Dispense-Gas-2013

SUREGASProduct: Carbon Dioxide MSDS Nr. 300-00-0032 Gas safety data sheet1. Identification of the substance/preparation and of 6. Accidental release measures the company Personal precautions Evacuate area.Wear self-contained breathing apparatus when entering areaProduct name Carbon Dioxide unless atmosphere is proved to be safe, i.e. oxygen concentration is 21% +/- 2%Chemical formula CO2 and CO2 concentration is less than 1.5%. Ensure adequate air ventilation.Company identification BOC, Priestley Road,Worsley, Manchester M28 2UTEmergency phone 08457 302 302 Small release For a leaking cylinder, try to stopnumber release by closing the valve if safe to do so.2. Composition/information on ingredients Major release Evacuate the area immediately.Substance/ Substance (e.g. bursting disc Cylinder bursting disc activation will bePreparation activation) evident by a sudden noise accompanied by a prolonged discharge of productComponents/ Contains no other components or seen as a white vapour. Frost may beImpurities impurities which will influence the seen on the cylinder.The cylinder classification of the product. should be left to discharge and BOC contacted.CAS Nr 00124-38-9EEC Nr (from EINECS) 2046969 Environmental Prevent from entering low lying Precautions areas where its accumulation can be3. Hazards identification dangerous, e.g. cellars.Hazards identification Liquefied gas. In high concentrations Clean up methods Ventilate area. may cause asphyxiation.4. First aid measures 7. Handling and storageInhalation Low concentrations of CO2 cause Handling and storage Cylinders should be secure whenSkin/eye contact increased respiration and headache. stored or in use. Only use cylindersIngestion when in an upright position. In high concentrations may cause asphyxiation. Suck back of water into the cylinder must be prevented. Do not allow Symptoms may include loss of backfeed into the cylinder. mobility/consciousness.Victim may not be aware of asphyxiation. When cylinder valves have been exposed to flooding in cellars, the Remove victim to uncontaminated area cylinder must not be used and BOC wearing self-contained breathing notified for collection. apparatus. Keep victim warm and rested. Call a doctor. Apply artificial Do not store cylinders adjacent to respiration if breathing stops. direct heat sources or within sealed rooms where ambient heat may build Immediately flush eyes thoroughly with up. Keep cylinder below 50°C. Failure water for at least 15 minutes. In case of to do so may cause the bursting disc to cold burn spray with water for at least rupture (see 6, Major Release above). 15 minutes. Apply a sterile dressing. Store in a well ventilated place, and if Obtain medical assistance. this is not possible conduct a confined space risk assessment. Ingestion is not considered a potential route of exposure. Use only properly specified equipment which is suitable for this product, its5. Fire fighting measures supply pressure and temperature.Specific hazards Exposure to fire may cause cylinders to Only open the cylinder valve when rupture/explode. connected to equipment. Open and Non-flammable. close valve slowly. Close cylinder valveHazardous combustion None. when not in use.products 8. Exposure controls/personal protectionSuitable extinguishing All known extinguishants canmedia Exposure limits Carbon Dioxide Occupational be used. Great Britain Exposure Standard (OES) Short Term Exposure Limit (STEL)Specific methods If possible, stop flow of product. 15000vpm Move cylinder away or cool with water Long Term Exposure Limit (LTEL) from a protected position. 5000vpm (EH 40/2002)Special protective In a confined space use self- Personal protection Ensure adequate ventilation to keepequipment for contained breathing apparatus. below exposure limits.fire fighters1 Emergency tel: 08457 302 302

9. Physical and chemical properties Labelling ADR Label 2.2: non-flammable, non-toxic gas. Other transportMolecular weight 44 information Avoid transport on vehicles where the load space is not separated from theMelting point -56.6°C driver’s compartment.Boiling point -78.5(s)°C Ensure vehicle driver is aware of the potential hazards of the load and knowsCritical temperature 30°C what to do in the event of an accident or an emergency.Relative density, gas 1.52 (air=1) Gas/vapour heavier than air. May accumulate in confined Before transporting cylinders ensure that spaces, particularly at or below they are firmly secured and: ground level. - cylinder valve is closed and not leakingRelative density, liquid 0.82 (water=1) - valve guard is correctly fittedVapour pressure 20°C 57.3 bar - there is adequate ventilationSolubility mg/l water 2000 mg/l - compliance with applicable regulations.Appearance/Colour Colourless gas.Odour No odour warning properties. 15. Regulatory information10. Stability and reactivity Number in Annex I Not included in Annex 1.Stability and reactivity Stable under normal conditions. of Dir 67/548 EC Classification Not classified as a dangerous substance.11.Toxicological information Labelling of cylindersGeneral Carbon Dioxide is mildly toxic, with no - Symbols Label 2.2: non-flammable non-toxic gas. cumulative effects. High concentrations cause rapid circulatory insufficiency. 16. Other information Symptoms are headache, nausea and vomiting, which may lead to Ensure all national/local regulations are unconsciousness. observed. Asphyxiant in high concentrations.12. Ecological information Keep container in well ventilated place. Do not breathe the gas.General When discharged in large quantities The hazard of asphyxiation is often may contribute to the greenhouse overlooked and must be stressed during effect. operator training. Contact with liquid may cause burns/Global warming factor 1. frost bite. Users of breathing apparatus must be13. Disposal considerations trained. For beverage dispense only.General Discharge to atmosphere in a well Before using this product in any new ventilated place. Do not discharge into process or experiment, a thorough any place where the gas may material compatibility and safety study accumulate. Discharge to atmosphere should be carried out. in large quantities should be avoided. Details given in this document are Contact BOC Gases if guidance is believed to be correct at the time of required. going to press.Whilst proper care has been taken in the preparation of this14.Transport information document, no liability for injury or damage resulting from its use can beUN Nr 1013 accepted.Class/Div 2.2ADR/RID 2A 5 015573 569118 5 015573 569118Classification Code SizeADR/RID Hazard Nr 20 Claybleinl dfoerr SRUBROcCEarGGbSAounASrEedgSSioaxsideCOMGPRA2ESSSED•B•OC•DCo•BKnoG•OAteanCaFseseocpOpGstt,hRaPcyswbroeixeBrsins,teiPtEathalreaVnityeilthEnisRqteRieolenuaryAgdihdRai,GWnoisgcaEoEahdar,DEs•nWwlceCIHoycoeS,ranMlePslNuclaaeEvensvyoNe,ceniM.hentSe2fartrrsEn0itaoctle4thaOhrseit6tMaosNe9tn2nbedL86rsuYa29MpriUrl2naT8sc2eUFTormRE3e0v271930 Pressure 50 bar at 15°CPIHNUpmOFsrdeeooEasUrodtNsanfueMulrrNsyreaEhtteE.eheOqee01uRftrpo”iep3i0r.nGncmf4e1oaeEron53nmdntNlaycs3.tuloiCiC0otslaneo2bYssvleeea3elafvofte0trhese2trlho“uiwsGselya.s–safetyVolume reference chartSureflow Gas Maximum Cylinder size Approx. Nominal Gross weight Nominalgas type cylinder filled pressure (cm) cylinder weight weight of gas cylinder + gas gas volume (bar) Diameter Height (kg) (kg) (kg) (m3) 3.15 10.15 1.7SUREGAS E 50 14.0 50.0 7 6.35 21.35 3.4Food quality CO2 B 50 14.0 83.0 15 6.35 22.35 3.4 B 50 14.0 94.0 16 6.35 18.35 3.4 SB 50 16.6 62.8 12 6.35 17.35 3.4 SB 50 17.6 69.0 11 12.70 36.70 6.8 P 50 14.0 150.0 24 13.80 43.80 7.4 R 50 20.3 87.0 30 34.00 99.00 18.2 K 50 23.0 149.5 65Notes: The nominal volume of gas is measured at 15°C and 1013mb pressure. Actual contents, volume and weight can vary around the nominal figures indicated. Cylinder height includes a 10cm allowance for the cylinder valve and guard.Emergency tel: 08457 302 302 22

SUREMIX 30, 50, 60Product: Nitrogen + Carbon Dioxide MSDS Nr. 300-15-0008 Gas safety data sheet1. Identification of the substance/preparation and of 6. Accidental release measures the company Personal precautions Evacuate area.Wear self-contained breathing apparatus when entering areaProduct name Asphyxiant (+CO2) unless atmosphere is proved to be safe, i.e. oxygen concentration is 21% +/- 2%Company identification BOC, Priestley Road,Worsley, and CO2 concentration is less than 1.5%. Ensure adequate air ventilation. Manchester M28 2UT For a leaking cylinder, try to stop release by closing the valve if safe toEmergency phone 08457 302 302 do so.number2. Composition/information on ingredientsSubstance/ Preparation Environmental Try to stop release if safe to do so.preparation precautions Prevent from entering low lying areas where its accumulation can beComponents/ Contains the following components: dangerous, e.g. cellars.impurities Nitrogen and Carbon Dioxide. Refer to table overleaf. Clean up methods Ventilate area.3. Hazards identification 7. Handling and storageHazards identification Compressed gas. Handling and storage Cylinders should be secure when In high concentrations may cause stored or in use. Only use cylinders asphyxiation. when in an upright position.4. First aid measures Low concentrations of CO2 cause Suck back of water into the cylinderInhalation increased respiration and headache. must be prevented. Do not allow feedback into the cylinder.Ingestion Exposure to high volumes of nitrogen and carbon dioxide mixtures may cause When cylinder valves have been asphyxiation. exposed to flooding in cellars, the cylinder must not be used and BOC Symptoms may include loss of notified for collection. mobility/consciousness.Victim may not be aware of asphyxiation. Remove Do not store cylinders adjacent to victim to uncontaminated area wearing direct heat sources or within sealed self-contained breathing apparatus. rooms where ambient heat may build Keep victim warm and rested. up. Keep cylinder below 50°C. Store in a well ventilated place, and if this is not Call a doctor. possible conduct a confined space Risk Assessment. Apply artificial respiration if breathing stops. Use only properly specified equipment which is suitable for this product, its Ingestion is not considered to be a supply pressure and temperature. potential route of exposure. Only open the cylinder valve when5. Fire fighting measures connected to equipment. Open and close valve slowly. Close cylinder valve when not in use.Specific hazards Exposure to fire may cause cylinders to rupture/explode. Non-flammable. 8. Exposure controls/personal protectionHazardous combustion None. Exposure limits Carbon Dioxide Occupationalproducts Great Britain Exposure Standard (OES) Short Term Exposure Limit (STEL)Suitable extinguishing All known extinguishants can 15000vpmmedia Long Term Exposure Limit (LTEL) be used. 5000vpm (EH 40/2002)Specific methods If possible, stop flow of product. Personal protection Ensure adequate ventilation to keep Move cylinder away or cool with water below exposure limits. from a protected position.Special protective In a confined space use self- 9. Physical and chemical propertiesequipment for contained breathing apparatus.fire fighters Relative density, gas Gas/vapour heavier than air. May accumulate in confined spaces, particularly at or below ground level. Solubility mg/l water No reliable data available. Appearance/colour Colourless gas. Odour No odour warning properties.31 Emergency tel: 08457 302 302

10. Stability and reactivity 15. Regulatory informationStability and reactivity Stable under normal conditions. Number in Annex I Not applicable for preparations. of Dir 67/54811.Toxicological information EC Classification Not classified as a dangerous preparation.General Carbon Dioxide is mildly toxic with no Labelling of cylinders cumulative effects. High concentrations cause rapid circulatory insufficiency. - Symbols Label 2: non-flammable non-toxic gas. Symptoms are headache, nausea and vomiting, which may lead to 16. Other information unconsciousness. Ensure all national/local regulations are observed.12. Ecological information Asphyxiant in high concentrations. Keep container in well ventilated place.General When discharged in large quantities may Do not breath the gas. contribute to the greenhouse effect. The hazard of asphyxiation is often overlooked and must be stressed during13. Disposal considerations operator training. Users of breathing apparatus must beGeneral Discharge to atmosphere in a well trained. ventilated place. Do not discharge into For beverage dispense only. any place where the gas may accumulate. Before using this product in any new Discharge to atmosphere in large process or equipment, a thorough quantities should be avoided. Contact material compatibility and safety study BOC Gases if guidance is required. should be carried out. Details given in this document are14.Transport information believed to be correct at the time of going to press.Whilst proper care hasUN No 1956 been taken in the preparation of thisClass/Div 2.2 document, no liability for injury orADR/RID damage resulting from its use can beClassification Code 1A accepted.ADR/RID Hazard No 20Labelling ADROther transport Label 2.2: non-flammable, non-toxic gas.information Avoid transport on vehicles where the load space is not separated from the driver’s compartment. Ensure vehicle driver is aware of the 5 015573 565127 Label for SUREMIX 50 5 015573 565127 potential hazards of the load and knows what to do in the event of an accident Size (see 6. Accidental release measures). S BOC GASES COMGPRA2ESSSEDcarbSnouinrtredomigoiexxnid50e•BO•DC•KoBG•AOenaeCFssoeppOGts,hRacPbsyoreirxBesne,siPEttaalreaVtniyeihEstnRtReloeeianyrAgdR,aGihWonsiaEogdar,hDsW•lweIcoyNS,roeMPsollnealEyncNov,ceMhedSneanoEsntttcurehOirarleaMNtstti2eoLe8rYndM2Us2pET8l92aU4cTF1eormRE3e02v61950 Before transporting cylinders ensure that Filled to 200 bar max at 15°CPIHNUpmOFsrdeeooEasUrodtNsanfueMulrrNsyreaEhtteE.eheOqee01uRftrpo”iep3i9r.nGncmf4e5oaeEron56nmdntNlaycs3.tuloiCiC0otslaneo2bYssvleeea3elafvofte0trhese2trlho“uiwsGselya.s–safety they are firmly secured and: - cylinder valve is closed and not leaking - valve guard is correctly fitted - there is adequate ventilation - compliance with applicable regulations. 5 015573 564120 Label for SUREMIX 30 5 015573 564120 5 015573 566216 Label for SUREMIX 60 5 015573 566216 Size Filled to 200 bar max at 15°CPIHNUpmOFsrdeeooEasUrodtNsanfueMulrrNsyreaEhtteE.eheOqee01uRftrpo”iep3i9r.nGncmf4e5oaeEron56nmdntNlaycs3.tuloiCiC0otslaneo2bYssvleeea3elafvofte0trhese2trlho“uiwsGselya.s–safety Size Filled to 180 bar max at 15°CPIHNUpmOFsrdeeooEasUrodtNsanfueMulrrNsyreaEhtteE.eheOqee01uRftrpo”iep3i9r.nGncmf4e5oaeEron56nmdntNlaycs3.tuloiCiC0otslaneo2bYssvleeea3elafvofte0trhese2trlho“uiwsGselya.s–safety V BOC GASES COMGPRA2ESSSEDcarbSnouinrtredomigoiexxnid30e•BO•DC•KoBG•AOenaeCFssoeppOGts,hRacPbsyoreirxBesne,siPEttaalreaVtniyeihEstnRtReloeeianyrAgdR,aGihWonsiaEogdar,hDsW•lweIcoyNS,roeMPsollnealEyncNov,ceMhedSneanoEsntttcurehOirarleaMNtstti2eoLe8rYndM2Us2pET8l92aU4cTF1eormRE3e02v61920 S BOC GASES COMGPRA2ESSSEDcarbSnouinrtredomigoiexxnid60e•BO•DC•KoBG•AOenaeCFssoeppOGts,hRacPbsyoreirxBesne,siPEttaalreaVtniyeihEstnRtReloeeianyrAgdR,aGihWonsiaEogdar,hDsW•lweIcoyNS,roeMPsollnealEyncNov,ceMhedSneanoEsntttcurehOirarleaMNtstti2eoLe8rYndM2Us2pET8l92aU4cTF1eormRE3e02v71900Reference chart Gas Maximum Cylinder size Approx. Nominal Gross weight Nominal cylinder filled pressure (cm) cylinder weight weight of gas cylinder + gas gas volume Sureflow gas type (bar) Diameter Height (kg) (kg) (kg) (m3)SUREMIX 30 V 220 14.0 094.0 16 03.45 19.45 02.4830% CO2 / 70% N2 S 220 20.3 087.0 30 06.27 36.27 04.51SUREMIX 50 N 220 23.0 149.5 65 16.33 81.33 11.7450% CO2 / 50% N2 V 200 14.0 094.0 16 04.20 20.20 02.75SUREMIX 60 S 200 20.3 087.0 30 07.73 37.33 05.0660% CO2 / 40% N2 N 200 23.0 149.5 65 22.25 87.25 12.94 V 180 14.0 094.0 16 04.53 20.53 02.80 S 180 20.3 087.0 30 08.32 38.32 05.12 N 180 23.0 149.5 65 20.99 85.99 13.14Notes: The nominal volume of gas is measured at 15°C and 1013mb pressure. Actual contents, volume and weight can vary around the nominal figures indicated. Cylinder height includes a 10cm allowance for the cylinder valve and guard.Emergency tel: 08457 302 302 42