmNm3/h PREN A measure of the acidity or lxl 06m; one thousandth of a basicity of a solutionNitrate millimetre/one millionth of a meter PSCNO QCL A polycyclic aromatic hydrocarbonNO2 Material Safety Datasheet and one of the U.S. EPA 16 priorityNOx RINA pollutants; C14H10 1 million tonnes; 1 x 106 tonnes rpm An ionic compound of phosphorus The chemical symbol for nitrogen and oxygen The chemical symbol for sodium A process that converts carbon dioxide into organic (carbon Sodium hydroxide, also commonly based) compounds, especially known as caustic soda sugars, using the energy from sunlight Non-dispersive infrared sensor; a spectroscopic device used to Microscopic organisms in the measure the concentration of upper layers of the ocean that form gaseous emissions, for example the basis of the marine food chain NOx and CO2 from an engine A distinct phase of matter, separate Non-dispersive ultraviolet sensor; from solids, liquids, and gases; a spectroscopic device used to a collection of charged particles measure the concentration of (free radicals) resulting from exposure gaseous emissions, for example to extremely high temperatures SO2 from an engine Particulate Matter Nano ( 1 O'9) meter Parts per million Normal cubic metres per hour; the volumetric flow rate of a Pitting Resistance Equivalent number; gas normalised to a standard indicates the ability of a stainless temperature and pressure steel to resist pitting corrosion An ionic compound of nitrogen Port State Control and oxygen; NO3” Quantum Cascade Laser; The chemical formula for a technology used to measure nitric oxide the concentration of gaseous The chemical formula for emissions nitrogen dioxide RINA; a Classification Society The generic term for (created by Registro Italiano Navale) nitrogen oxides - see http://www.rina.org/ Revolutions per minute 143

S The chemical symbol for sulphur t/MWh Tonnes per megawatt hour Salinity A measure of the concentration UNFCCC United Nations Framework of all the salts and ionic Urea Convention on Climate Change - SAM compounds in water U.S. EPA see http://unfccc.int/ Scavenge air Scavenge Air Moistening; a UV NOX control technique for 2-stroke The name of an organic SCFM engines - water is sprayed into v2o5 compound containing carbon, the engine's scavenge air to nitrogen, oxygen and hydrogen; SCR reduce oxygen content and Vapour pressure SECA increase heat capacity. * SECC Venturi SECP The charge of air used to purge (NH2)2CO SI cylinders of exhaust gas and WIF provide air for combustion in United States Environmental Slaked lime a diesel engine; normally used Protection Agency - in relation to 2-stroke slow so2 speed crosshead engines see http:/ /www.epa.gov/ S03 Standard cubic feet per minute; Ultraviolet light SO42- the volumetric flow rate of a Solute gas corrected to \"standardised\" The chemical formula for conditions of temperature, vanadium pentoxide SOx pressure and relative humidity. Spectroscopy The pressure exerted by a vapour Selective Catalytic Reduction in equilibrium with its condensed SSS phases in a closed vessel; a SWFGD SOx Emission Control Area substance with a high vapour TA (now superseded by ECA] pressure at normal temperatures is often referred to as volatile SOx Emissions Compliance Certificate A device with a tapered central constriction that causes an increase SOx Emissions Compliance in fluid velocity and a corresponding Plan decrease in fluid pressure Systeme International d'Unites: Water-in-fuel; a NOx control a complete metric system of technique, which lowers local standard units of measurement combustion temperatures A common name for calcium hydroxide; Ca(OH)2, also known as hydrated lime The chemical formula for sulphur dioxide The chemical formula for sulphur trioxide The chemical formula for sulphate A substance that dissolves in another (the solvent), to form a solution. The generic term for sulphur oxides The study of the way in which atoms absorb and emit light/ electromagnetic radiation Sea Surface Salinity Flue Gas Desulphurisation using seawater Total Alkalinity144

ADDENDA/CORRIGENDA • Unlike laboratory analysis online instruments cannot readily3.5.2.1 PAH measurement differentiate between the individual PAH species, because their fluorescent signatures overlap when exposed to UV lightAddendum - phenanthrene equivalents • Usefully, as well as being the most prevalent PAH dissolvedThe Guidelines for Exhaust Gas Cleaning Systems requirethat the PAH concentration in washwater be reported in in washwater the phenanthrene molecule gives the highest fluorescence signal of all the PAH species and onlineunits of phenanthrene equivalents (PAHphe). instruments can be readily tuned for its excitation and detection by calibration using a standard phenanthreneThis unit is used because solution. (Verification of the instrument's tuning can also be confirmed with an equivalent solid calibration cell.)• Studies have shown phenanthrene from diesel exhaust • The total fluorescence emitted from all detectable PAHs in to be the most prevalent PAH dissolved in scrubber washwater the washwater is therefore measured at the phenanthrene calibration point to express the concentration of the PAHs• Phenanthrene is derived from petrogenic (petroleum] in PAHphe units rather than pyrogenic (combustion related) sources and it is indicative of incompletely burned hydrocarbons in the • Phenanthrene is one of the U.S. EPA 16 priority pollutants exhaust gases and so this is a practical technique that gives a robust• Phenanthrene, along with other lighter PAHs, is dissolved online measure of polycyclic aromatic hydrocarbons in washwater in order to prevent harmful discharges to sea into the washwater during scrubbing, whereas heavier (pyrogenic] PAHs become bound onto particulate matter. (Pollutants in the washwater are removed by the washwater treatment plant and the effectiveness of particle removal is measured by turbidity meter)Figure: Fluorometer for PAH detection in water 145



It's one minute to twelve.Is your ship or fleet prepared for January 1, 2015?Time to look at your options. PureSOx from Alfa Lavalreduces harmful emissions by scrubbing sulphur from theexhaust gas from vessels operating on HFO. PureSOx isa hybrid system that runs in either seawater or freshwatermode.Cost-saving•Low-cost solution compared to running on low sulphur MGOFlexible•Exhaust from multiple engines cleaned with one scrubber•PureSOx functions in all known conditionsEasy to operate•Automatic switching between sea and freshwater mode•No need for chemical additives in seawater modeBased on experience•Largest system currently in operation (21 MW)For more information, please contact Rene Diks on+ 31 24 35 23 180 or [email protected] Scan the code and watch the PureSOx animationwww.alfalaval.com

BELCO® Marine Scrubbing SystemsControlling Air Emissions on Land and Sea The Benefits of BELCO® Marine Scrubbing Systems Reliable and cost effective design — Able to use various reagents and regenerative buffers. designed specifically for your vessels in conjunction with your engineering staff. Low pressure drop design. Open tower design. Able to High reliability and durability. operate uninterrupted for many years concurrent with required dry- Since the 1960s, BELCO® has been a dockings. No concern with plugging or global leader in the reduction of SOX' maintenance shutdowns while at sea. NOx and particulate emissions. Now the No hot by-pass required. shipping industry can benefit from the High efficiency of pollutant removal. extensive experience of BELCO®. Let the BELCO® Marine Scrubbing System help Helps meet all IMO, SECA, and EPA regulations, even when using high you save money by reducing your S02 sulfur fuels. emissions without switching to costly Designed to withstand upset conditions low sulfur fuel. and temperature excursions. -! * IKioto Seawater Supply Pumps uo© Exhaust Stack with S02 Monitor REFfMNC i LU Steam Coil for COMMNY Plume Suppression * GO mm BELCO I Scrubber Replaces Silencer * SCRUBBER =5 mJ> ft[ImwcmrBmimeKrrorrcscmoMrrmiomIi murr ,- /BL Expansion Bellows VALERO IS gn NOx reduction when required jgl A PROUD “ I/S1 IWMBEROf: Seawater Cooling Return r!» SEAWATER DISCHARGEBelco Technologies Corporation Exhaust Gas Outlet9 Entin Road - Parsippany, NJ 07054 USAPhone: +1 973-884-4700 Diesel Engine or BoilerFax: +1 973-884-4775E-mail: info@ belcotech.dupont.comwww.belcotech.dupont.comwww.sustainablesolutions.dupont.comDuPont Sustainable Solutions -The miracles of scienceCLEAN TECHNOLOGIESCopyright © 2012 DuPont. The DuPont Oval Logo, DuPont^, The miracles of sciencev, and BELCO® are registered trademarks or trademarks of El du Pont de Nemours and Company or its affiliates. All rights reserved.

CLEAN MARINEEXHAUSTGAS CLEANINGMADE BY SHIP OWNERSFOR SHIP OWNERSClean Marine is one of the pioneerswithin the maritime Exhaust GasCleaning System (EGCS) industry.We take pride in the way maritimeand process knowhow have beencombined and reflected in our EGCSproduct. Clean Marine EGCS is fullycompliant with IMO Annex VI sulfurrequirements.• One cleaning unit serves all exhaust sources (multistreaming)• Operates in both open and closed mode (process fluid recirculation)• Suitable for new buildings and existing ships.• Easy to maintain and operateDedicated Experienced KnowledgeableTrustworthy Qualified Bringing technology forwardwww.cleanmarine.no



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PROCAL emissions innovation Marine Emissions Monitoring Applications NOx Technical Code r* MEPC 184 (59) Scheme B Scrubber Exhaust Gas Analysis System (S02 / C 02) Ship Efficiency Approvals ABS Type Approval Annex VI Reg 13 NOx Tech Coder* IMO Res. MEPC 103 (49) IACS Unified Requirement E10 & IEC 60945 (parts) :: ' r s- .iralgr nwi ^rton ABS Kittiwake Procal Ltd KITTIWAKE: A Kittiwake Group Company monitoring innovationas ISO 9001:2008 TYPE APPROVED PRODUCT LBKjJAjSl Oualllv

TURNERr fDESIGNS * Hydrocarbon instruments # I Worldwide for Environmental and Process Oil in Water Monitors mEGC Washwater TD-4100XD / TD-4100XDCDischarge Monitors jfrom the industry The TD-4100XDC is a \"Closed Cell\" version of the rugged,tender in oii in world industry standard TD-4100XD Oil in Water Monitor. Itwater monitors! was designed for normally clean water applications or dirty water applications where fouling can be controlled byOur PAH Total System Concept uses our chemical injection or optional on-board cleaning systems.own fluorescence measurement for PAH The TD-4100XD is designed specifically for offshore oil production, refining, petro-chemical, mining, and otherplus turbidity and pH all in one system. industries that require robust on-line hardware for severeDesigned to meet the requirements of duty and hazardous area locations.Annex 9, MEPC.l 84(59), we aredeveloping a complete black box solution TD-4100 / -TD 4100Cto meet the rigorous schedule demands of TD-4100 reliably detects BTEX, gasoline, diesel, jet fuel and oil in water. The TD-4100 is a nonfouling, continuous,the new regulations. on-line monitor that provides hydrocarbon and oil in water monitoring down to low ppb.With a reputation for producing highlyaccurate and reliable instruments through The TD-4100C is a \"Closed Cell\" version of the worldquality design and manufacturing, we are industry standard TD-4100 Oil in Water Monitor. It wasdeveloping the new generation Washwater designed for normally clean water applications or dirtyDischarge Monitoring System. water applications where fouling can be controlled by chemical injection or external cleaning systems.Over the past 1 8 years, we inventedthe industry's first on-line oil in water TD-SOODfluorometer with internal cell conditiondetector (TD-4100 XDC), the first IMO TD-500D featuring the least expensive, lightest, smallest, easiest107(49)-certified purpose designed to use, most accurate and most repeatable device on the market forfluorescence bilge water monitor (TD-107), measuring crude oil and condensates in produced water, de-salter tailthe first hand held oil in water analyzer water, tank bottoms, cargo heaters, or anywhere that crude oil comes(TD-500D), and the first ever \"No-Solvent in contact with water. Compatible with all standard solvents. AnalyzeMethod\" for oil in water analysis. with solvent extraction or \"No-Solvent\" method.Our instruments are backed by TD-IOOOCexpert knowledge and a world DNV The field-proven TD-1000C is rugged and reliable with the lowest maintenance in the industry. Its fluorescence sensorclass service department. ISO 9001:2008 technology provides high accuracy and repeatibility as well as the earliest leak detection available.Please visit our website: TD-107www.oilinwatermonitors.comfor more information. TD- 107 uses our signature FLUORESCENCE measurement technology that can be universally applied to bilge water monitoring. Low maintenance, rugged, and all the features defined by marine customers and regulators. TD-3100 The TD-3100 is a low cost benchtop instrument that was developed to provide an alternative to industry standard oil and grease methods. Compatible with all standard solvents. Analyze with solvent extraction or \"No-Solvent\" method.TURNER DESIGNS Hydrocarbon Instruments2023 North Gateway Blvd., Suite 101, Fresno, California 93727 USA / TEL: 559 253 1414 / FAX: 559 253 1090 / www.oilinwatermonitors.com

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IIExhaust Gas Cleaning Systems are a highly effective solution to thechallenges of IMO MARPOL Annex VI air pollution regulations andthe added complexities of regional and national emissions legislation.It is crucial that ship owners and operators fully understand their optionsfor compliance. To aid decision making this guide contains a wealth ofinformation, including:• The impact of emissions, current and future regulation and the IMO Guidelines for Exhaust Gas Cleaning Systems• Types of Exhaust Gas Cleaning System for SOx, PM and NOx, including system configuration and installation, materials of construction and compliance instrumentation• Scrubbing processes, dry chemical treatment and washwater handling• Comprehensive details of commercially available systems from EGCSA membersAs exhaust gas cleaning technologies and legislation evolve, it is intendedto further update this publication to keep pace with developments andEGCSA encourages all with an interest in this business critical area to takefull advantage of each new edition as it is released.m EGCSAexhausf qa: clear toms QSSO jtion