10.7 fi1~ VI bVl~@l n~f?l-bua
}0.1 m6\"I\\ \\'l'\\\\C)'\\~oirW6'- b'Do( ·+- - t - +-!Cl + NClOH ) No..CA + H1P s~r ~ siY· bc.\\se, Nt..v.-TY-0J rz.a.tioh yel{.Otion\"~RkJitr:,;u 11 / Na.-+ ~me:, of1i ~n6' h'fmlt5is ~ ~et,ttl\"O-JI r~ = '7 LH-301) ~ [ot(J -:: 1X 1!7-4 M\"1\\~.,.. I~ 0.'2. M 8to'Ml 1i1Y't,\\,\\E ~ I ~cia 0) Mo! No.~ ~ 0. Z. wiol 'l< 10 r1L 1000- y\\l\\L = cY. e. M (D LJ~CIJ \"\" z ~10-J~, \")( 1000 ML 10 Ml 1L ·@ 'MOl 11 r· ML..l :--- o(JQ l1 r ~~ .) - 1 .,..,[J ( ~ ',. _A ~ ~ - 1,.... .L.'( )('l, lz ~C,\\ + ~Cl COi-\\ ~ Ba..G\\z_ + 2. \\..\\i,O - j'V\\~~ (} . 2.M 10 ~ L hh-ode =? to ML CD i~'\\\\li,~9J0. o..tor\\\\ ~ ~ z)(,o.i 'M.0\\ .>i 1t7 ML 10- 7 )IA.O l 1t,00 Ml, C\\ . -:.. II ® [ HCIJ ~ i wl ~c\\ )( z,qo·3 Y\\4ol ~ ~ A )( LliOO ML. \\ r. 1MDI ; 10 'M ir 1l ... --- (D + (D -;: 0.4 M 1., -. ,. .. LMC. \\] ,. P. \\Y\\ol -A x 0.2 Mo\\ P.> x io Ml 8 :,. ,oo~,~ 1 \"M.ol llJ 1000 ML B IOMLA 1L :: 0-4 M (.'rtlo/lL)
.. '----=-- - -- -pH -- -- - - - ------:------ t-}UvOl-\\ O '7 n6\\Jj 11 &6\\Hfl t 1,tJ~rt - pH~\"HJrfo\\M,..;1,--H.-,\"!'\"\\\"J\"li\"\"~\"_,'M'~~- - - - - - - - - - -- - ~H >YJ oS61eo\" +~vrf~ - - - - - - - - - - - , 5'5a4ffl2Je?JmJi1 ~\" 56.:___ _ _ _ _ _ _ __ 1. ~A t N{k,OH >~A -r Hi,0 - - - - - ' - - - ----- ,t,04 .lt ~l!t-t~I i~ + o ._w..1- j M=? --- ,ti 1'i ri/. --i- - --- . -------- J.-..:.! J!) i~~·ti£J~n 1-\\A ~ '\\ M.O\\ HA ~ O:_W4 .-1 1 >< io-3 MJI I. . 1J'4-. 'li ~ . © l ~A1 -;. 1 x 10-3 r-iol 'f. , DCO ~ -:.. 1,Z. r-i L 1L \\-1 A --;. 0-0'l )\"rlol 7- 12 l11ol -- er b 'I 10~a. ll'«'I \"{OOOML - 'IC ~.6x /0-4t:1f,I A '° B 1(X}O 'r\"l hl B~ fl''\\O 'l< I1 >--wl A '8\" ~L. B 1L ;: o.1i [V)
CD -@ [ N\"'OH] -: '\\ 'YV!o\\ N\"-OH Y. ~ \"Mo\\ \\-If\\ y. o.204-~ ~A )( )2, l\"ll HA x 1a:v ML ioa .zz~ 1'2-\"ML ~ ML t.J~H '\\ Mo\\ r\\ A 'l L ==- o.12.5 Y\"!o I / L M -~~1l~$0i 10.J ~- ~ 1- r\\ N0.3 4- \\(Or\\ ---7' -\\<. NOO ~ \\-\\1P M~ ~ 0-1M 2.s yv,L t\\\\YW-Je-~. £-O--'M· L- - - -- -~o.t~~}1~o\\ ficid ==- rvto\\ (D ~'\\b~'tbl~~ KO\\i \" 0.1 \"Mol x eorvvt_ 1 p_ .x 16'' \\\"AD) _______ _ ~woo M~ ® [HN0,1 \"' ;: o. O\\S M _ - - -- _ .t x 10 h'ID\\ )<. _ iDC,◊ )\\,\\L ~ [~NO J £5 VVl-l 1L = 1\"fvlOI A , y: o.11Y1ol 0 )( ~ ~'M,l_ 1' )< tooo -r,,L ::. _c,.o~M _ 1 'MDI 0 1ooa rAL ~ 2.5 \"\"'L A 1l ~ - _G\\/A-~ G_Vs - - -- - - -- __,__ -- 'I - = 0.0'6 M - -I l . N~QB + \\jC,\\ ~ NDI.CI ~ l:l-z,O__ _ _ 1.o M o.oo f. /Ill . ' '~ 4 6 ~- -- 1(1·-,0·-'M.L- - 4. • G) ~'U,'}tt,j)JN HCl ; o.00 2 M~I r- iOO'ML ::. 2_ X tO _ MD' ® ~.,~i~l~~ to oo '1\"\\t. NP--OH j V.t]~ ~ 1 )vlo\\ x ~ Y1 L -x j _'\\.l~ _.:. ~ x 1ci5_n_toJ_ _ 1000 'ML 1}.) \\-1.f)O'l -&.. -,: 10_5 : . ~-o~,~~ HCl b~~@ = 12 x tCY -5 ~ 2. ~ ~&. 0.5 - .1. 10 - ~ 10 ~ 1.S x 10£1 'MO\\ ~ti I:: 1-5 -< 10-.1)>'10 'J' 1000 ml ~ i .~ x -J n_ 10 10° )'\\\\L 1L
. ~ p~ = -\\o~t1-S)(10~ ~ 3)0Jio -\\0~1 -5 ~ 0 - 0.~'n ::c 2.B2. - --- J .. Nr\\j + ~e,, ~ Nrtlc,_ _ _ - -'-- _. _-_'-- 28~l 0-5 ~ ~,~bf\\~j\\ N\\-tJ ::: 'la + HJ)~ - - - - - - -.. -/· whl 37.-40Yr1L _ _ _ ~ 11 ~l ~ol ________ .,, ~ - - -f- wJ\\/ ,. _\\tJ ~N\"~ \"A j yrp\\N\\-\\~ ,c i,.,; V'lo\\\\.\\cl t. ~2.4o titL\\jCl 2...P)___ .. 1l'tol NH~ 1 'Mo\\\\-W,I 1000 rriL rtl e8 '!'YIL NH .3 ,. jJ ·/- W/\\,J..c.__ ·--- - -- - - - --- - - _4 .. G) ~:iti\\,l\\~ o\\ _(J\\~O~ _;; b()_'l)+ 1(8)_j:_ 6(1b)_ _:_ \"Mb 3/r,io,I .. - . - - - - ® ·L·_wly,i _.,, t1~ ~ CbHsOt. ,x 1}','O\\ C,rL~eib x (t.02 Y)l'.)I j\\koH ~ 15-to Y>llf\\ktOH~1\" £.\"10 I tv~ .. 1000 ~L Not0+1 0-1 ~ Ve, rriol Cd-lgD~ ----t-- -- - - - - - -·- - - - ________---------. - , ....... - - ------ ---- -- ---
O'mr\\j 10.5 1. C'r\\,cooH ~tl C\\\\.,G~Nlt coo~ _c,113 N~ -~➔-_ ()~coo- t Netf - . __ Cr\\,COOti / Cl\\,ccd ~ 1' - ~~s.i H,JO vnf'll ~ - + \\\\,,O-\\- ~~ Q-1.;C_OJH ~ z9 CC() - ~~OH- C+~c~ .:r OH- ~ _c~cco- ~ HzO ------- - ,Po + - -------- - ./0P. . H 4 ~JJ N~ ,1, \\i~f()_A I t-\\i.PO~ - ~\"'~ ~C)+ -+ r\\~P04 __::_ ~ Q ~ ~P04 -t \\-tp l - Oti~~&)\\ 4OHl-\\1,90A -t U ,0PD----:i.. 2 t \\.-12 • fo. N\\-\\:Cf n,-i N\\-\\, ~ ~l I ~HJ I -~e-1~ H_:)O NH~ -4- w_,ot ~~- NH: ~ ~io - b&!SJ m-1-
(\\i_,coo~ I c~coo- ~ ------ - C\\-\\?> COO\\-\\ t- \\\\ -z,0 ~ t - H-30 + C)-\\~CDO ~ • Lt¼6JTc}hcc<5J _. _ lCrhcoo\\-\\) [H~O+J : K~ ')( lt\\-\\ac,d)H) [.C\\-\\:{,oO) - - - -♦ ri~~~oX4J,~ f \\-\\ 1\"~ y'fo 1.. [C~}~ootl) = [CHJCOQ] pH : pKix_ - \\031 . F'\"' ~ pK~ - .2.,__[c~~~J >_[c~~61 2~ 1111 ~ pH = pK~ - \\~ ~ y\\-\\ \" ~~- o.801 yH < ?~ 2i. [ CH/~OOH J < [cH c,c()] 1M ~M 1 fH ~ fKo_ - 109 ~ -;: f~a. - CIa~ 1 - \\ o9i) V'1 :: f KI}., + Q.~<,j_ P'\"' :> f'KQ
0 cµ coo- t ~ 2o _CtbC-~H ~OH_ _ 3 K~ , ICH}~ooHJ[o~fJ _ _____ [cHJeco·J [011·] ~ K~[ Cl-\\ coo- J 3 [ C\\.\\_., c.ooH] - - - - - - - - -- - - - - - - -' - pH + pOt-\\ ~ J tt ____ prt = _14 -_po H --- --- ()\\f~ff@'lJ ~'>1 3J \\,f11-a. '\\!°\\}:1 b°l 1. I-\\J04 + N\"'-OH ➔ ~H.iiffi4 J-1 i~ - - 0 ,1M 0.1111 1(V) ~ + 5 ML 10'ML i ~~te 'V-.~6' _ 6\\\"1acn'tl.l.b61~u~ Pb ~ (-'I G) . v,~~1~i H}~A ~~~ '11,f)')abDO\\~n,Y' :e 1'Mol~P04 x 0.1 \\'YJC)' No.OH )( 5 ML -- 5 >< 10-4 Yll<Y) 1 l'V!OI NoL0\\1 1@ ML @. ~~1~~\\\\l~ l t~~a.. i~~~ (0.1 M '\\O_ ~) ~ -=- 0.1'M.o\\ >< 10 )'11\\_ -:c -i ~-1.if' )111.0 l @) lO~ wtL ~3PO4 -~b~~ ~%~CU\")~~ 1 _; - -~ \\ >-t<Y & ~10 MO! to ,q o'=- 5 ,.. 1o\\ s i'( 10-~l
-- @. ~'\\},~\\~~re N~\\\\ fb.1 ~~~J~ == 1 Mo\\ ~N~~oH2 004 i. 0.1~ 1NoiJ>tt >< 5'ML 1rv-ol 1000 Y\"\\l ---r-- - - - ~-_:_ -r_~lo3-(6.'q023, \"i--toJ _-_-__-__-_-__-_-_ - _ _ _::: ~ ~\\o~ 1<1._-Jo~ 1-.9.2. _____ -... \" _-_084_ __ 21 i_ \\')~ =- - - - - - , . - _ J , , . __ _ _ _ _ _ _ __ ~COO\\l @~la'1~6'1t) ;::.) ~ ------· - ---------· C\\-\\~caoNet ~ Cl-\\.;coo- -\\: N°\"-+ tl\\3eo6 +1-lzO ~ G) ~'qt1oroi6' Cl.f ~COONo. ~d~~f'-\\, t, °'-S :: 1~\\ GH./-OO~a -r: Q.1 Ntoo\\oC,~~ CeoH x. 1C> 'wll '\\ Pt0I cti ocro~
lI_\\ - ~ 20 _ C\\1C~Jl-l ~_QH CYJCOO t ~~ = l:CH[c3HC_O,OcCH<];J[o~f] [OH-} -;: k~rtH,c,oo-] [c~3 c,ooH] - \\03[0HJ ;: -\\05 Kb- \\o~<[r\"c'\"\".H...,.'C--o_<i~J - - - t c\\.t3c ooHJ pOH ,, pK0- logLC\"3 tocn __ [rn3 cmH] f~ + pO\\-t ~ 1t1. - - - - - - prt - j 4 -_po H_ - - - - - - - - - ------- 0 ,HI\\ o., \"1 OML r ---- ~~ @ u'V-~O\\ _ _ 5(16Cf\\'tb,b6)~ ~ ilb ~ (VI G) . 1,_t,~~1~i HafD..,_ ~~fi~niab~Ol~111Y) ~ 1'JVol \\:hP04 x 0.1mcJ' N~H x 8 ML ~ s ,'( 10-4 Y11.e>I 1ct)? ML 1 Y\\1101 NotOtl @. ;~~~\\I~ \\\\fOA- i~e~ ( OJ M '\\Q..._Ml._) . ------- • ,i --=- 0.:1 'r\"\\o\\ >< 10 ~ -:,. 1 \" 10~~ l}VlO 1c,i:o rvtL ~3PC'4 ~b~~ -- @) ~ 'U,~Ul '&-1~ l1 } 10-> - S 7-10-,i M O ___ to ~.10'=- s -,,.1 o\\ _s ~ 1G-~_1
@. ~'if\\,\\~~~ Net.\"-i ft)4 ~\\i#f~ = ~ No\\ Na.~ .)~4 i. 0.1M>I NoU>\\-\\ )( 5ML :: 8 \")( 10&Mu/ , N:,I NQ.O ti 100° l\"\\l • -- G) y\\1 ~ rKct - 103 ~ -- ~1,{)0d] - - ---- ~ = v\"°- - \\oj'\\ ~ - l~ (6-92- i- t<f\\ _ ::: ~\\D<j 1D - le~ b_q2,. ..... \" - 0-'64 pH ,:. 2-1~ wP.. e,~~COOH + Ncx.OH ~ JUJCY>J()., -4- 1-1.p ~-'\\ ~ 11.0ML o., rt1 ~ 13:b~\\4,r~h;.tf/ t OY-'L , - - -~1§~~~1tl ~) ~ - C\\-\\-'3ctJoNo., ➔ D-\\3COO- -le Ncx.i G) ( ) \\3 ooo' +\\-\\zO.~ 1~.1l \\1'6c\\~\"D\\0\\i\\-1 /~o+i) ~o\\l,toi 6\\ cM ~ COONa-. __ =- j Y'r'IO\\ CH'i CO-otJa :,< 0.1 ~\\ CB./oo H x 1C> wtl ~ llt0I CH OCooti tOCO Mt
® LCH_/-00] ~ 1)(.1CJ3 tv10I --i< 100◊ ~ ro lvll ~ c.5 x 1ci-2. M - 1L ct--1-3 coo- -t-tl va ~ G\\tCOOtJ + otf 5 i< lO- '- [ oHJ j\"\"' 8 X 16¼5Sb l<-l0- 10 ~ S..3 X 10-b M . @ ro\\4 ~ - lc3C,.21(10~ = ~lo~ 1o - \\o~~ __ ~ 6 - 0.12.A \"\" 5.'l7 lo p~ ~ 14 - 8 .1liTo = ~.11..4 bo-se .t O'\\a~\"ri~'JJ \"°1~1oJ v·h~6\\ · '\\.l<it'1 bi l CH j COOH 1CJ1~cfoN;_ - b~p-l tbO+ C1,1_3COo- -t H0 0+~ .C4.-3CD0 H t ~2,0 _ - b°'ai O~- __ _ 2.1 \\,Cl t Ncx.OH =-'?' 1J~J~i•h~oJ -\\_, $~Y'OVI; .- - -t1 ...-i g.1.. No,.,r\\CC\\ 9~ M N~2,OO, NoJ\\ CO, f\\J01 C,OJ -~ ➔ Ne:!- 4: t-\\CO, i,~ HCO~ / Co, - -t- Q.?, e,\\-\\ 3C.,00 No, ,\\\"~ 0~/~,00t\\ cM3coo\\1 / Ct\\ 3CCO-
·2 l\\ \\-'SJ~ ~ +- ~'\"'\"\"l~ d No.~2 Pod ~ No..t + \" l.rol1- ~~~.t I ~; VO4 05 t'< o SM I- J . N\"A C\\ I NH~ Nt\\: ~ \\\\1-0 ~ ~3ot- 4 NH3 p\\-\\- ~ yK~ - \\°J [NHj [Nt\\3] @ [~\":) ~ lN\\\\Jl f'1 ~ vK~- \\~1 p\\-\\ .. fK~ - ~ - \\oj ( S .5'- )( -10 10 > -:. 10\\03 iO - 103 5.5~ ~ tO - 0 .'74S ~ 9.255 ® l~~] > lt-J\\\\~1 l~ft~, 1M pH :. P~~ - c pK~ - o.3o1 pt\\ ~ fKet or\\4 \"' ~ '2.S'S - 0 .301 ~ ~ -'l 5.a pw @ [NI-/;] < [ ~~.,J . 1fH = fK.._i~ lo~~ ?l Uo9 1 - la,J z_) -- 0\\ ~s + o.2101 pt\\ '.: ~-55i [r1 > p\\((!_ I
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