اﻟﻐﺎزات Gases اﻟﻔﻜﺮة اﻟﻌﺎﻣﺔ ﺗﺴـﺘﺠﻴﺐ ﺍﻟﻐـﺎﺯﺍﺕ ﻟﺘﻐﲑﺍﺕ ﻛﻞ ﻣـﻦ ﺍﻟﻀﻐـﻂ ﻭﺩﺭﺟﺔ ﺍﳊـﺮﺍﺭﺓ ﻭﺍﳊﺠﻢ ﻭﻋﺪﺩ ﺍﳉﺴﻴﲈﺕ ﺑﻄﺮﺍﺋﻖ ﻳﻤﻜﻦ ﺍﻟﺘﻨﺒﺆ ﲠﺎ. 7-1ﻗﻮاﻧﻴﻦ اﻟﻐﺎزات اﻟﻔﻜﺮة اﻟﺮﺋﻴﺴﺔ ﺇﺫﺍ ﺗﻐﲑ ﺿﻐﻂ ﺃﻱ ﻛﻤﻴﺔ ﺛﺎﺑﺘﺔ ﻣﻦ ﻏﺎﺯ ﺃﻭ ﺩﺭﺟﺔ ﺣﺮﺍﺭﲥﺎ ﺃﻭ ﺣﺠﻤﻬﺎ ،ﻓﺴﻴﺘﺄﺛﺮ ﺍﳌﺘﻐﲑﺍﻥ ﺍﻵﺧﺮﺍﻥ. 7-2ﻗﺎﻧﻮن اﻟﻐﺎز اﻟﻤﺜﺎﻟﻲ اﻟﻔﻜﺮة اﻟﺮﺋﻴﺴﺔ ﻳﺮﺑﻂ ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ ﻋﺪﺩ ﺍﳉﺴﻴﲈﺕ ﻣﻊ ﻛﻞ ﻣﻦ ﺍﻟﻀﻐﻂ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻭﺍﳊﺠﻢ. 7-3اﻟﺤﺴﺎﺑﺎت اﻟﻤﺘﻌﻠﻘﺔ ﺑﺎﻟﻐﺎزات اﻟﻔﻜﺮة اﻟﺮﺋﻴﺴﺔ ﻋﻨﺪﻣﺎ ﺗﺘﻔﺎﻋﻞ ﺍﻟﻐﺎﺯﺍﺕ ﻓﺈﻥ ﺍﳌﻌﺎﻣﻼﺕ ﰲ ﺍﳌﻌﺎﺩﻻﺕ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ ﺍﳌﻮﺯﻭﻧﺔ ﺍﻟﺘﻲ ﲤﺜﻞ ﻫﺬﻩ ﺍﻟﺘﻔﺎﻋﻼﺕ ﺗﺸﲑ ﺇﱃ ﺃﻋﺪﺍﺩ ﺍﳌﻮﻻﺕ ﻭﺍﳊﺠﻮﻡ ﺍﻟﻨﺴﺒﻴﺔ ﻟﻠﻐﺎﺯﺍﺕ. ﺣﻘﺎﺋﻖ ﻛﻴﻤﻴﺎﺋﻴﺔ ﺩﺭﺟـﺔ ﺣـﺮﺍﺭﺓ ﺍﳍـﻮﺍﺀ ﰲ ﺍﳌﻨﻄـﺎﺩ ﻛﺎﻓﻴـﺔ ﻟﻐﲇ • ﺍﳌﺎﺀ. • ﺍﺳﺘﺨﺪﻡ ﺍﻟﻌﺎﱂ ﺟﻮﺯﻳﻒ ﺟﺎﻱ -ﻟﻮﺳﺎﻙ ﰲ • ﺍﻟﻘﺮﻥ ﺍﻟﺘﺎﺳﻊ ﻋﺸـﺮ ﻣﻨﻄﺎﺩ ﺍﳍﻮﺍﺀ ﺍﻟﺴﺎﺧﻦ ﰲ ﺃﺑﺤﺎﺛﻪ ﻭﲡﺎﺭﺑﻪ ،ﰲ ﺣﲔ ﺍﺳﺘﺨﺪﻡ ﺍﻟﻌﺎﱂ ﺟﺎﻙ ﺷﺎﺭﻝ ﻣﻨﻄﺎﺩ ﺍﳍﻴﺪﺭﻭﺟﲔ ﰲ ﲡﺎﺭﺑﻪ. ﳛﺘﻮﻱ ﻣﻨﻄﺎﺩ ﺍﳍﻮﺍﺀ ﺍﻟﺴﺎﺧﻦ ﰲ ﺍﳌﺘﻮﺳﻂ ﻋﲆ 2.5ﻣﻠﻴﻮﻥ ﻟﱰ ﻣﻦ ﺍﻟﻐﺎﺯ. 88
ﺍﻋـﻤـﻞ ﺍﳌﻄﻮﻳـﺎﺕ ﺍﻵﺗﻴﺔ ﻟﺘﺴـﺎﻋﺪﻙ ﻋـﲆ ﺗﻨﻈﻴـﻢ ﺩﺭﺍﺳـﺔ ﻗﻮﺍﻧﲔ ﺗﻌﻤﻞ ﺷﻌﻠﺔ ﺍﳌﻨﻄﺎﺩ ـ ﺍﻧﻈﺮ ﺍﻟﺼﻔﺤﺔ ﺍﻟﻴﻤﻨﻰ ـ ﻋﲆ ﺭﻓﻊ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ﺍﳍﻮﺍﺀ ﺩﺍﺧﻠﻪ ﻟﻴﺒﻘﻰ ﰲ ﺍﳍﻮﺍﺀ. ﺍﻟﻐﺎﺯ. 1 ﺃﺣــﴬ ﺛﻼﺙ ﻭﺭﻗﺎﺕ ،ﻭﺿﻊ ﺑﻌﻀﻬﺎ ﻓﻮﻕ ﺑﻌﺾ ،ﻭﺩﻉ ﺣﻮﺍﻓﻬﺎ ﺍﻟﻌﻠﻴﺎ ﻣﺘﺒﺎﻋﺪﺓ ﺭﺃﺳ ﹰﹼﻴﺎ ﺑﻤﻘﺪﺍﺭ 2 cm 2 ﺍﺛﻦ ﺍﻷﻃﺮﺍﻑ ﺍﻟﺴﻔﻠﻴﺔ ﻟـــﻸﻭﺭﺍﻕ ﻋﲆ ﺃﻥ ﺗﻜ ﹼﻮﻥ ﲬﺲ ﻃﻴﺎﺕ N.P1ﺍﻗﺮOﺃ MﺗﻌﻠﻴNLﲈﺕ ﺍﻟKMﺴﻼﻣPLﺔJﰲ ﺍﳌIKOﺨﺘﱪDFJ EGK FHL GIM HJN. .2ﺍﻧﻔﺦ ﺑﺎﻟﻮ ﹰﻧﺎ ﺛﻢ ﺍﺭﺑﻄﻪ. ﻣﺘﺴﺎﻭﻳﺔ .ﺛﻢ ﺍﺿﻐﻂ ﻋﲆ .3ﺍﺳﻜﺐ ﻣﺎ ﹰﺀ ﺑﺎﺭ ﹰﺩﺍ ﰲ ﺩﻟﻮ ﺇﱃ ﻣﻨﺘﺼﻔﻪ ،ﺛﻢ ﺃﺿﻒ ﺇﻟﻴﻪ ﻗﻄﻊ ﻣﻦ ﺍﻟﺜﻠﺞ. ﺍﻟﺜﻨﻴﺎﺕ ﻟﺘﺜﺒﻴﺘﻬﺎ ﰲ ﺃﻣﺎﻛﻨﻬﺎ. .4ﺍﺳﺘﺨﺪﻡ ﺧﻴ ﹰﻄﺎ ﻟﻘﻴﺎﺱ ﳏﻴﻂ ﺍﻟﺒﺎﻟﻮﻥ. AB 3BFACG BDH CE IﺛﺒAEﺖ ﺍﳌDﻄﻮﻳﺔC، .5ﺣﺮﻙ ﺍﳌﺎﺀ ﻭﺍﻟﺜﻠﺞ ﰲ ﺍﻟﺪﻟﻮ ﺟﻴ ﹰﺪﺍ ،ﺣﺘﻰ ﺗﺜﺒﺖ ﺩﺭﺟﺔ O P ﺣﺮﺍﺭﺗﻪ ،ﺛﻢ ﺍﻏﻤﺮ ﺍﻟﺒﺎﻟﻮﻥ ﰲ ﺍﳌﺎﺀ ﻭﺍﻟﺜﻠﺞ ﻣﺪﺓ 15ﺩﻗﻴﻘﺔ. ﻛﲈ ﰲ ﺍﻟﺸﻜﻞ ،ﻭﻋﻨﻮﻥ ﺍﻟﻄﻴﺎﺕ ﻋﲆ ﺍﻟﻨﺤﻮ ﺍﻵﰐ: .6ﺃﺧﺮﺝ ﺍﻟﺒﺎﻟﻮﻥ ﻣﻦ ﺍﳌﺎﺀ ،ﺛﻢ ﻗﺲ ﳏﻴﻄﻪ. ﻗـﻮﺍﻧـﲔ ﺍﻟــﻐــﺎﺯ ،ﺑﻮﻳﻞ، ﺷﺎﺭﻝ ،ﺟﺎﻱ-ﻟﻮﺳﺎﻙ ،ﺍﻟﻘﺎﻧﻮﻥ ﺍﻟﻌﺎﻡ ،ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ.اﻟﻤﻄﻮﻳﺎت 7-2 7-1 ﳋﺺ ﻗﻮﺍﻧﲔ ﺍﻟﻐﺎﺯﺍﺕ ﺑﻜﻠﲈﺗﻚ ﺍﳋﺎﺻﺔ. .1ﺻﻒ ﻣﺎ ﺣﺪﺙ ﳊﺠﻢ ﺍﻟﺒﺎﻟﻮﻥ ﻋﻨﺪﻣﺎ ﺍﻧﺨﻔﻀﺖ ﺩﺭﺟﺔﳌﺮﺍﺟﻌﺔ ﳏﺘﻮ ﻫﺬﺍ ﺍﻟﻔﺼﻞ ﻭﻧﺸـﺎﻃﺎﺗﻪ ﺍﺭﺟﻊ ﺇﱃ ﺣﺮﺍﺭﺗﻪ. ﺍﳌﻮﻗﻊ: .2ﺗﻮﻗﻊ ﻣﺎ ﳛﺪﺙ ﳊﺠﻢ ﺍﻟﺒﺎﻟﻮﻥ ﻟﻮ ﻛﺎﻥ ﺍﻟﺪﻟﻮ ﳛﺘﻮﻱ ﻣﺎ ﹰﺀ www.obeikaneducation.com ﺳﺎﺧ ﹰﻨﺎ. ﻣﺎﺫﺍ ﳛﺪﺙ ﺇﺫﺍ ﻣﻸﺕ ﺍﻟﺒﺎﻟﻮﻥ ﺑﺎﳍﻴﻠﻴﻮﻡ ﺑﺪ ﹰﻻ ﻣﻦ ﺍﳍﻮﺍﺀ ،ﻭﺃﺟﺮﻳﺖ ﺍﻟﺘﺠﺮﺑﺔ ﻣﺮﺓ ﺃﺧﺮ؟89
7-1 اﻟﻔﻜﺮة اﻟﺮﺋﻴﺴﺔ The Gas Laws ﻗﻮاﻧﻴﻦ اﻟﻐﺎزات ا ﻫﺪاف ﺍﻟﻌﻼﻗﺔ ﺑﲔ ﺍﻟﻀﻐﻂ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻭﺍﳊﺠﻢ ﳌﻘﺪﺍﺭ ﺛﺎﺑﺖ ﻣﻦ ﺍﻟﻐﺎﺯ. ﻗـﻮﺍﻧـﲔ ﺍﻟـﻐـﺎﺯ ﻋﲆ ﻣﺎﺫﺍ ﳛﺪﺙ ﻟﻐـﺎﺯ ﰲ ﺑﺎﻟـﻮﻥ ﺇﺫﺍ ﻗ ﹼﻠﻠﺖ ﺣﺠﻤﻪ ﺑﺎﻟﻀﻐﻂ ﻋﻠﻴﻪ؟ ﺳﺘﺸـﻌﺮ ﺍﳌﺴﺎﺋﻞ ﺍﻟﺘﻲ ﺗﺘﻀﻤﻦ ﺍﻟﻀﻐﻂ ﺑﺰﻳﺎﺩﺓ ﰲ ﺍﳌﻘﺎﻭﻣﺔ ،ﻭﻗﺪ ﺗﺸﺎﻫﺪ ﺍﻧﺘﻔﺎ ﹰﺧﺎ ﰲ ﺟﺰﺀ ﻣﻦ ﺍﻟﺒﺎﻟﻮﻥ. ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻭﺍﳊﺠﻢ ﳌﻘﺪﺍﺭ ﻗﺎﻧﻮن ﺑﻮﻳﻞ Boyle’s Law ﺿﻐـﻂ ﺍﻟﻐﺎﺯ ﻭﺣﺠﻤـﻪ ﻣﱰﺍﺑﻄـﺎﻥ .ﻭﻗﺪ ﻭﺻﻒ ﺍﻟﻌـﺎﱂ ﺍﻷﻳﺮﻟﻨـﺪﻱ ﺭﻭﺑﺮﺕ ﺑﻮﻳـﻞ )1627- ﳏ ﹼﺪﺩ ﻣﻦ ﺍﻟﻐﺎﺯ. (1691ﻫﺬﻩ ﺍﻟﻌﻼﻗﺔ. ﻣﺮاﺟﻌﺔ اﻟﻤﻔﺮدات ﻳﺼﻒ ﻋﻼﻗ ﹰﺔ ﻟﻘﺪ ﺻ ﹼﻤﻢ ﺑﻮﻳﻞ ﲡﺮﺑﺔ ﻛﺎﳌﺒﻴﻨﺔ ﰲ ﺍﻟﺸﻜﻞ ،7-1ﻭﻭ ﹼﺿﺢ ﰲ ﺍﻟﻄﺒﻴﻌﺔ ﺗﺪﻋﻤﻬﺎ ﻋﺪﺓ ﲡﺎﺭﺏ .ﻣﻦ ﺧﻼﳍﺎ ﺃﻧﻪ ﺇﺫﺍ ﻛﺎﻧﺖ ﻛﻤﻴﺔ ﺍﻟﻐﺎﺯ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺛﺎﺑﺘﺘﲔ ﻓﺈﻥ ﻣﻀﺎﻋﻔﺔ ﺍﻟﻀﻐﻂ ﺍﻟﻮﺍﻗﻊ ﻋﲆ ﺍﻟﻐـﺎﺯ ﻳﻘﻠﻞ ﻣﻦ ﺣﺠﻤﻪ ﺇﱃ ﺍﻟﻨﺼﻒ .ﻭﻣﻦ ﻧﺎﺣﻴﺔ ﺃﺧـﺮ ﻓﺈﻥ ﺗﻘﻠﻴﻞ ﺍﻟﻀﻐﻂ ﺍﻟﻮﺍﻗﻊ ﻋﲆ ﺍﻟﻐﺎﺯ اﻟﻤﻔﺮدات اﻟﺠﺪﻳﺪة ﺇﱃ ﺍﻟﻨﺼـﻒ ﻳﻀﺎﻋﻒ ﺣﺠﻢ ﺍﻟﻐﺎﺯ .ﻭﺗﻌ ﹶﺮﻑ ﺍﻟﻌﻼﻗﺔ ﺍﻟﺘﻲ ﻳﺰﻳﺪ ﻓﻴﻬﺎ ﺃﺣﺪ ﺍﳌﺘﻐﲑﻳﻦ ﻋﻨﺪﻣﺎ ﻳﻘﻞ ﻗﺎﻧﻮﻥ ﺑﻮﻳﻞ ﺍﻵﺧﺮ ﺑﻌﻼﻗﺔ ﺍﻟﺘﻨﺎﺳﺐ ﺍﻟﻌﻜﴘ. ﻗﺎﻧﻮﻥ ﺷﺎﺭﻝ ﺍﻟﺼﻔﺮ ﺍﳌﻄﻠﻖ ﻳﻨﺺ ﻗﺎﻧﻮﻥ ﺑﻮﻳﻞ ﻋﲆ ﺃﻥ ﺣﺠﻢ ﻣﻘﺪﺍﺭ ﳏ ﹼﺪﺩ ﻣﻦ ﺍﻟﻐﺎﺯ ﻳﺘﻨﺎﺳﺐ ﻋﻜﺴ ﹼﹰﻴﺎ ﻣﻊ ﺍﻟﻀﻐﻂ ﺍﻟﻮﺍﻗﻊ ﻗﺎﻧﻮﻥ ﺟﺎﻱ -ﻟﻮﺳﺎﻙ ﻋﻠﻴﻪ ﻋﻨﺪ ﺛﺒﻮﺕ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺗﻪ .ﻳﺒﲔ ﺍﻟﺸﻜﻞ 7-1ﺍﻟﻌﻼﻗﺔ ﺑﲔ ﺍﻟﻀﻐﻂ ﻭﺍﳊﺠﻢ ،ﺣﻴﺚ ﺍﻟﻘﺎﻧﻮﻥ ﺍﻟﻌﺎﻡ ﻟﻠﻐﺎﺯﺍﺕ ﻳﻮﺿﺢ ﺍﻟﺸﻜﻞ ﺍﻟﻌﻼﻗﺔ ﺍﻟﻌﻜﺴﻴﺔ ﺑﲔ ﺍﻟﻀﻐﻂ ﻭﺍﳊﺠﻢ ﰲ ﺍﳌﻨﺤﻨﻰ ﺍﳌ ﹼﺘﺠﻪ ﺇﱃ ﺃﺳﻔﻞ . 7-1 25°C )10 (1.0 atm, 10 L 8 L L )6 (2.0 atm, 5 L 10 L 25°C 25°C 25°C 10 4 1 atm 8 6 4 atm 2 )(4.0 atm, 2.5 L 4 2)3 = (4 atm)(2.5 L 0 2 atm 0 = 10 atm · L 0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 5 L 4 atm 0 0.5 = atm 2.5 L ﺍﺳﺘﺨﺪﻡ ﺍﻟﺮﺳﻢ ﻟﺘﺤﺪﻳﺪ ﺍﳊﺠﻢ ،ﺇﺫﺍ )P1V1 = (1 atm)(10 L )P2V2 = (2 atm)(5 L )P3V3 = (4 atm)(2.5 L = 10 atm · L = 10 atm · L = 10 atm · L ﻛﺎﻥ ﻣﻘﺪﺍﺭ ﺍﻟﻀﻐﻂ ).(2.5atm = = = 14-03C-828378-08.ai 90
ﻻﺣﻆ ﺃﻥ ﻧﺎﺗﺞ ﴐﺏ ﺍﻟﻀﻐﻂ ﰲ ﺍﳊﺠﻢ ﻋﻨﺪ ﻛﻞ ﻧﻘﻄﺔ ﰲ ﺍﻟﺸﻜﻞ 7-1ﻳﺴﺎﻭﻱ 10 atm.L ﻟﺬﺍ ﻳﻤﻜﻦ ﺍﻟﺘﻌﺒﲑ ﻋﻦ ﻗﺎﻧﻮﻥ ﺑﻮﻳﻞ ﺭﻳﺎﺿ ﹼﹰﻴﺎ ﻋﲆ ﺍﻟﻨﺤﻮ ﺍﻵﰐ: ﻗﺎﻧﻮﻥ ﺑﻮﻳﻞ : V :P P1V1 = P2V2ﺣﺎﺻﻞ ﴐﺏ ﺿﻐﻂ ﻛﻤﻴﺔ ﳏﺪﺩﺓ ﻣﻦ ﺍﻟﻐﺎﺯ ﰲ ﺣﺠﻤﻬﺎ ﻋﻨﺪ ﺛﺒﻮﺕ ﺩﺭﺟﺔ ﺣﺮﺍﺭﲥﺎ ﻳﺴﺎﻭﻱ ﻛﻤﻴﺔ ﺛﺎﺑﺘﺔ.ﻳﻤﺜﻞ ﻛﻞ ﻣﻦ P1ﻭ V1ﺍﻟﻀﻐﻂ ﻭﺍﳊﺠﻢ ﺍﻻﺑﺘﺪﺍﺋﻴﲔ ،ﰲ ﺣﲔ ﻳﻤﺜﻞ ﻛﻞ ﻣﻦ P2ﻭ V2ﺍﻟﻀﻐﻂ ﻭﺍﳊﺠﻢﺍﳉﺪﻳﺪﻳﻦ ،ﻓﺈﺫﺍ ﻋﻠﻤﺖ ﺛﻼﺛﺔ ﻣﻦ ﺍﳌﺘﻐﲑﺍﺕ ﺍﳌﻮﺟﻮﺩﺓ ﰲ ﺍﳌﻌﺎﺩﻟﺔ ﺃﻣﻜﻨﻚ ﻣﻌﺮﻓﺔ ﻗﻴﻤﺔ ﺍﳌﺘﻐﲑ ﺍﻟﺮﺍﺑﻊ. 71 ﻳﻨﻔﺦ ﻏﻮﺍﺹ ﻭﻫﻮ ﻋﲆ ﻋﻤﻖ 10mﲢﺖ ﺍﳌﺎﺀ ﻓﻘﺎﻋﺔ ﻫﻮﺍﺀ ﺣﺠﻤﻬﺎ ،0.75 Lﻭﻋﻨﺪﻣﺎ ﺍﺭﺗﻔﻌﺖ ﻓﻘﺎﻋﺔ ﺍﳍﻮﺍﺀ ﺇﱃ ﺍﻟﺴﻄﺢ ﺗﻐﲑ ﺿﻐﻄﻬﺎ ﻣﻦ 2.25 atmﺇﱃ ، 1.03 atmﻣﺎ ﺣﺠﻢ ﻓﻘﺎﻋﺔ ﺍﳍﻮﺍﺀ ﻋﻨﺪ ﺍﻟﺴﻄﺢ؟ 1ﺗﺤﻠﻴﻞ اﻟﻤﺴﺄﻟﺔﺑﺎﻻﻋﺘﲈﺩ ﻋﲆ ﻗﺎﻧﻮﻥ ﺑﻮﻳﻞ ،ﺑﻨﻘﺼﺎﻥ ﺍﻟﻀﻐﻂ ﻋﲆ ﻓﻘﺎﻋﺔ ﺍﳍﻮﺍﺀ ﻳﺰﺩﺍﺩ ﺣﺠﻤﻬﺎ ،ﻟﺬﺍ ﳚﺐ ﴐﺏ ﺍﳊﺠﻢ ﺍﻻﺑﺘﺪﺍﺋﻲ ﳍﺎ ﰲ ﻧﺴﺒﺔ ﺿﻐﻂ ﺃﻛﱪ ﻣﻦ .1 V2 = ? L V1 = 0.75 L P1 = 2.25 atm P2 = 1.03 atm 2ﺣﺴﺎب اﻟﻤﻄﻠﻮب ﺍﺳﺘﺨﺪﻡ ﻗﺎﻧﻮﻥ ﺑﻮﻳﻞ ﻹﳚﺎﺩ ﻗﻴﻤﺔ V2ﻭﺍﺣﺴﺐ ﺍﳊﺠﻢ ﺍﳉﺪﻳﺪ.P1V1 = P2V2 ( )V2 = V1 _P1 P2( )V2 = 0.75 L 2_.25 atm v10.75LP12.25atmP21.03atm 1.03 atm( )V2 = 0.75 L2_.25 atm = 1.6 L 1.03 atm 3ﺗﻘﻮﻳﻢ ا ﺟﺎﺑﺔ ﻗﻞ ﺍﻟﻀﻐﻂ ﺑﻤﻘﺪﺍﺭ ﺍﻟﻨﺼﻒ ﺗﻘﺮﻳ ﹰﺒﺎ ،ﻟﺬﺍ ﻓﺈﻥ ﺍﳊﺠﻢ ﺳﻴﺰﻳﺪ ﺇﱃ ﺍﻟﻀﻌﻒ ،ﻭﻳﻌﱪ ﻋﻦ ﺍﻹﺟﺎﺑﺔ ﺑﻮﺣﺪﺓ ﺍﻟﻠﱰ ،ﻭﻫﻲ ﻭﺣﺪﺓ ﻗﻴﺎﺱ ﺍﳊﺠﻢ ،ﻭﲢﺘﻮﻱ ﺍﻹﺟﺎﺑﺔ ﻋﲆ ﺭﻗﻤﲔ ﻣﻌﻨﻮﻳﲔ ،ﻭﻫﺬﺍ ﺻﺤﻴﺢ. ﺍﻓﱰﺽ ﺃﻥ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻭﻛﻤﻴﺔ ﺍﻟﻐﺎﺯ ﺛﺎﺑﺘﺎﻥ ﰲ ﺍﳌﺴﺎﺋﻞ ﺍﻵﺗﻴﺔ : .1ﺇﺫﺍ ﻛﺎﻥ ﺣﺠﻢ ﻏﺎﺯ ﻋﻨﺪ ﺿﻐﻂ 99.0 kPaﻫﻮ ، 300.0 mlﻭﺃﺻﺒﺢ ﺍﻟﻀﻐﻂ 188 kPaﻓﲈ ﺍﳊﺠﻢ ﺍﳉﺪﻳﺪ؟ .2ﺇﺫﺍ ﻛﺎﻥ ﺿﻐﻂ ﻋﻴﻨﺔ ﻣﻦ ﻏﺎﺯ ﺍﳍﻴﻠﻴﻮﻡ ﰲ ﺇﻧﺎﺀ ﺣﺠﻤﻪ 1.00 Lﻫﻮ 0.988 atmﻓﲈ ﻣﻘﺪﺍﺭ ﺿﻐﻂ ﻫﺬﻩ ﺍﻟﻌﻴﻨﺔ ﺇﺫﺍ ﹸﻧﻘﻠﺖ ﺇﱃ ﻭﻋﺎﺀ ﺣﺠﻤﻪ 2.00 L؟ .3ﺇﺫﺍ ﻛﺎﻥ ﻣﻘﺪﺍﺭ ﺣﺠﻢ ﻏﺎﺯ ﳏﺼﻮﺭ ﲢﺖ ﻣﻜﺒﺲ ﺃﺳﻄﻮﺍﻧﺔ ،145.7 Lﻭﺿﻐﻄﻪ ،1.08 atmﻓﲈ ﺣﺠﻤﻪ ﺍﳉﺪﻳﺪ ﻋﻨﺪﻣﺎ ﻳﺰﺩﺍﺩ ﺍﻟﻀﻐﻂ ﺑﻤﻘﺪﺍﺭ 25%؟91
ﻗﺎﻧﻮن ﺷﺎرل Charles’s Lawﻻﺣﻈﺖ ﰲ ﺍﻟﺘﺠﺮﺑﺔ ﺍﻻﺳﺘﻬﻼﻟﻴﺔ ﺃﻥ ﳏﻴﻂ ﺍﻟﺒﺎﻟﻮﻥ ﻗﺪ ﻗﻞ ﺑﻌﺪ ﻏﻤﺮﻩ ﰲ ﺍﳌﺎﺀ ﻭﺍﻟﺜ ﹺﻠﺞ .ﳌﺎﺫﺍ ﺣﺪﺙ ﺫﻟﻚ؟ﻛﲈ ﺃﻧﻚ ﺗﻼﺣﻆ ﺃ ﹼﻥ ﻛﺮﺓ ﺍﻟﻘﺪﻡ ﺗﻈﻬﺮ ﻏﲑ ﻣﻨﺘﻔﺨﺔ ﺟﻴ ﹰﺪﺍ ﺇﺫﺍ ﺗﺮﻛﺘﻬﺎ ﰲ ﻣﻜﺎﻥ ﺑﺎﺭﺩ ﻓﱰﺓ ﻣﻦ ﺍﻟﻮﻗﺖ ،ﰲﺣﲔ ﺗﺮﺍﻫﺎ ﻣﻨﺘﻔﺨﺔ ﺟﻴ ﹰﺪﺍ ﺇﺫﺍ ﺗﺮﻛﺖ ﰲ ﻣﻜﺎﻥ ﻣﺸﻤﺲ .ﻓﻠﲈﺫﺍ ﳜﺘﻠﻒ ﻣﻈﻬﺮ ﺍﻟﻜﺮﺓ؟ ﻳﻤﻜﻦ ﺍﻹﺟﺎﺑﺔ ﻋﻦ ﻫﺬﻩ ﺍﻷﺳﺌﻠﺔ ﻣﻦ ﺧﻼﻝ ﺗﻄﺒﻴﻖ ﻗﺎﻧﻮﻥ ﺷﺎﺭﻝ. ﺩﺭﺱ ﺟﺎﻙ ﺷﺎﺭﻝ ) (1746-1823ﺍﻟﻔﻴﺰﻳﺎﺋﻲ ﺍﻟﻔﺮﻧﴘﺍﻟﻌﻼﻗﺔ ﺑﲔ ﺍﳊﺠﻢ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ،ﺣﻴﺚ ﻻﺣﻆ ﺃﻥ ﻛ ﹼﹰﻼ ﻣﻦ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ﻭﺣﺠﻢ ﻋﻴﻨﺔ ﻣﻦ ﺍﻟﻐﺎﺯ ﻳﺰﺩﺍﺩﻋﻨﺪﻣﺎ ﻳﺒﻘﻰ ﻛﻞ ﻣﻦ ﻣﻘﺪﺍﺭ ﺍﻟﻌﻴﻨﺔ ﻭﺍﻟﻀﻐﻂ ﺛﺎﺑﺘﲔ .ﻳﻤﻜﻦ ﺗﻔﺴﲑ ﻫﺬﻩ ﺍﳋﺎﺻﻴﺔ ﺑﻨﺎ ﹰﺀ ﻋﲆ ﻧﻈﺮﻳﺔ ﺍﳊﺮﻛﺔﺍﳉﺰﻳﺌﻴﺔ :ﻓﻌﻨﺪﻣﺎ ﺗﺰﺩﺍﺩ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺗﺘﺤﺮﻙ ﺟﺴﻴﲈﺕ ﺍﻟﻐﺎﺯ ﻭﺗﺼﻄﺪﻡ ﺃﴎﻉ ﺑﺠﺪﺍﺭ ﺍﻹﻧﺎﺀ ﺍﻟﺬﻱ ﺗﻮﺟﺪﻓﻴﻪ ﻭﺑﻘﻮﺓ ﺃﻛﱪ .ﻭﻷﻥ ﺍﻟﻀﻐﻂ ﻳﻌﺘﻤﺪ ﻋﲆ ﻋﺪﺩ ﻭﻗﻮﺓ ﺍﺻﻄﺪﺍﻣﺎﺕ ﺟﺴﻴﲈﺕ ﺍﻟﻐﺎﺯ ﺑﺠﺪﺍﺭ ﺍﻹﻧﺎﺀ ﻓﺈﻥ ﻫﺬﺍﻳﺆﺩﻱ ﺇﱃ ﺯﻳﺎﺩﺓ ﺍﻟﻀﻐﻂ ،ﻭﺣﺘﻰ ﻳﺒﻘﻰ ﺍﻟﻀﻐﻂ ﺛﺎﺑ ﹰﺘﺎ ﻻ ﺑﺪ ﺃﻥ ﻳﺰﻳﺪ ﺍﳊﺠﻢ؛ ﺇﺫ ﲢﺘﺎﺝ ﺍﳉﺴﻴﲈﺕ ﺇﱃ ﺍﻻﻧﺘﻘﺎﻝ ﺇﱃ ﻣﺴﺎﻓﺎﺕ ﺃﺑﻌﺪ ﻗﺒﻞ ﺃﻥ ﺗﺼﻄﺪﻡ ﺑﺎﳉﺪﺍﺭ ،ﳑﺎ ﻳﻘﻠﻞ ﻣﻦ ﻋﺪﺩ ﺍﺻﻄﺪﺍﻣﺎﺕ ﺍﳉﺴﻴﲈﺕ ﺑﺠﺪﺍﺭ ﺍﻹﻧﺎﺀ. ﺗﻮﺿﺢ ﺍﻷﺳﻄﻮﺍﻧﺎﺕ ﰲ ﺍﻟﺸﻜﻞ 7-2ﻛﻴﻒ ﻳﺘﻐﲑ ﺣﺠﻢ ﻣﻘﺪﺍﺭ ﳏﺪﺩ ﻣﻦ ﺍﻟﻐﺎﺯ ﺑﺘﺴﺨﻴﻨﻪ. ﻣﺨﺘﺒﺮ ﺣﻞ اﻟﻤﺸﻜﻼت .1ﻃ ﹼﺒﻖ ﻗﺎﻧﻮﻥ ﺑﻮﻳﻞ ﻟﺘﻔﺴﲑ ﺍﻟﺴﺒﺐ ﺍﻟﺬﻱ ﳚﻌﻞ ﺍﳍﻮﺍﺀ ﺗﻄﺒﻴﻖ اﻟﺘﻔﺴﻴﺮات اﻟﻌﻠﻤﻴﺔﻳﺪﺧﻞ ﺇﱃ ﺍﻟﺮﺋﺘﲔ ﻋﻨﺪ ﺍﻟﺸﻬﻴﻖ ﻭﳜﺮﺝ ﻣﻨﻬﲈ ﻋﻨﺪ ﺃﻧﺖ ﺗﺘﻨﻔﺲ 20 ﺍﻟﺰﻓﲑ. ﻣﺮﺓ ﰲ ﺍﻟﺪﻗﻴﻘﺔ ،ﻭﺗﺴﺘﺒﺪﻝ ﺑﻐﺎﺯ ﺛﺎﲏ ﺃﻛﺴﻴﺪ ﺍﻟﻜﺮﺑﻮﻥ ﻏﺎ ﹶﺯ .2ﻭ ﹼﺿﺢ ﻣﺎ ﳛﺪﺙ ﺩﺍﺧﻞ ﺍﻟﺮﺋﺘﲔ ﻋﻨﺪﻣﺎ ﻳﺘﻌﺮﺽ ﺍﻷﻛﺴﺠﲔ ﻟﺘﺤﺎﻓﻆ ﻋﲆ ﺣﻴﺎﺗﻚ .ﻓﻜﻴﻒ ﻳﺘﻐﲑ ﺍﻟﻀﻐﻂﺍﻹﻧﺴﺎﻥ ﻟﴬﺑﺔ ﻋﲆ ﺍﻟﺒﻄﻦ ،ﻭﳜﺮﺝ ﺍﳍﻮﺍﺀ ﻣﻨﻪ. ﻭﺍﳊﺠﻢ ﰲ ﺭﺋﺘﻴﻚ ﰲ ﺃﺛﻨﺎﺀ ﺗﻨﻔﺴﻚ؟ ﺍﺳﺘﺨﺪﻡ ﻗﺎﻧﻮﻥ ﺑﻮﻳﻞ ﻟﺘﻔﺴﲑ ﺇﺟﺎﺑﺘﻚ. .3ﺍﺳﺘﻨﺘﺞ ﹶﺗ ﹾﻔﻘﺪ ﺑﻌﺾ ﺃﺟـﺰﺍﺀ ﺍﻟﺮﺋﺘﲔ ﻣﺮﻭﻧﺘﻬﺎﻭﺗﺘﻀﺨﻢ ،ﻭﻳﻨﺘﺞ ﻋﻦ ﺫﻟﻚ ﻣﺮﺽ ﺍﻧﺘﻔﺎﺥ ﺍﻟﺮﺋﺘﲔ. ﻳﺴﻤﺢ ﺍﻟﻨﺴﻴﺞ ﺍﻹﺳﻔﻨﺠﻲ ﺍﳌﺮﻥ ﺍﻟﺬﻱ ﺗﺘﻜﻮﻥ ﻣﻨﻪ ﺍﻟﺮﺋﺘﺎﻥﻛﻴﻒ ﺗﺴﺘﺪﻝ ﻣﻦ ﻗﺎﻧﻮﻥ ﺑﻮﻳﻞ ﻋﲆ ﺃﻥ ﻫﺬﺍ ﺍﻷﻣﺮ ﺑﺘﻤﺪﺩ ﺍﻟﺮﺋﺘﲔ ﻭﺍﻧﻘﺒﺎﺿﻬﲈ؛ ﻟﺘﺴﺘﺠﻴﺐ ﳊﺮﻛﺔ ﺍﳊﺠﺎﺏ ﺍﳊﺎﺟﺰ ،ﻭﻫﻮ ﺍﻟﻌﻀﻠﺔ ﺍﻟﻘﻮﻳﺔ ﺍﳌﻮﺟﻮﺩﺓ ﺃﺳﻔﻠﻬﲈ .ﻓﻌﻨﺪﻣﺎ ﻳﺆﺛﺮ ﰲ ﻋﻤﻠﻴﺔ ﺍﻟﺘﻨﻔﺲ؟ ﻳﺘﺤﺮﻙ ﺍﳊﺠﺎﺏ ﺍﳊﺎﺟﺰ ﺇﱃ ﺃﺳﻔﻞ ﻳﺰﺩﺍﺩ ﺣﺠﻢ ﺍﻟﺮﺋﺘﲔ، ﻭﺑﺬﻟﻚ ﻧﺘﻤﻜﻦ ﻣﻦ ﺍﻟﺸﻬﻴﻖ ،ﻛﲈ ﻳﺘﻘﻠﺺ ﺣﺠﻢ ﺍﻟﺮﺋﺘﲔ ﻋﻨﺪﻣﺎ .4ﻓ ﹼﴪ ﺍﻟﺴﺒﺐ ﰲ ﺗﻌﻠﻴﻢ ﺍﻟﻐﻮﺍﺻﲔ ﺍﳌﺒﺘﺪﺋﲔ ﺍﻟﺬﻳﻦ ﻳﺘﺤﺮﻙ ﺍﳊﺠﺎﺏ ﺍﳊﺎﺟﺰ ﺇﱃ ﺃﻋﲆ ،ﻭﺑﺬﻟﻚ ﻧﺘﻤﻜﻦ ﻣﻦ ﺍﻟﺰﻓﲑ.ﳛﻤﻠﻮﻥ ﺟﻬﺎﺯ ﺍﻟﺘﻨﻔﺲ ﲢﺖ ﺍﳌﺎﺀ ﻋﺪ ﹶﻡ ﺣﺒﺲ ﺃﻧﻔﺎﺳﻬﻢ ﰲ ﺃﺛﻨﺎﺀ ﺻﻌﻮﺩﻫﻢ ﻣﻦ ﺍﳌﻴﺎﺓ ﺍﻟﻌﻤﻴﻘﺔ. 92 C13-02A-874637.ai be
1 atm ml ˚C 7-2 600 ml 800 )600 (27°C, 600 ml )400 (-123°C, 300 ml300 K 200V2 = 600 ml 0 1 atm ml ˚CT2 300 K 300 250 200 150 100 50 0 50 600 ml 1 atm 800 = 2 ml/K ˚C 300 ml 600 (27° = K 150 K )400 (-123°C, 300 ml 200 ml800 300 K )600 (300 K, 600 ml 0 300 250 200 150 100 400 )200 (150 K, 300 ml ˚C 0 V1 = 300 ml V2 = 600 ml 0 50 100 150 200 250 300 350 T1 150 K T2 300 K K = 2 ml/K = 2 ml/K = = C14-05C-828378-08.ai ﻭﻋﲆ ﻋﻜﺲ ﺍﻟﺸﻜﻞ 7-1ﺇﺫ ﻳﺆﺛﺮ ﰲ ﺍﳌﻜﺒﺲ ﺿﻐﻂ ﺧﺎﺭﺟﻲ ﺑﺎﻹﺿﺎﻓﺔ ﺇﱃ ﺍﻟﻀﻐﻂ ﺍﳉﻮ nﻱb،eﻓﻘﺪ ﺑﻘﻲ ﺍﳌﻜﺒﺲ ﰲ ﺍﻟﺸﻜﻞ 7-2ﺣﺮ ﺍﳊﺮﻛﺔ .ﻭﻫﺬﺍ ﻳﻌﻨﻲ ﻗﻴﺎﻡ ﺍﻟﻐﺎﺯ ﺍﳌﻮﺟﻮﺩ ﰲ ﺍﻷﺳﻄﻮﺍﻧﺔ ﺑﺮﻓﻊ ﺍﳌﻜﺒﺲ ﺇﱃ ﺃﻥ ﻳﺘﺴﺎﻭ ﺍﻟﻀﻐﻂ ﺍﻟﻮﺍﻗﻊ ﻋﻠﻴﻪ ﻣﻊ ﺍﻟﻀﻐﻂ ﺍﳉﻮﻱ. ﻭﻛﲈ ﺗﻼﺣﻆ ﻳﺰﺩﺍﺩ ﺣﺠﻢ ﺍﻟﻐﺎﺯ ﺍﳌﺤﺼﻮﺭ ﻋﻨﺪ 1 atmﺑﺰﻳﺎﺩﺓ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﰲ ﺍﻷﺳﻄﻮﺍﻧﺔ ،ﻟﺬﺍ ﺗﻜﻮﻥ ﺍﳌﺴﺎﻓﺔ ﺍﻟﺘﻲ ﻳﺘﺤﺮﻛﻬﺎ ﺍﳌﻜﺒﺲ ﻣﻘﻴﺎ ﹰﺳﺎ ﻟﺰﻳﺎﺩﺓ ﺣﺠﻢ ﺍﻟﻐﺎﺯ ﻋﻨﺪﻣﺎ ﻳﺴﺨﻦ. ﻳﻮ ﹼﺿﺢ ﺍﻟﺸـﻜﻞ 7-2ﺃﻳ ﹰﻀـﺎ ﺍﻟﻌﻼﻗﺔ ﺑﲔ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻭﺍﳊﺠـﻢ ﳌﻘـﺪﺍﺭ ﳏ ﹼﺪﺩ ﻣﻦ ﺍﻟﻐﺎﺯ ﲢﺖ ﺗﺄﺛﲑ ﺿﻐﻂ ﺛﺎﺑﺖ؛ ﺣﻴﺚ ﺇﻥ ﻣﻨﺤﻨﻰ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻣﻊ ﺍﳊﺠﻢ ﺧ ﹼﻂ ﻣﺴـﺘﻘﻴﻢ ،ﻓﻴﻤﻜﻨـﻚ ﺗﻮﻗﻊ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺍﻟﺘﻲ ﻳﺼﺒﺢ ﺍﳊﺠﻢ ﻋﻨﺪﻫـﺎ ،0 Lﻭﺫﻟﻚ ﺑﻤ ﹼﺪ ﺍﳋﻂ ﺇﱃ ﺩﺭﺟﺎﺕ ﺣﺮﺍﺭﺓ ﺃﺩﻧﻰ ﻣﻦ ﺍﻟﺪﺭﺟﺎﺕ ﺍﻟﺘﻲ ﺗﻢ ﻗﻴﺎﺳﻬﺎ. ﰲ ﺍﻟﺮﺳﻢ ﺍﻟﺒﻴﺎﲏ ﺍﻷﻭﻝ ،ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺍﻟﺘﻲ ﻳﻜﻮﻥ ﻋﻨﺪﻫﺎ ﺍﳊﺠﻢ 0 Lﺗﺴﺎﻭﻱ ،-273˚Cﻟﺬﺍ ﻓﻬﺬﻩ ﺍﻟﻌﻼﻗﺔ ﺧﻄﻴﺔ ،ﻟﻜﻨﻬﺎ ﻟﻴﺴﺖ ﺗﻨﺎﺳ ﹰﺒﺎ ﻣﺒﺎ ﹰﴍﺍ .ﻓﻤﺜ ﹰﻼ ﻳﻤﻜﻨﻚ ﻣﻼﺣﻈﺔ ﻋﺪﻡ ﻣﺮﻭﺭ ﺍﳋﻂ ﺍﳌﺴﺘﻘﻴﻢ ﺑﻨﻘﻄﺔ ﺍﻷﺻﻞ ،ﻛﲈ ﺃﻥ ﻣﻀﺎﻋﻔﺔ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻣﻦ 25˚Cﺇﱃ 50˚Cﻻ ﺗﺆﺩﻱ ﺇﱃ ﻣﻀﺎﻋﻔﺔ ﺍﳊﺠﻢ. ﻳﺒﲔ ﺍﻟﺮﺳﻢ ﺍﻟﺒﻴﺎﲏ ﰲ ﺍﻟﺸﻜﻞ 7-2ﺃﻥ ﺍﻟﻌﻼﻗﺔ ﺑﲔ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺍﳌﻘﻴﺴﺔ ﺑﺎﻟﻜﻠﻔﻦ ) (Kﻭﺍﳊﺠﻢ ﻋﻼﻗﺔ ﻃﺮﺩﻳﺔ ﻭﺍﻟﺘﻨﺎﺳﺐ ﻣﺒﺎﴍ؛ ﺇﺫ ﺗﻘﺎﺑﻞ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ 0 Kﺣﺠ ﹰﲈ ﻣﻘﺪﺍﺭﻩ ،0 mlﻭﻋﻨﺪ ﻣﻀﺎﻋﻔﺔ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻳﺘﻀﺎﻋﻒ ﺍﳊﺠﻢ .ﻭﻳﻌﺮﻑ ﺍﻟﺼﻔﺮ ﻋﲆ ﺗﺪﺭﻳﺞ ﻛﻠﻔﻦ ﺑﺎﻟﺼﻔﺮ ﺍﳌﻄﻠﻖ ،ﻭﻫﻮ ﻳﻤﺜﻞ ﺃﻗﻞ ﻗﻴﻤﺔ ﳑﻜﻨﺔ ﻟﺪﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺍﻟﺘﻲ ﺗﻜﻮﻥ ﻋﻨﺪﻫﺎ ﻃﺎﻗﺔ ﺍﻟﺬﺭﺍﺕ ﺃﻗﻞ ﻣﺎ ﻳﻤﻜﻦ. ﳌﺎﺫﺍ ﻳﻮﺿـﺢ ﺍﻟﺮﺳـﻢ ﺍﻟﺒﻴـﺎﲏ ﺍﻟـﺜـﺎﲏ ﰲ ﺍﻟﺸﻜﻞ 7-2ﺗﻨﺎﺳ ﹰﺒﺎ ﻃﺮﺩ ﹼﹰﻳﺎ ﻣﺒﺎ ﹰﴍﺍ ،ﰲ ﺣﲔ ﻻ ﻳﻮﺿﺢ ﺍﻟﺮﺳﻢ ﺍﻟﺒﻴﺎﲏ ﺍﻷﻭﻝ ﺫﻟﻚ. 93
ﻳﻨﺺ ﻗﺎﻧﻮﻥ ﺷـﺎﺭﻝ ﻋﲆ ﺃﻥ ﺣﺠـﻢ ﺃﻱ ﻣﻘﺪﺍﺭ ﳏﺪﺩ ﻣﻦ ﺍﻟﻐﺎﺯ ﻳﺘﻨﺎﺳـﺐﻃﺮﺩ ﹰﹼﻳـﺎ ﻣﻊ ﺩﺭﺟـﺔ ﺣﺮﺍﺭﺗﻪ ﺍﳌﻄﻠﻘﺔ ﻋﻨﺪ ﺛﺒﻮﺕ ﺍﻟﻀﻐﻂ ،ﻭﻳﻤﻜﻦ ﺍﻟﺘﻌﺒﲑ ﻋﻦ ﻗﺎﻧﻮﻥ ﺷـﺎﺭﻝ ﺑﺎﻟﻌﻼﻗﺔ ﺍﻟﺮﻳﺎﺿﻴﺔ ﺍﻵﺗﻴﺔ: ﻗﺎﻧﻮﻥ ﺷﺎﺭﻝ V _V1 = _V2T T1 T2ﺣﺎﺻﻞ ﴐﺏ ﺿﻐﻂ ﻛﻤﻴﺔ ﳏﺪﺩﺓ ﻣﻦ ﺍﻟﻐﺎﺯ ﰲ ﺣﺠﻤﻬﺎ ﻋﻨﺪ ﺛﺒﻮﺕ ﺩﺭﺟﺔ ﺣﺮﺍﺭﲥﺎ ﻳﺴﺎﻭﻱ ﻛﻤﻴﺔ ﺛﺎﺑﺘﺔ.ﲤﺜﻞ T1،V1ﰲ ﺍﳌﻌﺎﺩﻟﺔ ﺃﻋﻼﻩ ﺍﻟﻈﺮﻭﻑ ﺍﻻﺑﺘﺪﺍﺋﻴﺔ ،ﰲ ﺣﲔ ﲤﺜﻞ T ، Vﺍﻟﻈﺮﻭﻑ ﺍﳉﺪﻳﺪﺓ ،ﻛﲈ ﰲ ﻗﺎﻧﻮﻥ ﺑﻮﻳﻞ ،ﻓﺈﺫ ﻋﺮﻓﺖ ﺛﻼﺙ ﻣﺘﻐﲑﺍﺕ ﺃﻣﻜﻨﻚ ﺣﺴﺎﺏ ﺍﳌﺘﻐﲑ ﺍﻟﺮﺍﺑﻊ.ﻭﻋﻨﺪ ﺍﺳﺘﺨﺪﺍﻡ ﻗﺎﻧﻮﻥ ﺷﺎﺭﻝ ﳚﺐ ﺍﻟﺘﻌﺒﲑ ﻋﻦ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺑﺎﻟﻜﻠﻔﻦ .ﻭﻛﲈ ﻗﺮﺃﺕ ﺳﺎﺑ ﹰﻘﺎ ،ﻋﻠﻴﻚﺇﺿﺎﻓﺔ 273ﺇﱃ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺍﻟﺴﻴﻠﻴﺰﻳﺔ ﻟﺘﺤﻮﻳﻞ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻣﻦ ﺍﻟﺘﺪﺭﻳﺞ ﺍﻟﺴﻴﻠﻴﺰﻱ ﺇﱃTK = 273 + TC ﺍﻟﺘﺪﺭﻳﺞ ﺑﺎﻟﻜﻠﻔﻦ: 72ﺇﺫﺍ ﻛﺎﻥ ﺣﺠﻢ ﺑﺎﻟﻮﻥ ﻫﻴﻠﻴﻮﻡ 2.32 Lﺩﺍﺧﻞ ﺳﻴﺎﺭﺓ ﻣﻐﻠﻘﺔ ،ﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ،40.0 ˚Cﻓﺈﺫﺍ ﻭﻗﻔﺖ ﺍﻟﺴﻴﺎﺭﺓﰲ ﺳﺎﺣﺔ ﺍﻟﺒﻴﺖ ﰲ ﻳﻮﻡ ﺣﺎﺭ ﻭﺍﺭﺗﻔﻌﺖ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺩﺍﺧﻠﻬﺎ ﺇﱃ ،75.0 ˚Cﻓﲈ ﺍﳊﺠﻢ ﺍﳉﺪﻳﺪ ﻟﻠﺒﺎﻟﻮﻥ ﺇﺫﺍ ﺑﻘﻲ ﺍﻟﻀﻐﻂ ﺛﺎﺑ ﹰﺘﺎ؟ 1ﺗﺤﻠﻴﻞ اﻟﻤﺴﺄﻟﺔﻳﻨﺺ ﻗﺎﻧﻮﻥ ﺷﺎﺭﻝ ﻋﲆ ﺃﻥ ﺣﺠﻢ ﻣﻘﺪﺍﺭ ﳏ ﹼﺪﺩ ﻣﻦ ﺍﻟﻐﺎﺯ ﻳﺰﺩﺍﺩ ﺑﺰﻳﺎﺩﺓ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺗﻪ ﺇﺫﺍ ﺑﻘﻲ ﺍﻟﻀﻐﻂ ﺛﺎﺑ ﹰﺘﺎ .ﻟﺬﺍ ﻳﺰﺩﺍﺩ ﺣﺠﻢ ﺍﻟﺒﺎﻟﻮﻥ ،ﻭﳚﺐ ﴐﺏ ﺍﳊﺠﻢ ﺍﻻﺑﺘﺪﺍﺋﻲ ﰲ ﻧﺴﺒﺔ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ﺃﻛﱪ ﻣﻦ ﻭﺍﺣﺪ. V2 = ? L T 2 = 40.0 °C V 1 = 2.32 L T 2 = 75.0 °C TK = 273 + TC 2ﺣﺴﺎب اﻟﻤﻄﻠﻮبT1 = 273 + 40.0 ˚C = 313.0 KT2 = 273 + 75.0 °C = 348.0 K ﺣ ﹼﻮﻝ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺍﻟﺴﻴﻠﻴﺰﻳﺔ ﺇﱃ ﺍﻟﻜﻠﻔﻦ. T140.0˚C T275.0˚C 94
ﺍﺳﺘﺨﺪﻡ ﻗﺎﻧﻮﻥ ﺷﺎﺭﻝ ﻹﳚﺎﺩ ،V2ﻭﻋﻮﺽ ﺑﺎﻟﻘﻴﻢ ﺍﳌﻌﺮﻭﻓﺔ ﰲ ﺍﳌﻌﺎﺩﻟﺔ ﺍﻟﺘﻲ ﹸﺃﻋﻴﺪ ﺗﺮﺗﻴﺒﻬﺎ. _V1 = _V2 V2 T1 T2 ( )V2 = V1 V 1 = 2.32 L، T 1 = 313.0 K، T 2 = 348.0 K _T2 T1 ( )V2 = 2.32 L _348.0 K 313.0 K ( )V2 = 2.32 L _348.0 K = 2.58 L 313.0 K 3ﺗﻘﻮﻳﻢ ا ﺟﺎﺑﺔ ﻛﺎﻧﺖ ﺍﻟﺰﻳﺎﺩﺓ ﰲ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺑﺎﻟﻜﻠﻔﻦ ﺻﻐﲑﺓ ﻧﺴﺒ ﹼﹰﻴﺎ ،ﻟﺬﺍ ﺳﺘﻜﻮﻥ ﺍﻟﺰﻳﺎﺩﺓ ﰲ ﺍﳊﺠﻢ ﺻﻐﲑﺓ ﺃﻳ ﹰﻀﺎ، ﻭﺳﺘﺴﺘﺨﺪﻡ ﻭﺣﺪﺓ ) ( Lﰲ ﺍﻹﺟﺎﺑﺔ ،ﻭﻫﻲ ﻭﺣﺪﺓ ﺍﳊﺠﻢ ،ﻭﻫﻨﺎﻙ ﺛﻼﺛﺔ ﺃﺭﻗﺎﻡ ﻣﻌﻨﻮﻳﺔ. ﺍﻓﱰﺽ ﺃﻥ ﺍﻟﻀﻐﻂ ﻭﻛﻤﻴﺔ ﺍﻟﻐﺎﺯ ﺛﺎﺑﺘﺎﻥ ﰲ ﺍﳌﺴﺎﺋﻞ ﺍﻵﺗﻴﺔ: 4.3 L .4ﻣﺎ ﺍﳊﺠﻢ ﺍﻟﺬﻱ ﻳﺸﻐﻠﻪ ﺍﻟﻐﺎﺯ ﰲ ﺍﻟﺒﺎﻟﻮﻥ ﺍﳌﻮﺟﻮﺩ ﻋﻦ ﺍﻟﻴﺴﺎﺭ ﻋﻨﺪ ﺩﺭﺟﺔ 250 K؟ 350 K .5ﺷﻐﻞ ﻏﺎﺯ ﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ 89 ˚Cﺣﺠ ﹰﲈ ﻣﻘﺪﺍﺭﻩ ) .(0.67 Lﻋﻨﺪ ﺃﻱ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ﺳﻴﻠﻴﺰﻳﺔ ﺳﻴﺰﻳﺪ ﺍﳊﺠﻢ ﻟﻴﺼﻞ ﺇﱃ 1.12 L؟ .6ﺇﺫﺍ ﺍﻧﺨﻔﻀﺖ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺍﻟﺴﻴﻠﻴﺰﻳﺔ ﻟﻌﻴﻨﺔ ﻣﻦ ﺍﻟﻐﺎﺯ ﺣﺠﻤﻬﺎ 3.0 Lﻣﻦ 80.0 ˚Cﺇﱃ 30.0 ˚C ﻓﲈ ﺍﳊﺠﻢ ﺍﳉﺪﻳﺪ ﻟﻠﻐﺎﺯ؟ .7ﻳﺸﻐﻞ ﻏﺎﺯ ﺣﺠ ﹰﲈ ﻣﻘﺪﺍﺭﻩ 0.67 Lﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ) .(350 Kﻣﺎ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺍﻟﻼﺯﻣﺔ ﳋﻔﺾ ﺍﳊﺠﻢ ﺑﻤﻘﺪﺍﺭ 45%؟C13-03A-874637.ai ben ﻗﺎﻧﻮن ﺟﺎي -ﻟﻮﺳﺎك Gay- Lussac،s Law ﻻﺣﻈﺖ ﰲ ﺍﻟﺘﺠﺮﺑﺔ ﺍﻻﺳﺘﻬﻼﻟﻴﺔ ﺗﻄﺒﻴﻘﺎﺕ ﻋﲆ ﻗﺎﻧﻮﻥ ﺷﺎﺭﻝ ،ﻓﻌﻨﺪ ﺗﻐﲑ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻳﺘﻐﲑ ﺣﺠﻢ ﺍﻟﺒﺎﻟﻮﻥ ،ﻭﻟﻜﻦ ﻣﺎﺫﺍ ﻳﻤﻜﻦ ﺃﻥ ﳛﺪﺙ ﻟﻮ ﻛﺎﻥ ﺍﻟﺒﺎﻟﻮﻥ ﺻﻠ ﹰﺒﺎ ﺛﺎﺑ ﹰﺘﺎ؟ ﻭﺇﺫﺍ ﻛﺎﻥ ﺣﺠﻤﻪ ﺛﺎﺑ ﹰﺘﺎ ﻓﻬﻞ ﻫﻨﺎﻙ ﻋﻼﻗﺔ ﺑﲔ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻭﺍﻟﻀﻐﻂ؟ ﻳﻤﻜﻦ ﺍﻹﺟﺎﺑﺔ ﻋﻦ ﻫﺬﺍ ﺍﻟﺴﺆﺍﻝ ﻣﻦ ﺧﻼﻝ ﻗﺎﻧﻮﻥ ﺟﺎﻱ -ﻟﻮﺳﺎﻙ. ﻳﻨﺘﺞ ﺍﻟﻀﻐﻂ ﻋﻦ ﺍﺻﻄﺪﺍﻡ ﺟﺴﻴﲈﺕ ﺍﻟﻐﺎﺯ ﺑﺠﺪﺭﺍﻥ ﺍﻟﻮﻋﺎﺀ؛ ﻓﻜﻠﲈ ﺍﺭﺗﻔﻌﺖ ﺩﺭﺟﺎﺕ ﺍﳊﺮﺍﺭﺓ ﺯﺍﺩ ﻋﺪﺩ ﺍﻻﺻﻄﺪﺍﻣﺎﺕ ﻭﻃﺎﻗﺘﻬﺎ .ﻟﺬﺍ ﺗﺆﺩﻱ ﺯﻳﺎﺩﺓ ﺍﳊﺮﺍﺭﺓ ﺇﱃ ﺯﻳﺎﺩﺓ ﺍﻟﻀﻐﻂ ﺇﺫﺍ ﱂ ﻳﺘﻐﲑ ﺍﳊﺠﻢ.95
7-3 1.0 L 1.0 Latm K 1 atm 2 atm 4.0 150 K 300 K 3.5 3.0 (300 K, 3.0 atm) P1 = 1.5 atm P2 = 3.0 atm 2.5 T1 150 K T2 300 K 2.0 1.5 (150 K, 1.5 atm) = 0.01 atm/K = 0.01 atm/K 1.0 0.5 = = 0 0 100 200 300 400 500 600 K ﻗﺎﺭﻥ ﺑﲔ ﺍﻟﺮﺳﻮﻡ .7-3 ﻭ7-2 ﺍﻟﺒﻴﺎﻧﻴﺔ ﰲ ﺍﻟﺸﻜﻠﲔ C13-04A-874637.ai ben( ﺃﻥ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺍﳌﻄﻠﻘﺔ ﺗﺘﻨﺎﺳﺐ1778-1850) ﻭﻗﺪ ﻭﺟﺪ ﺟﺎﻱ ﻟﻮﺳﺎﻙ ﻣﻬﻦ ﻓﻲ اﻟﻜﻴﻤﻴﺎء ﻭﻳﻨﺺ ﻗﺎﻧﻮﻥ ﺟﺎﻱ ﻟﻮﺳﺎﻙ.7-3 ﻛﲈ ﻫﻮ ﻣﻮﺿﺢ ﰲ ﺍﻟﺸﻜﻞ،ﻃﺮﺩ ﹰﹼﻳﺎ ﻣﻊ ﺍﻟﻀﻐﻂ ،ﻋﲆ ﺃﻥ ﺿﻐﻂ ﻣﻘﺪﺍﺭ ﳏ ﹼﺪﺩ ﻣﻦ ﺍﻟﻐﺎﺯ ﻳﺘﻨﺎﺳﺐ ﻃﺮﺩ ﹼﹰﻳﺎ ﻣﻊ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺍﳌﻄﻠﻘﺔ ﻟﻪ : ﻭﻳﻤﻜﻦ ﺍﻟﺘﻌﺒﲑ ﻋﻨﻪ ﺭﻳﺎﺿ ﹼﹰﻴﺎ ﻛﲈ ﻳﺄﰐ.ﺇﺫﺍ ﺑﻘﻲ ﺍﳊﺠﻢ ﺛﺎﺑ ﹰﺘﺎ ﻗﺎﻧﻮﻥ ﺟﺎﻱ ﻟﻮﺳﺎﻙ P _P1 = _P2 T T1 T2ﺣﺎﺻﻞ ﻗﺴﻤﺔ ﺍﻟﻀﻐﻂ ﻋﲆ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺍﳌﻄﻠﻘﺔ ﳌﻘﺪﺍﺭ ﳏﺪﺩ ﻣﻦ ﺍﻟﻐﺎﺯ ﺫﻱ .ﺣﺠﻢ ﺛﺎﺑﺖ ﻳﺴﺎﻭﻱ ﻣﻘﺪ ﹰﺭﺍ ﺛﺎﺑ ﹰﺘﺎ ﻓﺈﺫﺍ ﻋﺮﻓﺖ ﺛﻼﺛﺔ ﻣﺘﻐﲑﺍﺕ ﺃﻣﻜﻨﻚ،ﻭﻛﲈ ﻫﻮ ﺍﳊﺎﻝ ﰲ ﻗﺎﻧﻮﲏ ﺑﻮﻳﻞ ﻭﺷﺎﺭﻝ ﺗﺬﻛﺮ ﺃﻥ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﳚﺐ ﺃﻥ ﺗﻜﻮﻥ.ﺣﺴﺎﺏ ﺍﳌﺘﻐﲑ ﺍﻟﺮﺍﺑﻊ ﺑﺎﺳﺘﺨﺪﺍﻡ ﺍﳌﻌﺎﺩﻟﺔ .( ﺃﻳﻨﲈ ﺍﺳﺘﺨﺪﻣﺖ ﰲ ﻣﻌﺎﺩﻻﺕ ﻗﻮﺍﻧﲔ ﺍﻟﻐﺎﺯk) ﻣﻄﻠﻘﺔ 96
73 -ﺇﺫﺍ ﻛﺎﻥ ﺿﻐﻂ ﻏﺎﺯ ﺍﻷﻛﺴﺠﲔ ﺩﺍﺧﻞ ﺍﻷﺳﻄﻮﺍﻧﺔ 5.00 atmﻋﻨﺪ ﺩﺭﺟﺔ ، 25.0˚Cﻭﻭﺿﻌﺖﺍﻷﺳﻄﻮﺍﻧﺔ ﰲ ﺧﻴﻤﺔ ﻋﲆ ﻗﻤﺔ ﺟﺒﻞ ﺇﻓﺮﺳﺖ ،ﺣﻴﺚ ﺗﻜﻮﻥ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ -10.0˚Cﻓﲈ ﺍﻟﻀﻐﻂ ﺍﳉﺪﻳﺪ ﺩﺍﺧﻞ ﺍﻷﺳﻄﻮﺍﻧﺔ؟ 1ﺗﺤﻠﻴﻞ اﻟﻤﺴﺄﻟﺔﻳﻨﺺ ﻗﺎﻧﻮﻥ ﺟﺎﻱ -ﻟﻮﺳﺎﻙ ﻋﲆ ﺃﻧﻪ ﺇﺫﺍ ﺍﻧﺨﻔﻀﺖ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ﺍﻟﻐﺎﺯ ﺍﳌﺤﺼﻮﺭ ﻓﺈﻥ ﺿﻐﻄﻪ ﻳﻨﺨﻔﺾ ﺇﺫﺍ ﺑﻘﻲ ﺣﺠﻤﻪ ﺛﺎﺑ ﹰﺘﺎ. ﻟﺬﻟﻚ ﻳﻘﻞ ﺍﻟﻀﻐﻂ ﰲ ﺃﺳﻄﻮﺍﻧﺔ ﺍﻷﻛﺴﺠﲔ .ﳚﺐ ﴐﺏ ﻣﻘﺪﺍﺭ ﺍﻟﻀﻐﻂ ﺍﻻﺑﺘﺪﺍﺋﻲ ﰲ ﻧﺴﺒﺔ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ﺃﻗﻞ ﻣﻦ .1 P2 = ? atm P1 = 5.00 atm T1 = 25.0 ˚C T2 = -10.0 ˚C 2ﺣﺴﺎب اﻟﻤﻄﻠﻮب ﺣﻮﻝ ﺩﺭﺟﺎﺕ ﺍﳊﺮﺍﺭﺓ ﺍﻟﺴﻴﻠﻴﺰﻳﺔ ﺇﱃ ﻣﻄﻠﻘﺔ TK = 273 + TC T1 = 273 + 25.0 ˚C = 298.0 K T125.0 ˚C T2 = 273 + (-10.0 °C) = 263.0 K T2 = 10.0 ˚C ﺍﺳﺘﺨﺪﻡ ﻗﺎﻧﻮﻥ ﺟﺎﻱ ﻟﻮﺳﺎﻙ؛ ﻹﳚﺎﺩ ﻗﻴﻤﺔ ،P2ﻭﻋﻮﺽ ﺑﺎﻟﻘﻴﻢ ﺍﳌﻌﺮﻭﻓﺔ ﰲ ﺍﳌﻌﺎﺩﻟﺔ ﺍﻟﺘﻲ ﺃﻋﻴﺪ ﺗﺮﺗﻴﺒﻬﺎ. ( )_P_1= _P_2 T2 P2 T1 P2 = P1 _T2 T1 ( )P2 = 5.00 atm _263.0 K P15.00atmT1298.0KT2263.0K 298.0 K ( )P2 = 5.00 atm _263.0 K = 4.41 atm 298.0 K 3ﺗﻘﻮﻳﻢ ا ﺟﺎﺑﺔ ﺗﻘﻞ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺍﳌﻄﻠﻘﺔ ،ﻟﺬﺍ ﻳﻘﻞ ﺍﻟﻀﻐﻂ .ﻭﺣﺪﺓ ﺍﻟﻀﻐﻂ ،atmﻭﻫﻨﺎﻙ ﺛﻼﺛﺔ ﺃﺭﻗﺎﻡ ﻣﻌﻨﻮﻳﺔ. .8ﺇﺫﺍ ﻛﺎﻥ ﺿﻐﻂ ﺇﻃﺎﺭ ﺳﻴﺎﺭﺓ 1.88 atmﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ، 250 ˚Cﻓﻜﻢ ﻳﻜﻮﻥ ﺍﻟﻀﻐﻂ ﺇﺫﺍ ﺍﺭﺗﻔﻌﺖ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺇﱃ 37.0 ˚C؟ .9ﻳﻮﺟﺪ ﻏﺎﺯ ﻫﻴﻠﻴﻮﻡ ﰲ ﺃﺳﻄﻮﺍﻧﺔ ﺣﺠﻤﻬﺎ ،2Lﲢﺖ ﺗﺄﺛﲑ ﺿﻐﻂ ﺟﻮﻱ ﻣﻘﺪﺍﺭﻩ ،1.12 atmﻓﺈﺫﺍ ﺃﺻﺒﺢ ﺿﻐﻂ ﺍﻟﻐﺎﺯ 2.56 ،atmﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ،36.5 ˚Cﻓﲈ ﻗﻴﻤﺔ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ﺍﻟﻐﺎﺯ ﺍﻻﺑﺘﺪﺍﺋﻴﺔ؟ .10ﺇﺫﺍ ﻛﺎﻥ ﺿﻐﻂ ﻋﻴﻨﺔ ﻣﻦ ﺍﻟﻐﺎﺯ ﻳﺴﺎﻭﻱ 30.7 KPaﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ،00.0 ˚Cﻓﻜﻢ ﻳﻨﺒﻐﻲ ﺃﻥ ﺗﺮﺗﻔﻊ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺍﻟﺴﻴﻠﻴﺰﻳﺔ ﻟﻠﻌﻴﻨﺔ ﺣﺘﻰ ﻳﺘﻀﺎﻋﻒ ﺿﻐﻄﻬﺎ؟97
7-4 اﻟﻘﺎﻧﻮن اﻟﻌﺎم ﻟﻠﻐﺎزات The Combined Gas Law اﻟﻜﻴﻤﻴﺎء ﻓﻲ واﻗﻊ اﻟﺤﻴﺎةﻳﻤﻜﻦ ﺃﻥ ﻳﺘﻐﲑ ﻛﻞ ﻣﻦ ﺍﻟﻀﻐﻂ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻭﺍﳊﺠﻢ ﰲ ﺍﻟﻌﺪﻳﺪ ﻣﻦ ﺍﻟﺘﻄﺒﻴﻘﺎﺕ ﺍﻟﻌﻤﻠﻴﺔ ﻟﻠﻐﺎﺯﺍﺕ ،ﻛﲈ ﰲ ﺑﺎﻟﻮﻥ ﺍﻟﻄﻘﺲ ﰲ ﺍﻟﺸﻜﻞ .7-4ﻛﲈ ﻳﻤﻜﻦ ﲨﻊ ﻗﺎﻧﻮﻥﺑﻮﻳﻞ ﻭﻗﺎﻧﻮﻥ ﺷﺎﺭﻝ ﻭﻗﺎﻧﻮﻥ ﺟﺎﻱ -ﻟﻮﺳﺎﻙ ﰲ ﻗﺎﻧﻮﻥ ﻭﺍﺣﺪ ﻳﻄﻠﻖ ﻋﻠﻴﻪ ﺍﻟﻘﺎﻧﻮﻥ ﺍﻟﻀﻐﻂ ﻟﻮﻋﺎﺀ ﺍﻟﻀﻐﻂ ﻏﻄﺎﺀﺍﻟﻌﺎﻡ ﻟﻠﻐﺎﺯﺍﺕ ،ﻭﻫﻮ ﳛ ﹼﺪﺩ ﺍﻟﻌﻼﻗﺔ ﺑﲔ ﺍﻟﻀﻐﻂ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻭﺍﳊﺠﻢ ﻟﻜﻤﻴﺔﳏ ﹼﺪﺩﺓ ﻣﻦ ﺍﻟﻐﺎﺯ .ﻭﻳﻮﺟﺪ ﺑﲔ ﺍﳌﺘﻐﲑﺍﺕ ﺍﻟﺜﻼﺛﺔ ﻧﻔﺲ ﺍﻟﻌﻼﻗﺔ ﺍﳌﻮﺟﻮﺩﺓ ﰲ ﺍﻟﻘﻮﺍﻧﲔ ﳏﻜﻢ ﺍﻹﻏﻼﻕ ،ﻭﺣﺠﻤﻪ ﺛﺎﺑﺖ .ﻭﻋﻨﺪﺍﻷﺧﺮ .ﻓﺎﻟﻀﻐﻂ ﻳﺘﻨﺎﺳﺐ ﻋﻜﺴ ﹰﹼﻴﺎ ﻣﻊ ﺍﳊﺠﻢ ،ﻭﻃﺮﺩ ﹰﹼﻳﺎ ﻣﻊ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ. ﺗﺴﺨﻴﻨﻪ ﻳــﺰﺩﺍﺩ ﺍﻟﻀﻐﻂ ﰲ ﺍﻹﻧــﺎﺀ، ﻭﺑﺰﻳﺎﺩﺓ ﺍﻟﻀﻐﻂ ﺗﺴﺘﻤﺮ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻭﻳﻤﻜﻦ ﺍﻟﺘﻌﺒﲑ ﻋﻦ ﺍﻟﻘﺎﻧﻮﻥ ﺍﻟﻌﺎﻡ ﻟﻠﻐﺎﺯﺍﺕ ﺭﻳﺎﺿ ﹼﹰﻴﺎ ﻋﲆ ﺍﻟﻨﺤﻮ ﺍﻵﰐ: ﰲ ﺍﻻﺭﺗﻔﺎﻉ ،ﻓﻴﺘﻢ ﺑﺬﻟﻚ ﻃﻬﻮ ﺍﻟﻄﻌﺎﻡ ﺍﻟﻘﺎﻧﻮﻥ ﺍﻟﻌﺎﻡ ﻟﻠﻐﺎﺯﺍﺕ ﺑﴪﻋﺔ ﺃﻛﱪ.VP _P1V1 = _P2V2 98 T T1 T2ﺣﻴﺚ ﺣﺎﺻﻞ ﴐﺏ ﺍﻟﻀﻐﻂ ﻭﺍﳊﺠﻢ ﻣﻘﺴﻮ ﹰﻣﺎ ﻋﲆ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺍﳌﻄﻠﻘﺔ ﳌﻘﺪﺍﺭ ﳏ ﹼﺪﺩ ﻣﻦ ﺍﻟﻐﺎﺯ ﻳﺴﺎﻭﻱ ﻣﻘﺪﺍ ﹰﺭﺍ ﺛﺎﺑ ﹰﺘﺎ.ﺍ ﻳﺴﺎﻋﺪﻙ ﺍﻟﻘﺎﻧﻮﻥ ﺍﻟﻌﺎﻡ ﻟﻠﻐﺎﺯﺍﺕ ﻋﲆ ﺣﻞﺍﳌﺴﺎﺋﻞ ﺍﻟﺘﻲ ﺗﺘﻀﻤﻦ ﺃﻛﺜﺮ ﻣﻦ ﻣﺘﻐﲑ ﻭﺍﺣﺪ ،ﻛﲈ ﻳﻘﺪﻡ ﻟﻚ ﻃﺮﻳﻘﺔ ﻟﺘﺬﻛﺮ ﺍﻟﻘﻮﺍﻧﲔﺍﻟﺜﻼﺛﺔ ﺍﻷﺧﺮ ﺩﻭﻥ ﺗﺬﻛﺮ ﻣﻌﺎﺩﻻﲥﺎ ،ﻓﺈﺫﺍ ﻛﻨﺖ ﻗﺎﺩ ﹰﺭﺍ ﻋﲆ ﻛﺘﺎﺑﺔ ﻣﻌﺎﺩﻟﺔ ﻗﺎﻧﻮﻥﺍﻟﻐﺎﺯﺍﺕ ﺍﻟﻌﺎﻡ ﻓﺈﻧﻪ ﻳﻤﻜﻨﻚ ﺍﺷﺘﻘﺎﻕ ﺍﻟﻘﻮﺍﻧﲔ ﺍﻷﺧﺮ ﻣﻦ ﺧﻼﻝ ﺗﺬﻛﺮ ﺍﳌﺘﻐﲑ ﺍﻟﺜﺎﺑﺖ ﰲ ﻛﻞ ﺣﺎﻟﺔ.ﻣﺜ ﹰﻼ ﺇﺫﺍ ﺑﻘﻴﺖ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺛﺎﺑﺘﺔ ﺑﻴﻨﲈ ﺗﻐﲑ ﺍﻟﻀﻐﻂ ﻭﺍﳊﺠﻢ ﻓﺈﻥ .T2=T1ﻭﺑﻌﺪ ﺗﺒﺴﻴﻂ ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﻟﻌﺎﻡ ﲢﺖ ﻫﺬﻩ ﺍﻟﻈﺮﻭﻑ ﺳﺘﺠﺪ ﺃﻥ ﺍﳌﻌﺎﺩﻟﺔ ﺃﺻﺒﺤﺖ ،P1V1 =P2V2ﻭﺍﻟﺘﻲ ﻳﻨﺒﻐﻲ ﺃﻥ ﺗﺴﺘﻨﺘﺞ ﺃﳖﺎ ﻗﺎﻧﻮﻥ ﺑﻮﻳﻞ. ﻗﺎﻧﻮﻥ ﺷﺎﺭﻝ ،ﻭﻗﺎﻧﻮﻥ ﺟﺎﻱ-ﻟﻮﺳﺎﻙ ﻣﻦ ﺍﻟﻘﺎﻧﻮﻥ ﺍﳉﺎﻣﻊ ﻟﻠﻐﺎﺯﺍﺕ.
74 ﺇﺫﺍ ﻛﺎﻥ ﺣﺠﻢ ﻛﻤﻴﺔ ﻣﻦ ﻏﺎﺯ ﻣﺎ ﲢﺖ ﺿﻐﻂ ، 110 KPaﻭﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ 30.0˚Cﻳﺴﺎﻭﻱ ،2.00 L ﻭﺍﺭﺗﻔﻌﺖ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺇﱃ ،80.0˚Cﻭﺯﺍﺩ ﺍﻟﻀﻐﻂ ﻭﺃﺻﺒﺢ ،440 KPaﻓﲈ ﻣﻘﺪﺍﺭ ﺍﳊﺠﻢ ﺍﳉﺪﻳﺪ؟ 1ﺗﺤﻠﻴﻞ اﻟﻤﺴﺄﻟﺔ ﺗﻐﲑ ﻛﻞ ﻣﻦ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻭﺍﻟﻀﻐﻂ؛ ﻟﺬﻟﻚ ﳚﺐ ﺃﻥ ﺗﺴﺘﺨﺪﻡ ﺍﻟﻘﺎﻧﻮﻥ ﺍﻟﻌﺎﻡ ﻟﻠﻐﺎﺯﺍﺕ.ﻟﻘﺪ ﺯﺍﺩ ﺍﻟﻀﻐﻂ ﺃﺭﺑﻊ ﻣﺮﺍﺕ ،ﻟﻜﻦ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﱂ ﺗﺮﺗﻔﻊ ﺑﻤﺜﻞ ﻫﺬﺍ ﺍﳌﻌﺎﻣﻞ ﺍﻟﻀﺨﻢ ،ﻟﺬﻟﻚ ﻓﺈﻥ ﺍﳊﺠﻢ ﺍﳉﺪﻳﺪ ﺳﻴﻜﻮﻥ ﺃﻗﻞ P1 = 110 kPa ﻣﻦ ﺍﳊﺠﻢ ﺍﻻﺑﺘﺪﺍﺋﻲ. T1 = 30.0 ºC V2 = ? L P2 = 440 kPa T2 = 80.0 °C V1 = 2.00 L 2ﺣﻞ اﻟﻤﻄﻠﻮب ﺣ ﹼﻮﻝ ﺩﺭﺟﺎﺕ ﺍﳊﺮﺍﺭﺓ ﻣﻦ ﺍﻟﺴﻴﻠﻴﺰﻳﺔ ﺇﱃ ﻣﻄﻠﻘﺔ. TK = 273 + TC T1 = 273 + 30.0°C = 303.0 K T130.0°C T2 = 273 + 80.0°C = 353.0 K T230.0°C ﺍﺳﺘﺨﺪﻡ ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯﺍﺕ ﺍﻟﻌﺎﻡ ،ﻟﺘﺠﺪ ﻗﻴﻤﺔ Vﺛﻢ ﻋﻮﺽ ﺍﻟﻘﻴﻢ ﺍﳌﻌﺮﻭﻓﺔ ﰲ ﺍﳌﻌﺎﺩﻟﺔ ﺍﻟﺘﻲ ﺃﻋﻴﺪ ﺗﺮﺗﻴﺒﻬﺎ. _P1V1 =_PT22V2 V2 T1 P1110kPaP2440kPaT1303.0K ( )( )V2=V1_P1 _T2 P2 T1 ( )( )V2 = 2.00 L _110 kPa _353.0 K 440 kPa 303.0 K ( )( )V2 T2353.0K = 2.00 L _110 kPa _353.0 K = 0.58 L 440 kPa 303.0 K 3ﺗﻘﻮﻳﻢ ا ﺟﺎﺑﺔﺗﻐﲑ ﺍﻟﻀﻐﻂ ﺑﺸﻜﻞ ﺃﻛﱪ ﻣﻦ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ،ﻟﺬﺍ ﻓﻘﺪ ﻗﻞ ﺍﳊﺠﻢ .ﺍﻟﻮﺣﺪﺓ ﻫﻲ) ،(Lﻭﻫﻲ ﺣﺪﺓ ﻗﻴﺎﺱ ﺍﳊﺠﻢ ،ﻭﻫﻨﺎﻙ ﺭﻗﲈﻥ ﻣﻌﻨﻮﻳﺎﻥ. .11ﹸﲢﺪﺙ ﻋﻴﻨﺔ ﻣﻦ ﺍﳍﻮﺍﺀ ﰲ ﺣﻘﻨﺔ ﺿﻐ ﹰﻄﺎ ﻣﻘﺪﺍﺭﻩ ،1.02 atmﻋﻨﺪ ،22.0˚Cﻭﻭﺿﻌﺖ ﻫﺬﻩ ﺍﳊﻘﻨﺔ ﰲ ﲪﺎﻡ ﻣﺎﺀ ﻳﻐﲇ )ﺩﺭﺟﺔﺣﺮﺍﺭﺓ (100.0˚Cﻭﺍﺯﺩﺍﺩ ﺍﻟﻀﻐﻂ ﺇﱃ 1.23 atmﺑﺪﻓﻊ ﻣﻜﺒﺲ ﺍﳊﻘﻨﺔ ﺇﱃ ﺍﻟﺪﺍﺧﻞ ،ﳑﺎ ﺃﺩ ﺇﱃ ﻧﻘﺼﺎﻥ ﺍﳊﺠﻢ ﺇﱃ 0.224 mlﻓﻜﻢ ﻛﺎﻥ ﺍﳊﺠﻢ ﺍﻻﺑﺘﺪﺍﺋﻲ؟ 0.00°C .12ﳛﺘﻮﻱ ﺑﺎﻟﻮﻥ ﻋﲆ 146.0 mlﻣﻦ ﺍﻟﻐﺎﺯ ﺍﳌﺤﺼﻮﺭ ﲢﺖ ﺿﻐﻂ ﻣﻘﺪﺍﺭﻩ 1.30 atmﻭﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ 5.0˚Cﻓﺈﺫﺍ ﺗﻀﺎﻋﻒ ﺍﻟﻀﻐﻂ ﻭﺍﻧﺨﻔﻀﺖ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺇﱃ 2.0˚Cﻓﻜﻢ ﻳﻜﻮﻥ ﺣﺠﻢ ﺍﻟﻐﺎﺯ ﰲ ﺍﻟﺒﺎﻟﻮﻥ؟ 1.00atm .13ﺇﺫﺍ ﺯﺍﺩﺕ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﰲ ﺍﻷﺳﻄﻮﺍﻧﺔ ﺍﳌﺠﺎﻭﺭﺓ ﻟﺘﺼﻞ ﺇﱃ ، 30.0˚Cﻭﺯﺍﺩ ﺍﻟﻀﻐﻂ ﺇﱃ 30.0ml 1.20 atmﻓﻬﻞ ﻳﺘﺤﺮﻙ ﻣﻜﺒﺲ ﺍﻷﺳﻄﻮﺍﻧﺔ ﺇﱃ ﺃﻋﲆ ﺃﻡ ﺇﱃ ﺃﺳﻔﻞ؟99
Combined T PV PV 71 Charles’s Combined _PT11V1=_PT22V2 P_P1 T _P2 V P_V1 =T _TV22V P1PV1 = P2VV2 ﻣﻘﺪﺍﺭ ﺍﻟﻐﺎﺯ T1 = T2 T1 PV inedﻣbﻘmـoﺪﺍCﺭ ﺍﻟﻐـﺎﺯ ﻭﺩﺭﺟـﺔ ﺍﳊﺮﺍ’sﺭsﺓharleﻣCﻘﺪﺍﺭ ﺍﻟﻐﺎﺯ ﻭﺍﻟﻀﻐﻂ yle’sﻣoﻘBﺪﺍﺭ ﺍﻟﻐﺎﺯ ﻭﺍﳊﺠﻢ Combined T T T PV PV PV Gay-Lussac’s Boyle’s Charles’s T TT T PV PV PVﻣﻦ ﻛﻞ ﺑﻪ ﻗﺎﻡ ﺍﻟﺬﻱ Charles’s 74637.aiTGay-Lussac’sTBoyle’sﻻ-8ﺑﺪ Aﺃ2ﻧ-1ﻚ13ﻻCﺣﻈﺖ T ﺃﻥ ﺍﻟﻌﻤﻞﺷـﺎﺭVﻝ ﻭﺟﺎ Pﻱ -ﻟﻮﺳـﺎﻙ ﻗﺪ ﺳـﺒﻖ ﺗﻄﻮﻳﺮ ﺍﻟﺘﺪﺭﻳnﺞ eﺍbﳌﻄﻠﻖ ) ،(Kﻋﲆ ﺍﻟﺮﻏﻢ ﻣﻦ ﺃVﻥ ﻗﺎﻧﻮﻧﻴﻬPﲈ ﺗﻄﻠﺒﺎay-Lussac’sﺍGﺳﺘﺨﺪﺍﻡ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺍﳌﻄﻠﻘﺔ ) .(Kﺣﻴﺚ ﺍﺳﺘﺨﺪﻡ ﺍﻟﻌﻠﲈﺀ ﰲ ﺍﻟﻘﺮﻥ 1Bo7yl0e’0sﻭﺑﺪﺍﻳﺎﺕ ﺍﻟﻘﺮﻥ 18 Tﺣﺮﺍﺭiﺓ.aﳐ7ﺘﻠ3ﻔ6ﺔ7.4ﻓ8nﻌb-eﲆ2PAﺳ1ـﺒ-ﻴ3ﻞ1ﺍﳌCﺜﺎﻝﻧﻔﺴﻪ ﺍTﻟﻌ Pﴫ ﰲ ﺣﺘ Vﻰ ﻓﺮﻧﺴﺎ ﰲ ﺭﻳﻮﻣﺮ ﺗﺪﺭﻳﺞ ﺍﺳـﺘﺨﺪﻡ ﻣﻘﺎﻳﻴﺲ Pﺍﻟﺬﻱ ﻋﺎﺵ ﻓﻴﻪ ﺷﺎﺭﻝ ﺗﻘﺮﻳ ﹰﺒﺎ .ﻭﺑﺎﺳﺘﺨﺪﺍﻡ ﻫﺬﺍ ﺍﻟﺘﺪﺭﻳﺞ ﺃﻭ ﺃﻱ ﺗﺪﺭﻳc’sﺞssaﻻuﻳ-LﻌyﺘaﻤGﺪ ﻋﲆ ﺍﻟﺼﻔﺮ ﺍﳌﻄﻠﻖ874637.aiﺗA-ﺼﺒ12ﺢ-ﺍﳌ3ﻌ1ﺎCﺩﻟﺔ ﺍﻟﺘﻲ ﺗﻌﱪ ﻋﻦ ﻗﺎﻧﻮﻥ ﺷﺎﺭﻝ ﺃﻛﺜﺮ ﺗﻌﻘﻴ ﹰﺪﺍ؛ ﻓﻬﻲ ﲢﺘﺎﺝ ﺇﱃ ﺛﺎﺑﺘﲔ ﺇﺿﺎﻓﺔ ﺇTﱃ ﺍﳊﺠﻢ Venﻭbﺩﺭ Pﺟﺔ ﺍﳊﺮﺍﺭﺓ .Tﻭﻗﺪ ﺑ ﹼﺴPﻂ ﺍﻟﺘﺪﺭﻳﺞ ﺍﳌﻄﻠﻖ ﺍﻷﻣﻮﺭ ،ﻭﻧﺘﺠﺖ ﻗﻮﺍﻧﲔ ﺍﻟﻐﺎﺯﺍﺕ ﺍﳌﺴﺘﺨﺪﻣﺔ ﺍﻵﻥ. V TV Tﺃﻳ ﹰﻀﺎ ﰲ.aiﻋﻴ7ﻨﺔ63ﻣ4ﻦ7ﺍ8ﻟ-ﻐﺎAﺯ-1.2ﻭﻳ3ﻤ1ﻜCﻨﻚ ﻣ’ﺘesﻐarlﲑﺍChﺕ ﻛﻴﻒ ﺍﻵﻥ ﻋﺮﻓﺖ ﻭﺍ dﳊeﺮnﺍiﺭbﺓomﻭCﺍﳊﺠﻢ ﺍﻟﻀﻐﻂ ﺗﺆﺛﺮﺍPﺳﺘﺨﺪﺍﻡ ﻗﻮﺍﻧﲔ ﺍﻟﻐﺎﺯﺍﺕ ﺍﻟﺘPﻲ ﺗﻢ ﺗﻠﺨﻴﺼﻬﺎ ﰲ ﺍ Pﳉﺪﻭﻝ 7-1ﺇﺫﺍ ﻛﺎﻧﺖnﻛeﻤbﻴﺔ ﺍﻟﻐﺎﺯ ﺛﺎﺑﺘﺔ ،ﻟﻜﻦ P Tﻣﺎﺫﺍ ﳛﺪﺙ ﺇﺫﺍVﺗﻐ Tﲑﺕ ﻛﻤﻴﺔ ﺍﻟﻐﺎﺯ؟Vﻫﺬﺍ ﻣﺎ ﺳﺘﺪﺭﺳﻪ ﻻﺣ ﹰﻘﺎ. Combined ’Charles PP P TاﻟﺘﻘﻮﻳT Vﻢ P 7-1 V TV T V Boyle’s Gay-Lussac’s Combined اﻟ ’ﺨlesﻼChaPrﺻﺔ P .14اﻟﻔﻜﺮة اﻟﺮﺋﻴﺴﺔ ﻭﺿﺢﺍﻟﻌﻼﻗﺔﺑﲔﺍﻟﻀﻐﻂﻭﺩﺭﺟﺔﺍﳊﺮﺍﺭﺓﻭﺣﺠﻢﻛﻤﻴﺔﺛﺎﺑﺘﺔﻣﻦﺍﻟﻐﺎﺯ.ﺗﻨﺎﺳ ﹰﺒﺎ ﺗﺘﻨﺎ Vﺳﺐ ﻣﻦ ﺍﻟﻐﺎﺯ، ﻛﻤﻴﺔVﺛﺎﺑﺘTﺔ ﺗﺆﺛﺮ ﰲ ﺍﻟTﺘﻲ ﺃﻱ ﺍﳌﺘﻐﲑﺍﺕVﺍﻟﺜﻼﺛﺔ، ﺍ Tﴍﺡ .V15 ﻗﺎﻧﻮﻥ ﺑﻮﻳﻞ ﻋﲆ ﺃﻥ Tﺣﺠﻢ ﻣﻘﺪﺍﺭ ﻳﻨﺺ Boyle’s ﳏ ﹼﺪﺩ Combined ’Charles ﻃﺮﺩ ﹰﹼﻳﺎ ،ﻭﺃﳞﺎ ﺗﺘﻨﺎﺳﺐ ﻋﻜﺴ ﹼﹰﻴﺎ؟ Gay-Lussac’s ﻛ ﹼﹰﻼPﻣﻦ P ﹸﺃﻃﻠﻖ ﻣﻦ ﺍﻟﻐﺎﺯ ﻳﺘﻨﺎﺳﺐ ﻋﻜﺴ ﹼﹰﻴﺎ ﻣﻊﺍﻻﺑﺘﺪﺍﺋﻲ ﺣﺠﻤﻪ ﺗﻌﺮﻑ ﻭﺃﻧﺖ ﺍﳉﻮﻱ، ﺍﻟﻐﻼﻑ ﺇﱃ ﻃﻘﺲ ﺑﺎﻟﻮﻥ ﺣﻠﻞ .16 V ﺿﻐﻄﻪ ﻋﻨﺪ ﺛﺒﻮﺕ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ . TV T ﻳsﻨ’sacﺺsﻗuﺎLﻧ-ﻮayﻥGﺷﺎﺭﻝ ﻋﲆ ﺃﻥ ﺣ ’sﺠleﻢyﻣoﻘBﺪﺍﺭﻭﺩﺭﺟﺔﺣﺮﺍﺭﺗﻪﻭﺿﻐﻂﺍﳍﻮﺍﺀﻓﻴﻪ.ﻣﺎﺍﳌﻌﻠﻮﻣﺎﺕﺍﻟﺘﻲﲢﺘﺎﺝﺇﻟﻴﻬﺎﳊﺴﺎﺏﺍﳊﺠﻢﺍﻟﻨﻬﺎﺋﻲﻟﻠﺒﺎﻟﻮﻥ ﻋﻨﺪﻣﺎ ﻳﺼﻞ ﺇﱃ ﺃﻗﴡ ﺍﺭﺗﻔﺎﻉ ﻟﻪ؟ ﻭﺃﻱ ﺍﻟﻘﻮﺍﻧﲔ ﺗﺴﺘﺨﺪﻡ ﳊﺴﺎﺏ ﺍﳊﺠﻢ؟ ﳏ ﹼﺪﺩ ﻣﻦ ﺍﻟﻐﺎﺯ ﻳﺘﻨﺎﺳﺐ ﻃﺮﺩ ﹼﹰﻳﺎ ﻣﻊ ﺩﺭﺟﺔﺣﺮﺍﺭﺗﻪ ﺍﳌﻄﻠﻘﺔ ﻋﻨﺪ ﺛﺒﻮﺕ ﺍﻟﻀﻐﻂ .17 .ﺍﺳﺘﻨﺘﺞ ﳌﺎﺫﺍ ﹸﺗﻀﻐﻂ ﺍﻟﻐﺎﺯﺍﺕ ﺍTﻟﺘﻲc’sﺗsaﺴsﺘLuﺨy-ﺪaﻡGﰲ ﺍVﳌﺴﺘTﺸﻔﻴﺎ ’sﺕoy،leﻭBﻣﻨﻬﺎ ﺍ Vﻷﻛﺴﺠﲔ؟ﻭﳌﺎﺫﺍ ﳚﺐ ﲪﺎﻳﺘﻬﺎ ﻣﻦ ﺍﺭﺗﻔﺎﻉ ﺩﺭﺟﺎﺕ ﺍﳊﺮﺍﺭﺓ ؟ ﻭﻣﺎﺫﺍ ﳚﺐ ﺃﻥ ﳛﺪﺙ ﻟﻸﻛﺴﺠﲔ ﻳﻨﺺ ﻗﺎﻧﻮﻥ ﺟﺎﻱ -ﻟﻮﺳﺎﻙ ﻋﲆ ﺃﻥ ﺍﳌﻀﻐﻮﻁ ﻗﺒﻞ ﺍﺳﺘﻨﺸﺎﻗﻪ؟ ﺿﻐﻂ ﻣﻘﺪﺍﺭ ﳏ ﹼﺪﺩ ﻣﻦ ﺍﻟﻐﺎﺯ ﻳﺘﻨﺎﺳﺐﻃﺮﺩ ﹼﹰﻳﺎ ﻣﻊ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺍﳌﻄﻠﻘﺔ ﻋﻨﺪ .18ﺍﺣﺴﺐ ﳛﺘﻮﻱ ﺇﻧﺎﺀ ﺑﻼﺳﺘﻴﻜﻲ ﺻﻠﺐ ﻋﲆ 1.00 Lﻣﻦ ﻏﺎﺯ ﺍﳌﻴﺜﺎﻥ ﻋﻨﺪ ﺿﻐﻂ ﺟﻮﻱﻣﻘﺪﺍﺭﻩ ،660 torrﻭﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ، 22.0˚Cﻣﺎ ﻣﻘﺪﺍﺭ ﺍﻟﻀﻐﻂ ﺍﻟﺬﻱ ﳛﺪﺛﻪ ﺍﻟﻐﺎﺯ ﺛﺒﻮﺕ ﺍﳊﺠﻢ. ﻋﻨﺪ ﺍﺭﺗﻔﺎﻉ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺇﱃ 44.6˚C؟ ﻳﺮﺑﻂ ﺍﻟﻘﺎﻧﻮﻥ ﺍﻟﻌﺎﻡ ﻟﻠﻐﺎﺯﺍﺕ ﺑﲔﺍﻟﻀﻐﻂ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻭﺍﳊﺠﻢ ﰲ .19ﺻ ﹼﻤﻢ ﺧﺮﻳﻄﺔ ﻣﻔﺎﻫﻴﻤﻴﺔ ﺗﻮ ﹼﺿﺢ ﻓﻴﻬﺎ ﺍﻟﻌﻼﻗﺎﺕ ﺑﲔ ﺍﻟﻀﻐﻂ ﻭﺍﳊﺠﻢ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﰲ ﻗﻮﺍﻧﲔ ﺑﻮﻳﻞ ،ﻭﺷﺎﺭﻝ ،ﻭﺟﺎﻱ -ﻟﻮﺳﺎﻙ. ﻣﻌﺎﺩﻟﺔ ﻭﺍﺣﺪﺓ. 100
7-2اﻟﻔﻜﺮة اﻟﺮﺋﻴﺴﺔ ﻗﺎﻧﻮن اﻟﻐﺎز اﻟﻤﺜﺎﻟﻲ The Ideal Gas Law ا ﻫﺪاف ﺗﻌﻠﻢ ﺃﻥ ﺇﺿﺎﻓﺔ ﺍﳍﻮﺍﺀ ﺇﱃ ﺇﻃﺎﺭ ﺍﻟﺴﻴﺎﺭﺓ ﻳﺰﻳﺪ ﻣﻦ ﺿﻐﻂ ﺍﳍﻮﺍﺀ ﰲ ﺍﻹﻃﺎﺭ، ﻋﺪﺩ ﺍﳉﺴﻴﲈﺕ ﺑﺎﳊﺠﻢﻭﻟﻜـﻦ ﻫـﻞ ﺗﻌﻠﻢ ﺃﻥ ﻗﻴﻤﺔ ﺍﻟﻀﻐﻂ ﺍﳌﺤﺪﺩﺓ ﻟﻺﻃﺎﺭ ﻫﻲ ﻗﻴﻤﺔ ﺍﻟﻀﻐﻂ ﰲ ﺍﻹﻃﺎﺭ ﻋﻨﺪﻣﺎ ﻳﻜﻮﻥ ﻣﺴﺘﺨﺪ ﹰﻣﺎ ﻣﺒﺪﺃ ﺃﻓﻮﺟﺎﺩﺭﻭ.ﺑـﺎﺭ ﹰﺩﺍ؟ ﻓﻌﻨﺪﻣـﺎ ﺗﺘﺤﺮﻙ ﺇﻃﺎﺭﺍﺕ ﺍﻟﺴـﻴﺎﺭﺍﺕ ﻋـﲆ ﺍﻟﻄﺮﻳﻖ ﻳﻌﻤﻞ ﺍﻻﺣﺘـﻜﺎﻙ ﻋﲆ ﺭﻓﻊ ﺩﺭﺟﺔ ﻛﻤﻴـﺔ ﺍﻟﻐـﺎﺯ ﺑﻀﻐـﻄﻪ ﺍﳊﺮﺍﺭﺓ ،ﻓﻴﺰﻳﺪ ﺍﻟﻀﻐﻂ. ﻭﺩﺭﺟـــﺔ ﺣــﺮﺍﺭﺗــﻪ ﻭﺣﺠﻤﻪ ﻣﺴﺘﺨﺪ ﹰﻣﺎ ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ. ﺑﲔ ﺧﺼـﺎﺋـﺺ ﺍﻟﻐـﺎﺯ ﻣﺒﺪأ أﻓﻮﺟﺎدرو Avogadro’s Principle ﺍﳊﻘﻴﻘﻲ ﻭﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ.ﲣﺘﻠﻒ ﺣﺠﻮﻡ ﺟﺴﻴﲈﺕ ﺍﻟﻐﺎﺯﺍﺕ ،ﻭﻣﻊ ﺫﻟﻚ ﺗﻔﱰﺽ ﻧﻈﺮﻳﺔ ﺍﳊﺮﻛﺔ ﺍﳉﺰﻳﺌﻴﺔ ﺃﻥ ﺟﺴﻴﲈﺕ ﻣﺮاﺟﻌﺔ اﻟﻤﻔﺮداتﺍﻟﻐﺎﺯ ﰲ ﺃﻱ ﻋﻴﻨﺔ ﺗﻜﻮﻥ ﻣﺘﺒﺎﻋﺪﺓ ﻛﺜ ﹰﲑﺍ ﺟ ﹰﹼﺪﺍ ،ﺑﺤﻴﺚ ﻳﺼﺒﺢ ﺗﺄﺛﲑ ﺣﺠﻢ ﺍﳉﺴﻴﲈﺕ ﻗﻠﻴ ﹰﻼ ﻭﺣﺪﺓ ﻗﻴﺎﺳـﻴـﺔ ﺩﻭﻟﻴـﺔﺟ ﹰﹼﺪﺍ ﻋﲆ ﺍﳊﺠﻢ ﺍﻟﺬﻱ ﻳﺸﻐﻠﻪ ﺍﻟﻐﺎﺯ .ﻓﻤﺜ ﹰﻼ ﻳﺸﻐﻞ 1000ﺟﺴﻴﻢ ﻣﻦ ﻏﺎﺯ ﺍﻟﻜﺮﺑﺘﻮﻥ ﺍﻟﻜﺒﲑﺓ ﺗﺴﺘﺨـﺪﻡ ﻟﻘﻴـﺎﺱ ﻛﻤﻴـﺔ ﺍﳌـﺎﺩﺓ،ﻧﺴﺒ ﹰﹼﻴﺎ ﺍﳊﺠﻢ ﻧﻔﺴﻪ ﻟـ 1000ﺟﺴﻴﻢ ﻣﻦ ﻏﺎﺯ ﺍﳍﻴﻠﻴﻮﻡ ﺍﻷﺻﻐﺮ ﺣﺠ ﹰﲈ ﻋﻨﺪ ﻧﻔﺲ ﺩﺭﺟﺔ ﻭﲤﺜﻞ ﻣـﻘـﺪﺍﺭ ﺍﳌـﺎﺩﺓ ﺍﻟﻨﻘـﻴـﺔﺍﳊﺮﺍﺭﺓ ﻭﺍﻟﻀﻐﻂ .ﻭﻛﺎﻥ ﺃﻓﻮﺟﺎﺩﺭﻭ ﰲ ﻋﺎﻡ 1811ﻡ ﺃﻭﻝ ﻣﻦ ﻗﺪﻡ ﻫﺬﻩ ﺍﻟﻔﻜﺮﺓ .ﻭﻳﻨﺺ ﻣﺒﺪﺃ ﺍﻟﺘﻲ ﲢﺘﻮﻱ ﻋﲆ 6.02 X 1023ﻣﻦﺃﻓﻮﺟﺎﺩﺭﻭ ﻋﲆ ﺃﻥ ﺍﳊﺠﻮﻡ ﺍﳌﺘﺴﺎﻭﻳﺔ ﻣﻦ ﺍﻟﻐﺎﺯﺍﺕ ﺍﳌﺨﺘﻠﻔﺔ ﲢﺘﻮﻱ ﺍﻟﻌﺪﺩ ﻧﻔﺴﻪ ﻣﻦ ﺍﳉﺴﻴﲈﺕ ﺍﳉﺴﻴﲈﺕ.ﻋﻨﺪ ﻧﻔﺲ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻭﺍﻟﻀﻐﻂ .ﻭﻳﺒﲔ ﺍﻟﺸﻜﻞ 7-5ﺣﺠﻮ ﹰﻣﺎ ﻣﺘﺴﺎﻭﻳﺔ ﻣﻦ ﺛﺎﲏ ﺃﻛﺴﻴﺪ اﻟﻤﻔﺮدات اﻟﺠﺪﻳﺪة ﺍﻟﻜﺮﺑﻮﻥ ﻭﺍﳍﻴﻠﻴﻮﻡ ﻭﺍﻷﻛﺴﺠﲔ. ﻣﺒﺪﺃ ﺃﻓﻮﺟﺎﺩﺭﻭ ﺩﺭﺳـﺖ ﺳـﺎﺑ ﹰﻘﺎ ﺃﻥ ﺍﳌـﻮﻝ ﺍﻟﻮﺍﺣـﺪ ﻣـﻦ ﺃﻱ ﻣـﺎﺩﺓ ﳛﺘـﻮﻱ ﻋـﲆ ﺍﳊﺠﻢ ﺍﳌﻮﻻﺭﻱ 6.02 × 1023ﻣﻦ ﺍﳉﺴـﻴﲈﺕ .ﻭﺍﳊﺠﻢ ﺍﳌﻮﻻﺭﻱ ﻟﻐﺎﺯ ﻫﻮ ﺍﳊﺠﻢ ﺍﻟﺬﻱ ﻳﺸـﻐﻠﻪ 1 molﻣﻨﻪ ﺛﺎﺑﺖ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ )(R ﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ،0.0˚Cﻭﺿﻐﻂ ﺟﻮﻱ .1atm ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄﻭﺗﻌﺮﻑ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ 0.0˚Cﻭﺍﻟﻀﻐﻂ ﺍﳉﻮﻱ 1atmﺑﺪﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻭﺍﻟﻀﻐﻂ ﺍﳌﻌﻴﺎﺭﻳﲔ.ﻫﺬﺍ ﻭﻗﺪ ﺑ ﱠﲔ ﺃﻓﻮﺟﺎﺩﺭﻭ ﺃﻥ 1molﻣﻦ ﺃﻱ ﻏﺎﺯ ﻳﺸﻐﻞ ﺣﺠ ﹰﲈ ﻣﻘﺪﺍﺭﻩ ،22.4 Lﻟﺬﺍ ﻳﻤﻜﻨﻚﺍﺳﺘﻌﲈﻝ 22.4 L/molﺑﻮﺻﻔﻪ ﻣﻌﺎﻣﻞ ﲢﻮﻳﻞ ﻋﻨﺪﻣﺎ ﻳﻜﻮﻥ ﺍﻟﻐﺎﺯ ﰲ ﺍﻟﻈﺮﻭﻑ ﺍﳌﻌﻴﺎﺭﻳﺔ .ﻓﺈﺫﺍﺭﻏﺒﺖ ﻣﺜ ﹰﻼ ﰲ ﻣﻌﺮﻓﺔ ﻋﺪﺩ ﺍﳌﻮﻻﺕ ﰲ ﻋﻴﻨﺔ ﻣﻦ ﻏﺎﺯ ﺣﺠﻤﻬﺎ ، 3.72 Lﰲ ﺍﻟﻈﺮﻭﻑ ﺍﳌﻌﻴﺎﺭﻳﺔ، ﻓﻴﺘﻌﲔ ﻋﻠﻴﻚ ﺍﺳﺘﺨﺪﺍﻡ ﺍﳊﺠﻢ ﺍﳌﻮﻻﺭﻱ ﻟﺘﺤﻮﻳﻞ ﻭﺣﺪﺍﺕ ﺍﳊﺠﻢ ﺇﱃ ﻣﻮﻻﺕ. 3.72 L × _1 mol = 0.166 mol 22.4 L 7-5 101
75 ﺍﳌﻜﻮﻥ ﺍﻟﺮﺋﻴﺲ ﻟﻠﻐﺎﺯ ﺍﻟﻄﺒﻴﻌﻲ ﺍﳌﺴﺘﺨﺪﻡ ﰲ ﺍﳌﻨﺎﺯﻝ ﻷﻏﺮﺍﺽ ﺍﻟﺘﺪﻓﺌﺔ ﻭﺍﻟﻄﻬﻮ ﻫﻮ ﺍﳌﻴﺜﺎﻥ .CH4ﺍﺣﺴﺐ ﺣﺠﻢ 2.00 Kgﻣﻦ ﻏﺎﺯ ﺍﳌﻴﺜﺎﻥ ﰲ ﺍﻟﻈﺮﻭﻑ ﺍﳌﻌﻴﺎﺭﻳﺔ .STP 1ﺗﺤﻠﻴﻞ اﻟﻤﺴﺄﻟﺔﻳﻤﻜﻦ ﺣﺴﺎﺏ ﻋﺪﺩ ﺍﳌﻮﻻﺕ ﻣﻦ ﺧﻼﻝ ﻗﺴﻤﺔ ﻛﺘﻠﺔ ﺍﻟﻌﻴﻨﺔ ) (mﻋﲆ ﺍﻟﻜﺘﻠﺔ ﺍﳌﻮﻟﻴﺔ .Mﻭﻷﻥ ﺍﻟﻐﺎﺯ ﲢﺖ ﺍﻟﻈﺮﻭﻑ ﺍﳌﻌﻴﺎﺭﻳﺔ ) ،(STPﻟﺬﺍ ﻳﻤﻜﻨﻚ ﺍﺳﺘﺨﺪﺍﻡ ﺍﳊﺠﻢ ﺍﳌﻮﻻﺭﻱ ﻟﺘﺤﻮﻳﻞ ﻋﺪﺩ ﺍﳌﻮﻻﺕ ﺇﱃ ﺣﺠﻢ. V=?L m = 2.00 kg T = 0.00 ˚C P = 1.00 atm 2ﺣﺴﺎب اﻟﻤﻄﻠﻮب( ) ( )M = 1 C atom ﺣ ﹼﺪﺩ ﺍﻟﻜﺘﻠﺔ ﺍﳌﻮﻟﻴﺔ ﻟﻠﻤﻴﺜﺎﻥ _12.01 amu + 4 H atoms _1.01 amu 1 C atom 1 H atom = 12.01 amu + 4.04 amu = 16.05 amu = 16.05 g/mol gmol ( )2.00 kg ﺣ ﹼﺪﺩ ﻋﺪﺩ ﻣﻮﻻﺕ ﺍﳌﻴﺜﺎﻥ _1000 g = 2.00 × 103 g g Kg 1 kg _m = _2.00 ×_103 g = 125 mol M 16.05 g/mol ﺍﺳﺘﺨﺪﻡ ﺍﳊﺠﻢ ﺍﳌﻮﻻﺭﻱ ﻟﺘﺤﺪﻳﺪ ﺣﺠﻢ ﺍﳌﻴﺜﺎﻥ ﰲ ﺍﻟﻈﺮﻭﻑ ﺍﳌﻌﻴﺎﺭﻳﺔ .STP _22.4 LV = 125 mol × = 2.80 × 10 3 L 22.4Lmol 1 mol 3ﺗﻘﻮﻳﻢ ا ﺟﺎﺑﺔﻣﻘﺪﺍﺭ ﺍﳌﻴﺜﺎﻥ ﺍﳌﻮﺟﻮﺩ ﺃﻛﱪ ﻣﻦ 1 mol؛ ﻟﺬﺍ ﳚﺐ ﺃﻥ ﺗﺘﻮﻗﻊ ﺣﺠ ﹰﲈ ﻛﺒ ﹰﲑﺍ ،ﻭﻫﺬﺍ ﻳﺘﻔﻖ ﻣﻊ ﺍﻹﺟﺎﺑﺔ .ﺍﻟﻮﺣﺪﺓ ﻫﻲ ) ،( Lﻭﻫﻲ ﻭﺣﺪﺓ ﻗﻴﺎﺱ ﺍﳊﺠﻢ ،ﻭﻫﻨﺎﻙ ﺛﻼﺛﺔ ﺃﺭﻗﺎﻡ ﻣﻌﻨﻮﻳﺔ. .20ﻣﺎ ﺣﺠﻢ ﺍﻟﻮﻋﺎﺀ ﺍﻟﻼﺯﻡ ﻻﺣﺘﻮﺍﺀ 0.0459 molﻣﻦ ﻏﺎﺯ ﺍﻟﻨﻴﱰﻭﺟﲔ N2ﰲ ﺍﻟﻈﺮﻭﻑ ﺍﳌﻌﻴﺎﺭﻳﺔ STP؟ .21ﻣﺎ ﻛﺘﻠﺔ ﻏﺎﺯ ﺛﺎﲏ ﺃﻛﺴﻴﺪ ﺍﻟﻜﺮﺑﻮﻥ ﺑﺎﳉﺮﺍﻣﺎﺕ ،ﺍﳌﻮﺟﻮﺩﺓ ﰲ ﺑﺎﻟﻮﻥ ﺣﺠﻤﻪ 1.0 Lﰲ ﺍﻟﻈﺮﻭﻑ ﺍﳌﻌﻴﺎﺭﻳﺔ STP؟ .22ﻣﺎ ﺍﳊﻴﺰ ) ،(mlﺍﻟﺬﻱ ﻳﺸﻐﻠﻪ ﻏﺎﺯ ﺍﳍﻴﺪﺭﻭﺟﲔ ﺍﻟﺬﻱ ﻛﺘﻠﺘﻪ 0.00922 gﰲ ﺍﻟﻈﺮﻭﻑ ﺍﳌﻌﻴﺎﺭﻳﺔ STP؟ .23ﻣﺎ ﺍﳊﺠﻢ ﺍﻟﺬﻱ ﺗﺸﻐﻠﻪ ﻛﺘﻠﺔ ﻣﻘﺪﺍﺭﻫﺎ 0.416 gﻣﻦ ﻏﺎﺯ ﺍﻟﻜﺮﺑﺘﻮﻥ ﰲ ﺍﻟﻈﺮﻭﻑ ﺍﻟﻘﻴﺎﺳﻴﺔ STP؟ .24ﺍﺣﺴﺐ ﺍﳊﺠﻢ ﺍﻟﺬﻱ ﺗﺸﻐﻠﻪ ﻛﺘﻠﺔ ﻣﻘﺪﺍﺭﻫﺎ 4.5 Kgﻣﻦ ﻏﺎﺯ ﺍﻹﻳﺜﻴﻠﲔ C2H4ﰲ ﺍﻟﻈﺮﻭﻑ ﺍﳌﻌﻴﺎﺭﻳﺔ STP؟ .25ﺇﻧﺎﺀ ﺑﻼﺳﺘﻴﻜﻲ ﻣﺮﻥ ﳛﺘﻮﻱ 0.86 gﻣﻦ ﻏﺎﺯ ﺍﳍﻴﻠﻴﻮﻡ ﺑﺤﺠﻢ ) .(19.2 Lﻓﺈﺫﺍ ﹸﺃﺧﺮﺝ 0.205 gﻣﻦ ﻏﺎﺯ ﺍﳍﻴﻠﻴﻮﻡ ﻋﻨﺪ ﺿﻐﻂ ﻭﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ﺛﺎﺑﺘﲔ ،ﻓﲈ ﺍﳊﺠﻢ ﺍﳉﺪﻳﺪ؟ 102
ﻗﺎﻧﻮن اﻟﻐﺎز اﻟﻤﺜﺎﻟﻲ The Ideal Gas Law ﻳﻤﻜﻦ ﲨﻊ ﻛﻞ ﻣﻦ ﻣﺒﺪﺃ ﺃﻓﻮﺟﺎﺩﺭﻭ ﻭﻗﻮﺍﻧﲔ ﺑﻮﻳﻞ ﻭﺷﺎﺭﻝ ﻭﺟﺎﻱ -ﻟﻮﺳﺎﻙ ﰲ ﻋﻼﻗﺔ ﺭﻳﺎﺿﻴﺔ ﻭﺍﺣﺪﺓ ﺗﺼﻒ ﺍﻟﻌﻼﻗﺔ ﺑﲔ ﺍﻟﻀﻐﻂ ﻭﺍﳊﺠﻢ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻭﻋﺪﺩ ﻣﻮﻻﺕ ﺍﻟﻐﺎﺯ. ﺗﻌﻄﻲ ﻫﺬﻩ ﺍﻟﺼﻴﻐﺔ ﻧﺘﺎﺋﺞ ﺃﻓﻀﻞ ﻟﻠﻐﺎﺯﺍﺕ ﺍﻟﺘﻲ ﺗﻨﻄﺒﻖ ﻋﻠﻴﻬﺎ ﺍﻓﱰﺍﺿﺎﺕ ﻧﻈﺮﻳﺔ ﺍﳊﺮﻛﺔ ﺍﳉﺰﻳﺌﻴﺔ ،ﺍﻟﺘﻲ ﺗﻌﺮﻑ ﺑﺎﻟﻐﺎﺯﺍﺕ ﺍﳌﺜﺎﻟﻴﺔ .ﺇﻥ ﺣﺠﻮﻡ ﺟﺴﻴﲈﺕ ﺍﻟﻐﺎﺯﺍﺕ ﺻﻐﲑﺓ ﺟ ﹰﹼﺪﺍ ،ﻭﺑﻴﻨﻬﺎ ﻓﺮﺍﻏﺎﺕ ﻛﺒﲑﺓ ﻟﺪﺭﺟﺔ ﺃﻥ ﻗﻮ ﺍﻟﺘﺠﺎﺫﺏ ﺃﻭ ﺍﻟﺘﻨﺎﻓﺮ ﻓﻴﲈ ﺑﻴﻨﻬﺎ ﺗﺼﺒﺢ ﺃﻗﻞ ﻣﺎ ﻳﻤﻜﻦ. ﻳﺮﺑﻂ ﺍﻟﻘﺎﻧﻮﻥ ﺍﻟﻌﺎﻡ ﻟﻠﻐﺎﺯﺍﺕ ﺑﲔ ﻣﺘﻐﲑﺍﺕ ﺍﻟﻀﻐﻂ ﻭﺍﳊﺠﻢ ﻭ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﳌﻘﺪﺍﺭ ﳏ ﹼﺪﺩ ﻣﻦ ﺍﻟﻐﺎﺯ. _P1V1 = _P2V2 T1 T2 ﻭﺗﺒﻘﻰ ﻋﻼﻗﺔ ﺍﻟﻀﻐﻂ ﻭﺍﳊﺠﻢ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺩﺍﺋ ﹰﲈ ﻧﻔﺴﻬﺎ ﻟﻌﻴﻨﺔ ﳏ ﹼﺪﺩﺓ ﻣﻦ ﺍﻟﻐﺎﺯ .ﻭﻳﻤﻜﻦ 7-6 ﺇﻋﺎﺩﺓ ﻛﺘﺎﺑﺔ ﺍﻟﻌﻼﻗﺔ ﺍﳌﻤﺜﻠﺔ ﰲ ﺍﻟﻘﺎﻧﻮﻥ ﺍﻟﻌﺎﻡ ﻟﻠﻐﺎﺯﺍﺕ ﻋﲆ ﺍﻟﻨﺤﻮ ﺍﻵﰐ : ﺛﺎﺑ ﹰﺘﺎ ﻣﻘﺪﺍ ﹰﺭﺍ = _PV T اﻟﻤﻄﻮﻳﺎت ﻳﻮ ﹼﺿﺢ ﺍﻟﺸﻜﻞ 7-6ﺃﻥ ﺯﻳﺎﺩﺓ ﻣﻘﺪﺍﺭ ﺍﻟﻐﺎﺯ ﺍﳌﻮﺟﻮﺩ ﰲ ﺍﻟﻌﻴﻨﺔ ﻳﺆﺩﻱ ﺇﱃ ﺯﻳﺎﺩﺓ ﺍﻟﻀﻐﻂ ،ﺇﺫﺍﺃﺩﺧﻞ ﻣﻌﻠﻮﻣﺎﺕ ﻣﻦ ﻫﺬﺍ ﺍﻟﻘﺴﻢ ﻛﺎﻧﺖ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻭﺍﳊﺠﻢ ﺛﺎﺑﺘﲔ ،ﻛﲈ ﺃ ﹼﻥ ﺍﳊﺠﻢ ﻳﺰﺩﺍﺩ ﻋﻨﺪ ﺇﺿﺎﻓﺔ ﺍﳌﺰﻳﺪ ﻣﻦ ﺟﺴﻴﲈﺕ ﰲ ﻣﻄﻮﻳﺘﻚ. ﺍﻟﻐﺎﺯ .ﻭﻧﺤﻦ ﻧﻌﺮﻑ ﺃﻥ ﻛ ﹰﹼﻼ ﻣﻦ ﺍﳊﺠﻢ ﻭﺍﻟﻀﻐﻂ ﻳﺘﻨﺎﺳﺒﺎﻥ ﺗﻨﺎﺳ ﹰﺒﺎ ﻃﺮﺩ ﹼﹰﻳﺎ ﻣﻊ ﻋﺪﺩ ﺍﳌﻮﻻﺕ ) ،(nﻟﺬﺍ ﻳﻤﻜﻦ ﻭﺿﻊ ﻋﺪﺩ ﺍﳌﻮﻻﺕ ) (nﰲ ﻣﻌﺎﺩﻟﺔ ﺍﻟﻘﺎﻧﻮﻥ ﺍﻟﻌﺎﻡ ﻟﻠﻐﺎﺯﺍﺕ ،ﻛﲈ ﻳﺄﰐ: ﺛﺎﺑ ﹰﺘﺎ = _PV nT ﻭﻟﻘﺪ ﺣﺪﺩﺕ ﺍﻟﺘﺠﺎﺭﺏ ﺍﻟﺘﻲ ﺍﺳﺘﺨﺪﻣﺖ ﻓﻴﻬﺎ ﻗﻴﻢ ﻣﻌﺮﻭﻓﺔ ﻟﻜﻞ ﻣﻦ V، T،P.nﻗﻴﻤﺔ ﻫﺬﺍ ﺍﻟﺜﺎﺑﺖ ،ﻭﺍﻟﺬﻱ ﻳﻌﺮﻑ ﺑﺜﺎﺑﺖ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ ،ﻭﻳﺮﻣﺰ ﻟﻪ ﺑﺎﻟﺮﻣﺰ .Rﻓﺈﺫﺍ ﻛﺎﻥ ﺍﻟﻀﻐﻂ ﻣﻘﻴ ﹰﺴﺎ ﺑﻮﺣﺪﺓ atmﻓﺈﻥ ﻗﻴﻤﺔ Rﻫﻲ . 0.0821 L.atm/mol.K ﻻﺣﻆ ﺃﻥ ﻭﺣﺪﺓ Rﲡﻤﻊ ﺑﺒﺴﺎﻃﺔ ﻭﺣﺪﺍﺕ ﺍﳌﺘﻐﲑﺍﺕ ﺍﻷﺭﺑﻊ .ﻭﻳﺒﲔ ﺍﳉﺪﻭﻝ 7-2ﺍﻟﻘﻴﻢ ﺍﻟﺮﻗﻤﻴﺔ ﻟـ Rﺑﻮﺣﺪﺍﺕ ﳐﺘﻠﻔﺔ ﻟﻠﻀﻐﻂ. ﳌﺎﺫﺍ ﺃﺿﻴﻒ ﻋﺪﺩ ﺍﳌﻮﻻﺕ ) (nﺇﱃ ﺍﳌﻘﺎﻡ ﰲ ﺍﳌﻌﺎﺩﻟﺔ ﺃﻋﻼﻩ؟ ﻋﻨﺪ ﺍﻟﺘﻌﻮﻳﺾ ﻋﻦ Rﰲ ﺍﳌﻌﺎﺩﻟﺔ ﺃﻋﻼﻩ ،ﻭﻋﻨﺪ ﺇﻋﺎﺩﺓ ﺗﺮﺗﻴﺐ ﺍﳌﺘﻐﲑﺍﺕ ﺗﻨﺘﺞ ﺍﻟﺼﻴﻐﺔ ﺍﻷﻛﺜﺮ R 72 ﺷﻴﻮ ﹰﻋﺎ ﻟﻘﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ؛ ﺣﻴﺚ ﻳﺼﻒ ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ ﺍﻟﺴﻠﻮﻙ ﺍﻟﻔﻴﺰﻳﺎﺋﻲ ﻟﻠﻐﺎﺯ ﺍﳌﺜﺎﱄ ﻣﻦ ﺣﻴﺚ ﺍﻟﻀﻐﻂ ﻭﺍﳊﺠﻢ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻭﻋﺪﺩ ﻣﻮﻻﺕ ﺍﻟﻐﺎﺯ ﺍﳌﺘﻮﺍﻓﺮﺓ. R R ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ _L·atm 0.0821 P V mol·K n PV = nRT R _L·kPa 8.314 T mol·K_L·mmHg 62.4 ﺇﻥ ﺣﺎﺻﻞ ﴐﺏ ﺍﻟﻀﻐﻂ ﻭﺍﳊﺠﻢ ﰲ ﻣﻘﺪﺍﺭ ﻣﻌﲔ ﻣﻦ ﺍﻟﻐﺎﺯ ﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ﺛﺎﺑﺘﺔ ﻳﺴﺎﻭﻱ mol·K ﻣﻘﺪ ﹰﺭﺍ ﺛﺎﺑ ﹰﺘﺎ.103
76ﺍﺣﺴﺐ ﻋﺪﺩ ﻣﻮﻻﺕ ﻏﺎﺯ ﺍﻷﻣﻮﻧﻴﺎ NH3ﺍﳌﻮﺟﻮﺩﺓ ﰲ ﻭﻋﺎﺀ ﺣﺠﻤﻪ 3.0 Lﻋﻨﺪ 3.0 × 102 Kﻭﺿﻐﻂ ).(1.5 atm 1ﺗﺤﻠﻴﻞ اﻟﻤﺴﺄﻟﺔﺃﻋﻄﻴﺖ ﺍﳊﺠﻢ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻭﺍﻟﻀﻐﻂ ﻟﻌﻴﻨﺔ ﻣﻦ ﺍﻟﻐﺎﺯ .ﺍﺳﺘﺨﺪﻡ ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ ،ﻭﺍﺧﱰ ﻗﻴﻤﺔ ﺍﻟﺜﺎﺑﺖ Rﺑﺎﻻﻋﺘﲈﺩ ﻋﲆﻭﺣﺪﺓ ﺍﻟﻀﻐﻂ ﰲ ﺍﻟﺴـﺆﺍﻝ .ﻻﺣـﻆ ﺃ ﱠﻥ ﹺﻗﻴﻢ ﺍﻟﻀﻐﻂ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻗﺮﻳﺒﺔ ﻣﻦ ﺍﻟﻈﺮﻭﻑ ﺍﳌﻌﻴﺎﺭﻳﺔ ،ﻟﻜﻦ ﺍﳊﺠﻢ ﺃﺻﻐﺮ ﻛﺜ ﹰﲑﺍ ﻣﻦ ،22.4 Lﻓﻌﻠﻴﻚ ﺃﻥ ﺗﺘﻮﻗﻊ ﺃ ﹼﻥ ﺍﻹﺟﺎﺑﺔ ﺃﻗﻞ ﻛﺜ ﹰﲑﺍ ﻣﻦ ﻣﻮﻝ ﻭﺍﺣﺪ. n = ? mol V = 3.0 L T = 3.00 × 102 K P = 1.50 atm _L·atm R = 0.0821 mol·K 2ﺣﺴﺎب اﻟﻤﻄﻠﻮب ﺍﺳﺘﺨﺪﻡ ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ ،ﺛﻢ ﻋ ﱢﻮﺽ ﺑﺎﻟﻘﻴﻢ ﺍﳌﻌﺮﻭﻓﺔ ﻹﳚﺎﺩ ﻗﻴﻤﻪ )(n PV = nRT n = _PV n RT )_(1.5_0 atm)(3.0_L V3.0LT3.00× 102KP1.50atm =( )n R0.0821L·atmmol·K _L·atm 0.0821 (3.00 × )102 K mol·K= )_(1.5_0 atm)(3.0_L = 0.18 mol ( )n 0.0821 _L·atm (3.00 × 102 )K mol·K 3ﺗﻘﻮﻳﻢ ا ﺟﺎﺑﺔ ﺗﺘﻔﻖ ﺍﻹﺟﺎﺑﺔ ﻣﻊ ﺗﻮﻗﻊ ﺃ ﹼﻥ ﻋﺪﺩ ﺍﳌﻮﻻﺕ ﺃﻗﻞ ﻛﺜ ﹰﲑﺍ ﻣﻦ ، 1 molﻭﺣﺪﺓ ﺍﻹﺟﺎﺑﺔ ،molﻭﲢﺘﻮﻱ ﺭﻗﻤﲔ ﻣﻌﻨﻮﻳﲔ. .26ﻣﺎ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ 2.49 molﻣﻦ ﺍﻟﻐﺎﺯ ﺍﳌﻮﺟﻮﺩ ﰲ ﺇﻧﺎﺀ ﺳﻌﺘﻪ ، 1.00 Lﻭﲢﺖ ﺿﻐﻂ ﻣﻘﺪﺍﺭﻩ 143 KPa .27ﺍﺣﺴﺐ ﺣﺠﻢ 0.323 molﻣﻦ ﻏﺎﺯ ﻣﺎ ﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ 256 Kﻭﺿﻐﻂ ﺟﻮﻱ ﻣﻘﺪﺍﺭﻩ 0.90 atm .28ﻣــﺎ ﻣﻘﺪﺍﺭ ﺿﻐﻂ ، 0.108 molﺑـﻮﺣﺪﺓ ﺍﻟﻀﻐﻂ ﺍﳉﻮﻱ ) (atmـ ﻟﻌﻴﻨﺔ ﻣﻦ ﻏﺎﺯ ﺍﳍﻴﻠﻴﻮﻡ ﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ،20.0˚C ﺇﺫﺍ ﻛﺎﻥ ﺣﺠﻤﻬﺎ 0.050 L؟ .29ﺇﺫﺍ ﻛﺎﻥ ﺿﻐﻂ ﻏﺎﺯ ﺣﺠﻤﻪ 0.044 Lﻳﺴﺎﻭﻱ 3.81 atmﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ،25.0˚Cﻓﲈ ﻋﺪﺩ ﻣﻮﻻﺕ ﺍﻟﻐﺎﺯ؟ .30ﻏﺎﺯ ﻣﺜﺎﱄ ﺣﺠﻤﻪ ،3.0 Lﻓﺈﺫﺍ ﺗﻀﺎﻋﻒ ﻋﺪﺩ ﻣﻮﻻﺗﻪ ﻭﺩﺭﺟﺔ ﺣﺮﺍﺭﺗﻪ ﻭﺑﻘﻲ ﺍﻟﻀﻐﻂ ﺛﺎﺑ ﹰﺘﺎ ،ﻓﲈ ﺣﺠﻤﻪ ﺍﳉﺪﻳﺪ؟ 104
ﻗﺎﻧﻮن اﻟﻐﺎز اﻟﻤﺜﺎﻟﻲ -اﻟﻜﺘﻠﺔ اﻟﻤﻮﻟﻴﺔ واﻟﻜﺜﺎﻓﺔ The Ideal Gas Law - Molar Mass and Density ﺍﳌﻮﻝ Moleﺟﺎﺀﺕ ﻣﻦ ﺍﻟﻜﻠﻤﺔ ﺍﻷﳌﺎﻧﻴﺔ ،Molﻭﻫﻲ ﻳﻤﻜﻦ ﺃﻥ ﻳﺴﺘﺨﺪﻡ ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ ﰲ ﺇﳚﺎﺩ ﺃﻱ ﻗﻴﻤﺔ ﻣﻦ ﻗﻴﻢ ﺍﳌﺘﻐﲑﺍﺕ ﺍﻷﺭﺑﻌﺔﺍﺧﺘﺼـﺎﺭ ،Molekulargewicht ،P،V،T،nﺇﺫﺍ ﻛﺎﻧﺖ ﺍﻟﻘﻴﻢ ﺍﻟﺜﻼﺙ ﺍﻷﺧﺮ ﻣﻌﺮﻭﻓﺔ .ﻛﲈ ﻳﻤﻜﻦ ﺇﻋﺎﺩﺓ ﺗﺮﺗﻴﺐ ﺍﳌﻌﺎﺩﻟﺔ ﻭﺗﻌﻨﻲ ﺍﻟﻮﺯﻥ ﺍﳉﺰﻳﺌﻲ. PV=nRTﳊﺴﺎﺏ ﺍﻟﻜﺘﻠﺔ ﺍﳌﻮﻟﻴﺔ ﻭﺍﻟﻜﺜﺎﻓﺔ ﻟﻌﻴﻨﺔ ﻣﻦ ﺍﻟﻐﺎﺯ. ﻹﳚﺎﺩ ﺍﻟﻜﺘﻠﺔ ﺍﳌﻮﻟﻴﺔ ﻟﻌﻴﻨﺔ ﻏﺎﺯ ﳚﺐ ﺃﻥ ﻳﻜﻮﻥ ﻛ ﹼﹰﻼ ﻣﻦ ﺍﻟﻜﺘﻠﺔ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻭﺍﻟﻀﻐﻂ ﻭﺣﺠﻢ ﺍﻟﻐﺎﺯ ﻣﻌﺮﻭ ﹰﻓﺎ .ﺗﺬﻛﺮ ﻣﺎ ﺗﻌﻠﻤﺘﻪ ﺳﺎﺑ ﹰﻘﺎ ،ﺣﻴﺚ ﺇﻥ ﻋﺪﺩ ﻣﻮﻻﺕ ﺍﻟﻐﺎﺯ) (nﺗﺴﺎﻭﻱ ﺍﻟﻜﺘﻠﺔ ) (mﻣﻘﺴﻮﻣﺔ ﻋﲆ ﺍﻟﻜﺘﻠﺔ ﺍﳌﻮﻟﻴﺔ ) .(Mﻟﺬﻟﻚ ﻳﻤﻜﻦ ﺍﻟﺘﻌﻮﻳﺾ ﻋﻦ nﺑﻤﻘﺪﺍﺭ . m/M PV = nRT n = _m PV = _mRT M M ﻭﻳﻤﻜﻨﻚ ﺇﻋﺎﺩﺓ ﺗﺮﺗﻴﺐ ﺍﳌﻌﺎﺩﻟﺔ ﻟﺘﺼﺒﺢ ﻋﲆ ﺍﻟﻨﺤﻮ ﺍﻵﰐ: M = _mRT PV ﺗﺬﻛﺮ ﺃﻥ ﻛﺜﺎﻓﺔ ﺃﻱ ﻣﺎﺩﺓ ) (Dﺗﺴـﺎﻭﻱ ﻛﺘﻠﺘﻬﺎ ) (mﰲ ﻭﺣـﺪﺓ ﺍﳊﺠﻮﻡ ) ،(Vﻭﺑﻌﺪ ﺇﻋﺎﺩﺓ ﺗﺮﺗﻴﺐ ﻣﻌﺎﺩﻟﺔ ﺍﻟﻐـﺎﺯ ﺍﳌﺜﺎﱄ ﻹﳚﺎﺩ ﺍﻟﻜﺘﻠﺔ ﺍﳌﻮﻟﻴﺔ ﻳﻤﻜﻦ ﺍﻟﺘﻌﻮﻳﺾ ﻋﻦ ) (m/Vﺑﺎﻟﻘﻴﻤﺔ . D M = _mRT D=_mV M = _DRT PV P ﻳﻤﻜﻨﻚ ﺇﻋﺎﺩﺓ ﺗﺮﺗﻴﺐ ﺍﳌﻌﺎﺩﻟﺔ ﻹﳚﺎﺩ ﺍﻟﻜﺜﺎﻓﺔ ﻟﺘﺼﺒﺢ ﻋﲆ ﺍﻟﻨﺤﻮ ﺍﻟﺘﺎﱄ: D = _MP RT ﳌﺎﺫﺍ ﲢﺘﺎﺝ ﺇﱃ ﻣﻌﺮﻓﺔ ﻛﺜﺎﻓﺔ ﺍﻟﻐﺎﺯ؟ ﻓﻜﺮ ﰲ ﻃﺮﺍﺋﻖ ﺇﻃﻔﺎﺀ ﺍﳊﺮﻳﻖ .ﺗﻌﺘﻤﺪ ﺇﺣﺪ ﻃﺮﺍﺋﻖ ﺇﻃﻔﺎﺀ ﺍﳊﺮﻳﻖ ﻋﲆ ﻣﻨﻊ ﻏﺎﺯ ﺍﻷﻛﺴﺠﲔ ﻣﻦ ﺍﻟﻮﺻﻮﻝ ﻣﻦ ﺧﻼﻝ ﺗﻐﻄﻴﺔ ﺍﳊﺮﻳﻖ ﺑﻐﺎﺯ ﺁﺧﺮ ﻻ ﳛﱰﻕ ﻭﻻ ﻳﺴﺎﻋﺪ ﻋﲆ ﺍﻻﺣﱰﺍﻕ ،ﻛﲈ ﻫﻮ ﻣﻮﺿﺢ ﰲ ﺍﻟﺸﻜﻞ .7-7ﻟﺬﺍ ﳚﺐ ﺃﻥ ﺗﻜﻮﻥ ﻛﺜﺎﻓﺔ ﻫﺬﺍ ﺍﻟﻐﺎﺯ ﺃﻛﱪ ﻣﻦ ﻛﺜﺎﻓﺔ ﺍﻷﻛﺴﺠﲔ ﻟﻴﺤﻞ ﳏﻠﻪ. 7-7 105
ﻻ ﲡﻌﻞ ﳖﺎﻳﺔ ﻃﺮﻑ ﺍﻷﺳﻄﻮﺍﻧﺔ ﻳﻼﻣﺲ ﺍﻟﺸﻤﻌﺔ إﻋﺪاد ﻧﻤﻮذج ﻟﻄﻔﺎﻳﺔ ﺣﺮﻳﻖ ﳌﺎﺫﺍ ﻳﺴﺘﺨﺪﻡ ﻏﺎﺯ ﺛﺎﲏ ﺃﻛﺴﻴﺪ ﺍﻟﻜﺮﺑﻮﻥ ﻹﻃﻔﺎﺀ ﺍﳊﺮﻳﻖ؟ ﺍﳌﺸﺘﻌﻠﺔ. .7ﻭﺑﻴﻨـﲈ ﻳﺴـﺘﻤﺮ ﺍﻟﺘﻔﺎﻋـﻞ ﰲ ﺍﻟـﻜﺄﺱ ﰲ ﺇﻧﺘـﺎﺝ ﻏـﺎﺯ ﺛﺎﲏ اﻟﺨﻄﻮاتA B J L DFDKM EGEALNﺃECﻛCﺴKﻴIﺪBﺍDﻟBﻜJﺮﺑHAﻮACﻥ ،IﻣGﺮBﺭ ﺍﻟHﻐFﺎAﺯ ﺑGﺤEﺬﺭ ﺷFﺪDﻳﺪE،ﻭﻟﻴCﺲDﺍﻟBﺴﺎﺋCﻞA FHMFBO GNIGCP I .1NPNJﺍMﻗMOﺮﺃ ﺗLﻌHﻠLﻴNﲈﺕKGﺍMﻟKﺴ FﻼLJﻣJﺔ ﰲEIﺍKPﳌIﺨﺘDﱪH.JOH OOK PP ﰲ ﺍﻷﺳﻄﻮﺍﻧﺔ .ﺳﺠﻞ ﻣﻼﺣﻈﺎﺗﻚ. .2ﻗـﺲ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺑﺎﺳـﺘﺨﺪﺍﻡ ﻣﻘﻴﺎﺱ ﺍﳊـﺮﺍﺭﺓ ،ﻭﺍﻟﻀﻐﻂ ﺍﳉـﻮﻱ ﺑﺎﺳـﺘﺨﺪﺍﻡ ﺍﻟﺒﺎﺭﻭﻣـﱰ ،ﺛـﻢ ﺳـﺠﻞ ﺍﻟﺒﻴﺎﻧـﺎﺕ ﺍﻟﺘﻲ ﺣﺼﻠﺖ ﻋﻠﻴﻬﺎ. .3ﻟ ﹼﻒﻗﻄﻌﺔﻣـﻦﻭﺭﻕﺍﻟﻘﺼﺪﻳﺮﺃﺑﻌﺎﺩﻫﺎ 23cm×30cm ﺗﺤﻠﻴﻞ ﻋﲆ ﺃﺳـﻄﻮﺍﻧﺔ ﺍﺭﺗﻔﺎﻋﻬﺎ 30 cmﻭﻧﺼﻒ ﻗﻄﺮﻫﺎ 6 cm .1ﺍﺣﺴﺐ ﺍﳊﺠﻢ ﺍﳌﻮﻻﺭﻱ ﻟﻐﺎﺯ ﺛﺎﲏ ﺃﻛﺴﻴﺪ ﺍﻟﻜﺮﺑﻮﻥ ﺗﻘﺮﻳﺒ ﹰﺎ ﺛﻢ ﺃﻟﺼﻖ ﺃﻃﺮﺍﻑ ﻗﻄﻌﺔ ﺍﻟﻘﺼﺪﻳﺮ. CO2ﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ﺍﻟﻐﺮﻓﺔ ﻭﺍﻟﻀﻐﻂ ﺍﳉﻮﻱ ﺍﻟﻌﺎﺩﻱ. .4ﺍﺳﺘﺨﺪﻡ ﺃﻋﻮﺍﺩ ﺍﻟﺜﻘﺎﺏ ﻹﺷﻌﺎﻝ ﺍﻟﺸﻤﻌﺔ. .2ﻛﺜﺎﻓﺔ ﻛﻞ ﻣﻦ ﺛﺎﲏ ﺃﻛﺴﻴﺪ ﺍﻟﻜﺮﺑﻮﻥ ﻭﺍﻷﻛﺴﺠﲔ ﺍﺳـﻜﺐ ﺍﳌـﺎﺀ ﻓﻮﻕ ﺃﻋﻮﺍﺩ ﺍﻟﺜﻘـﺎﺏ ﻗﺒﻞ ﺭﻣﻴﻬﺎ، ﻭﺍﻟﻨﻴﱰﻭﺟﲔ ﺑﻮﺣﺪﺓ g/Lﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ﺍﻟﻐﺮﻓﺔ. ﻭﺍﺑﺘﻌﺪ ﻋﻦ ﻣﺼﺎﺩﺭ ﺍﻟﻠﻬﺐ. ﺗﺬﻛﺮ ﺃﻥ ﻋﻠﻴﻚ ﺣﺴﺎﺏ ﺍﻟﻜﺘﻠﺔ ﺍﳌﻮﻟﻴﺔ ﻟﻜﻞ ﻏﺎﺯ ﺣﺘﻰ .5ﺿـﻊ 30 gﻣﻦ ﺻـﻮﺩﺍ ﺍﳋﺒـﺰ NaHCO3ﰲ ﻛﺄﺱ ﻛﺒﲑﺓ، ﻭﺃﺿـﻒ ﺇﻟﻴﻬـﺎ 40 mlﻣـﻦ ﺍﳋـﻞ CH3COOHﺗﺮﻛﻴﺰﻩ ﺗﺘﻤﻜﻦ ﻣﻦ ﺣﺴﺎﺏ ﻛﺜﺎﻓﺔ ﻛﻞ ﻏﺎﺯ. ).(5% .3ﻫﻞ ﺗﺪﻋﻢ ﻣﻼﺣﻈﺎﺗﻚ ﻭﺣﺴﺎﺑﺎﺗﻚ ﺍﺳﺘﺨﺪﺍﻡ ﺛﺎﲏ .6ﺿﻊ ﺃﺳﻄﻮﺍﻧﺔ ﺍﻟﻘﺼﺪﻳﺮ ﺑﴪﻋﺔ ﻓﻮﻕ ﳍﺐ ﺍﻟﺸﻤﻌﺔ ﺑﺰﺍﻭﻳﺔ ﺃﻛﺴﻴﺪ ﺍﻟﻜﺮﺑﻮﻥ ﰲ ﻣﻜﺎﻓﺤﺔ ﺍﳊﺮﺍﺋﻖ؟ ﻭﳌﺎﺫﺍ؟ ﻣﻘﺪﺍﺭﻫﺎ )˚.(45 اﻟﻐﺎز اﻟﺤﻘﻴﻘﻲ ﻣﻘﺎﺑﻞ اﻟﻐﺎز اﻟﻤﺜﺎﻟﻲ Real Versus Ideal Gases ﻣﺎﺫﺍ ﻳﻌﻨﻲ ﻣﺼﻄﻠﺢ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ؟ ﺗﺘﺒﻊ ﺍﻟﻐﺎﺯﺍﺕ ﺍﳌﺜﺎﻟﻴﺔ ﻓﺮﺿﻴﺎﺕ ﻧﻈﺮﻳﺔ ﺍﳊﺮﻛﺔ ﺍﳉﺰﻳﺌﻴﺔ ﺍﻟﺘﻲ ﺩﺭﺳﺘﻬﺎ ﺳﺎﺑ ﹰﻘﺎ .ﻓﺤﺠﻢ ﺟﺴﻴﲈﺕ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ ﻳﻜﺎﺩ ﻳﻜﻮﻥ ﻣﻌﺪﻭ ﹰﻣﺎ ،ﻛﲈ ﺃﻥ ﻫﺬﻩ ﺍﳉﺴﻴﲈﺕ ﻻ ﺗﺸﻐﻞ ﺣﻴ ﹰﺰﺍ ،ﻭﻻ ﺗﻮﺟﺪ ﻗﻮ ﲡﺎﺫﺏ ﺑﻴﻨﻬﺎ ،ﻭﻻ ﺗﺘﺠﺎﺫﺏ ﻣﻊ ﺟﺪﺭﺍﻥ ﺍﻟﻮﻋﺎﺀ ﺍﳌﻮﺟﻮﺩﺓ ﻓﻴﻪ ،ﻭﻻ ﺗﺘﻨﺎﻓﺮ ﻣﻌﻪ .ﻭﺗﺘﺤﺮﻙ ﻫﺬﻩ ﺍﳉﺴﻴﲈﺕ ﺣﺮﻛﺔ ﻋﺸﻮﺍﺋﻴﺔ ﺩﺍﺋﻤﺔ ﰲ ﺧﻄﻮﻁ ﻣﺴﺘﻘﻴﻤﺔ ﺣﺘﻰ ﻳﺼﻄﺪﻡ ﺑﻌﻀﻬﺎ ﺑﺒﻌﺾ ﺃﻭ ﺑﺠﺪﺍﺭ ﺍﻟﻮﻋﺎﺀ ﺍﻟﺬﻱ ﳛﺘﻮﳞﺎ ،ﻭﻫﺬﻩ ﺍﻟﺘﺼﺎﺩﻣﺎﺕ ﻣﺮﻧﺔ ،ﳑﺎ ﻳﻌﻨﻲ ﺃﻥ ﺍﻟﻄﺎﻗﺔ ﺍﳊﺮﻛﻴﺔ ﻟﻠﻨﻈﺎﻡ ﻻ ﺗﺘﻐﲑ .ﻭﻳﺘﺒﻊ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ ﻗﻮﺍﻧﲔ ﺍﻟﻐﺎﺯ ﲢﺖ ﻛﻞ ﺍﻟﻈﺮﻭﻑ ﻣﻦ ﺍﻟﻀﻐﻂ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ. ﻭﻟﻜﻦ ﰲ ﺍﳊﻘﻴﻘﺔ ﻟﻴﺲ ﻫﻨﺎﻙ ﻏﺎﺯ ﻣﺜﺎﱄ؛ ﻓﺠﺴﻴﲈﺕ ﺍﻟﻐﺎﺯ ﳍﺎ ﺣﺠﻢ ﻭ ﺇﻥ ﻛﺎﻥ ﺻﻐ ﹰﲑﺍ ،ﻭﺗﻮﺟﺪ ﺑﻴﻨﻬﺎ ﻗﻮ ﲡﺎﺫﺏ ،ﻛﲈ ﺃﻥ ﺍﻟﺘﺼﺎﺩﻣﺎﺕ ﻓﻴﲈ ﺑﻴﻨﻬﺎ ﻭﺑﲔ ﺍﻟﻮﻋﺎﺀ ﻟﻴﺴﺖ ﺗﺼﺎﺩﻣﺎﺕ ﻣﺮﻧﺔ ﲤﺎ ﹰﻣﺎ .ﻭﻋﲆ ﺍﻟﺮﻏﻢ ﻣﻦ ﺫﻟﻚ ﺗﺴﻠﻚ ﻣﻌﻈﻢ ﺍﻟﻐﺎﺯﺍﺕ ﺳﻠﻮﻙ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ ﰲ ﻧﻄﺎﻗﺎﺕ ﻭﺍﺳﻌﺔ ﻣﻦ ﺍﻟﻀﻐﻂ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ .ﻛﲈ ﺃﻥ ﺍﳊﺴﺎﺑﺎﺕ ﺍﻟﺘﻲ ﲡﺮﻱ ﺑﺎﺳﺘﺨﺪﺍﻡ ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ ﺗﻘﺎﺭﺏ ﺍﻟﻘﻴﺎﺳﺎﺕ ﺍﻟﺘﺠﺮﻳﺒﻴﺔ . ﺍﻟﻌﻼﻗﺔ ﺑﲔ ﻧﻈﺮﻳﺔ ﺍﳊﺮﻛﺔ ﺍﳉﺰﻳﺌﻴﺔ ﻭﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ. 106
PV1 = nRT1 PV2 = nRT2 _V1 = _nR _V2 = _nR ﺇﺫﺍ ﺃﺗﻘﻨﺖ ﺍﻻﺳﱰﺍﺗﻴﺠﻴﺎﺕ ﺍﻵﺗﻴﺔ ،ﻓﺈﻥ ﻋﻠﻴﻚ ﺗﺬﻛﺮ ﻗﺎﻧﻮﻥ T1 P T2 P ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ ﻓﻘﻂ .ﺧﺬ ﻣﺜﺎ ﹰﻻ ،ﺍﻟﻜﻤﻴﺔ ﺍﻟﺜﺎﺑﺘﺔ ﻣﻦ ﺍﻟﻐﺎﺯ ﺍﳌﻮﺟﻮﺩﺓ ﲢﺖ ﺿﻐﻂ ﺛﺎﺑﺖ. ﺍﺳﺘﺨﺪﻡ ﻗﺎﻧﻮﻥ ﺷﺎﺭﻝ ﳊﻞ ﺍﳌﺴﺎﺋﻞ ﺍﻟﺘﻲ ﺗﺘﻀﻤﻦ ﺍﳊﺠﻢ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ. _V1 = _V2 .1ﺍﺳﺘﺨﺪﻡ ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ ﻟﻜﺘﺎﺑﺔ ﻣﻌﺎﺩﻟﺘﲔ ﺗﺼﻔﺎﻥ ﻋﻴﻨﺔ ﺍﻟﻐﺎﺯ ﻋﻨﺪ ﺩﺭﺟﺔ T1 T2 ﺣﺮﺍﺭﺓ ﻭﺣﺠﻢ ﳐﺘﻠﻔﲔ )ﺍﻟﻜﻤﻴﺎﺕ ﺍﻟﺘﻲ ﻻ ﺗﺘﻐﲑ ﺗﻈﻬﺮ ﺑﺎﻟﻠﻮﻥ ﺍﻷﲪﺮ(. .2ﺍﻋﺰﻝ ﺍﳊﺠﻢ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ،ﻭﳘﺎ ﺍﻟﻘﻴﻤﺘﺎﻥ ﺍﻟﻠﺘﺎﻥ ﺗﺘﻐﲑﺍﻥ ﰲ ﺍﳉﻬﺔ ﻧﻔﺴﻬﺎ ﻣﻦ ﺍﳌﻌﺎﺩﻟﺔ. .3ﻭﻷﻥ ﻛ ﹼﹰﻼ ﻣﻦ P،R،nﺛﺎﺑﺖ ﲢﺖ ﻫﺬﻩ ﺍﻟﻈﺮﻭﻑ ،ﻓﺈﻧﻪ ﻳﻤﻜﻨﻚ ﺟﻌﻞ ﻛﻞ ﻣﻦ ﺍﳊﺠﻢ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻣﺘﺴﺎﻭﻳﲔ ﻻﺷﺘﻘﺎﻕ ﻗﺎﻧﻮﻥ ﺷﺎﺭﻝ. ﺍﺷﺘﻖ ﻗﺎﻧﻮﻥ ﺑﻮﻳﻞ ﻭﺟﺎﻱ -ﻟﻮﺳﺎﻙ ﻭﺍﻟﻘﺎﻧﻮﻥ ﺍﻟﻌﺎﻡ ﻟﻠﻐﺎﺯﺍﺕ ﺍﺳﺘﻨﺎ ﹰﺩﺍ ﺇﱃ ﺍﻟﻘﺎﻋﺪﺓ ﺃﻋﻼﻩ. ﻣﺘﻰ ﻳﻜـﻮﻥ ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ ﻏﲑ ﻣﻨﺎﺳـﺐ ﻟﻼﺳـﺘﺨﺪﺍﻡ ﻣﻊ ﺍﻟﻐﺎﺯ ﺍﳊﻘﻴﻘـﻲ؟ ﲢﻴـﺪ ﻣﻌﻈﻢ ﺍﻟﻐﺎﺯﺍﺕ ﺍﳊﻘﻴﻘﻴﺔ ﰲ ﺳـﻠﻮﻛﻬﺎ ﻋﻦ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ ﻋﻨـﺪ ﺍﻟﻀﻐﻂ ﺍﻟﻌﺎﱄ ﻭﺩﺭﺟﺎﺕ ﺍﳊـﺮﺍﺭﺓ ﺍﳌﻨﺨﻔﻀـﺔ .ﻭﻳﺴـﻠﻚ ﻏـﺎﺯ ﺍﻟﻨﻴﱰﻭﺟـﲔ ﰲ ﺍﳋـﺰﺍﻥ ﺍﻟﻈﺎﻫـﺮ ﰲ ﺍﻟﺸـﻜﻞ 7-8ﺳـﻠﻮﻙ ﺍﻟﻐﺎﺯ ﺍﳊﻘﻴﻘـﻲ .ﻭﻋﻨﺪ ﺍﻧﺨﻔﺎﺽ ﺩﺭﺟﺎﺕ ﺣـﺮﺍﺭﺓ ﻏﺎﺯ ﺍﻟﻨﻴﱰﻭﺟﲔ ﺗﻨﺨﻔﺾ ﻃﺎﻗﺔ ﺟﺴـﻴﲈﺗﻪ ﺍﳊﺮﻛﻴﺔ ،ﻭﻫﺬﺍ ﻳﻌﻨﻲ ﺃﻥ ﻗﻮ ﺍﻟﺘﺠﺎﺫﺏ ﺑﲔ ﻫﺬﻩ ﺍﳉﺴﻴﲈﺕ ﻗﻮﻳﺔ ،ﳑﺎ ﳚﻌﻠﻬﺎ ﺗﺆﺛﺮ ﰲ ﺳﻠﻮﻛﻬﺎ .ﻭﻋﻨﺪﻣﺎ ﺗﻨﺨﻔﺾ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺑﻘﺪﺭ ﻛﺎ ﹴﻑ ﻳﺘﻜﺎﺛﻒ ﺍﻟﻐﺎﺯ ﺍﳊﻘﻴﻘﻲ ﻣﻜ ﹼﻮ ﹰﻧﺎ ﺳـﺎﺋ ﹰﻼ .ﻭﻳﺴـﻠﻚ ﻏﺎﺯ ﺍﻟﱪﻭﺑﺎﻥ ﰲ ﺍﳋﺰﺍﻥ ﺍﻟﻈﺎﻫﺮ ﰲ ﺍﻟﺸـﻜﻞ 7-8ﺃﻳ ﹰﻀﺎ ﺳـﻠﻮ ﹶﻙ ﺍﻟﻐﺎﺯ ﺍﳊﻘﻴﻘﻲ .ﻭﺗﻌﻤﻞ ﺯﻳﺎﺩﺓ ﺍﻟﻀﻐﻂ ﻋﲆ ﺍﻟﻐﺎﺯ ﻋﲆ ﺇﺟﺒﺎﺭ ﺟﺴـﻴﲈﺗﻪ ﻋﲆ ﺍﻻﻗـﱰﺍﺏ ﺑﻌﻀﻬـﺎ ﻣﻦ ﺑﻌﺾ ،ﺣﺘـﻰ ﻳﺼﺒﺢ ﻣﻦ ﻏﲑ ﺍﳌﻤﻜﻦ ﺇﳘﺎﻝ ﺍﳊﺠﻢ ﺍﻟﺬﻱ ﺗﺸـﻐﻠﻪ ﺍﳉﺴـﻴﲈﺕ. ﻭﺗﺘﺤﻮﻝ ﺍﻟﻐﺎﺯﺍﺕ ﺍﳊﻘﻴﻘﻴﺔ ـ ﻭﻣﻨﻬﺎ ﺍﻟﱪﻭﺑﺎﻥ ـ ﺇﱃ ﺳﺎﺋﻞ ﺇﺫﺍ ﺗﻌﺮﺿﺖ ﻟﻀﻐﻂ ﻛﺎ ﹴﻑ. 7-8 270 (-196˚C) 107
7-9 ﺗﺆﺛﺮ ﻃﺒﻴﻌﺔ ﺍﳉﺴـﻴﲈﺕ ﺍﻟﺘﻲ ﻳﺘﻜـ ﹼﻮﻥ ﻣﻨﻬﺎ ﺍﻟﻐﺎﺯ ﰲ ﺳـﻠﻮﻛﻪ ﺑﻄﺮﻳﻘـﺔ ﻣﺜﺎﻟﻴﺔ .ﻓﻤﺜ ﹰﻼ ﻳﻮﺟﺪ ﺑﲔ ﺟﺴـﻴﲈﺕ ﺍﻟﻐﺎﺯ ﺍﻟﻘﻄﺒﻴﺔ ﻛﲈ ﰲ ﺑﺨـﺎﺭ ﺍﳌﺎﺀ ﻗﻮ ﲡﺎﺫﺏ ﺃﻛﱪ ﻣـﻦ ﺍﻟﻘﻮ ﺍﻟﺘﻲ ﺗﻜﻮﻥ ﺑﲔ ﺟﺴـﻴﲈﺕ ﺍﻟﻐﺎﺯﺍﺕ ﻏـﲑ ﺍﻟﻘﻄﺒﻴﺔ ﻛﺎﳍﻴﻠﻴـﻮﻡ .ﻓﺘﻨﺠﺬﺏ ﺍﻷﻃﺮﺍﻑ ﺍﳌﺨﺘﻠﻔﺔ ﻟﻠﺠﺴﻴﲈﺕ ﺍﻟﻘﻄﺒﻴﺔ ﺑﻌﻀﻬﺎ ﻧﺤﻮ ﺑﻌﺾ ﺑﻮﺳﺎﻃﺔ ﻗﻮ ﻛﻬﺮﻭﺳﺘﺎﺗﻴﻜﻴﺔ ،ﻛﲈ ﰲ ﺍﻟﺸﻜﻞ ،7-9ﻟﺬﺍ ،ﻻ ﺗﺴـﻠﻚ ﺍﻟﻐﺎﺯﺍﺕ ﺍﻟﻘﻄﺒﻴﺔ ﺳـﻠﻮﻙ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ .ﻭﺗﺸﻐﻞ ﺟﺴﻴﲈﺕ ﺍﻟﻐﺎﺯﺍﺕ ﻏﲑ ﺍﻟﻘﻄﺒﻴـﺔ ﺍﻟﻜﺒـﲑﺓ ﺍﳊﺠﻢ ﻛﺎﻟﺒﻴﻮﺗـﺎﻥ C4H10ﺣﻴ ﹰﺰﺍ ﺃﻛﱪ ﻣﻦ ﺍﳊﻴﺰ ﺍﻟﺬﻱ ﻳﺸـﻐﻠﻪ ﻋﺪﺩ ﳑﺎﺛﻞ ﻣﻦ ﺟﺴـﻴﲈﺕ ﻏﺎﺯ ﺻﻐﲑﺓ ﺍﳊﺠﻢ ﻛﺎﳍﻴﻠﻴﻮﻡ .Heﻭﳍﺬﺍ ﺍﻟﺴـﺒﺐ ﲤﻴﻞ ﺟﺴـﻴﲈﺕ ﺍﻟﻐﺎﺯ ﺍﻟﻜﺒﲑﺓ ﺇﱃ ﺍﻻﺑﺘﻌﺎﺩ ﻋﻦ ﺍﻟﺴﻠﻮﻙ ﺍﳌﺜﺎﱄ ﺃﻛﺜﺮ ﻣﻦ ﺟﺴﻴﲈﺕ ﺍﻟﻐﺎﺯ ﺍﻟﺼﻐﲑﺓ. .31اﻟﻔﻜﺮة اﻟﺮﺋﻴﺴﺔ ﻓﴪ ﳌﺎﺫﺍ ﻳﻨﻄﺒﻖ ﻣﺒﺪﺃ ﺃﻓﻮﺟﺎﺩﺭﻭ ﻋﲆ ﺍﻟﻐﺎﺯﺍﺕ ﺍﻟﺘﻲ ﺗﺘﻜﻮﻥ اﻟﺘﻘﻮﻳﻢ 7-2 ﻣﻦ ﺟﺰﻳﺌﺎﺕ ﺻﻐﲑﺓ ﻭﺍﻟﺘﻲ ﺗﺘﻜﻮﻥ ﻣﻦ ﺟﺰﻳﺌﺎﺕ ﻛﺒﲑﺓ؟ اﻟﺨﻼﺻﺔ .32ﺍﻛﺘﺐ ﻣﻌﺎﺩﻟﺔ ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ. ﻳﻨﺺ ﻣﺒﺪﺃ ﺃﻓﻮﺟﺎﺩﺭﻭ ﻋﲆ ﺃﻥ ﺍﳊﺠﻮﻡ .33ﺣ ﹼﻠﻞ ﻛﻴﻒ ﻳﻨﻄﺒﻖ ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ ﻋﲆ ﺍﻟﻐﺎﺯ ﺍﳊﻘﻴﻘﻲ ﻣﺴﺘﺨﺪ ﹰﻣﺎ ﻧﻈﺮﻳﺔ ﺍﳌﺘﺴـﺎﻭﻳﺔ ﻣـﻦ ﺍﻟﻐـﺎﺯﺍﺕ ﻋﻨـﺪ ﻧﻔـﺲ ﺍﻟﻀﻐـﻂ ﻭﺩﺭﺟﺔ ﺍﳊـﺮﺍﺭﺓ ﲢﺘﻮﻱ ﻋﲆ ﺍﳊﺮﻛﺔ ﺍﳉﺰﻳﺌﻴﺔ؟ ﺍﻟﻌﺪﺩ ﻧﻔﺴﻪ ﻣﻦ ﺍﳉﺴﻴﲈﺕ. .34ﺗﻮﻗﻊ ﺍﻟﻈﺮﻭﻑ ﺍﻟﺘﻲ ﳛﺘﻤﻞ ﺃﻥ ﳜﺘﻠﻒ ﻋﻨﺪﻫﺎ ﺳﻠﻮﻙ ﺍﻟﻐﺎﺯ ﺍﳊﻘﻴﻘﻲ ﻋﻦ ﺳﻠﻮﻙ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ؟ ﻳﺮﺑﻂ ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ ﻛﻤﻴﺔ ﺍﻟﻐﺎﺯ ﻣﻊ ﺿﻐﻄﻪ ﻭﺩﺭﺟﺔ ﺣﺮﺍﺭﺗﻪ ﻭﺣﺠﻤﻪ. .35ﺿﻊ ﰲ ﻗﺎﺋﻤﺔ ،ﺍﻟﻮﺣﺪﺍﺕ ﺍﻷﻛﺜﺮ ﺷﻴﻮ ﹰﻋﺎ ﻟﻠﻤﺘﻐﲑﺍﺕ ﰲ ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ. ﻳﻤﻜـﻦ ﺍﺳـﺘﺨﺪﺍﻡ ﻗﺎﻧﻮﻥ ﺍﻟﻐـﺎﺯ ﺍﳌﺜﺎﱄ .36ﺍﺣﺴﺐ ﻛﺘﻠﺔ ﻏﺎﺯ ﺍﻟﱪﻭﺑﺎﻥ C3H8ﺍﳌﻮﺟﻮﺩ ﰲ ﺩﻭﺭﻕ ﺣﺠﻤﻪ 2.0 Lﻋﻨﺪ ﻹﳚـﺎﺩ ﺍﻟﻜﺘﻠﺔ ﺍﳌﻮﻟﻴـﺔ ﻟﻠﻐﺎﺯ ﺇﺫﺍ ﻛﺎﻧﺖ ﺿﻐﻂ ﺟﻮﻱ ﻣﻘﺪﺍﺭﻩ 1.00 atmﻭﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ .-15.0˚C ﻛﺘﻠـﺔ ﺍﻟﻐـﺎﺯ ﻣﻌﺮﻭﻓـﺔ ،ﻭﻳﻤﻜـﻦ ﺃﻳ ﹰﻀﺎ ﺍﺳـﺘﺨﺪﺍﻣﻪ ﻹﳚـﺎﺩ ﻛﺜﺎﻓـﺔ ﺍﻟﻐـﺎﺯ ﺇﺫﺍ .37ﺍﺭﺳﻢ ﺭﺳ ﹰﲈ ﺑﻴـﺎﻧـ ﹰﹼﻴﺎ ﻭﺍﺳﺘﺨـﺪﻣـﻪ ﻳﻨﺨـﻔـﺾ ﺿﻐـﻂ ﺇﻃﺎﺭﺍﺕ ﺍﻟﺴـﻴـﺎﺭﺍﺕ ﺑﻤﻘﺪﺍﺭ (14.7psi=1.0 atm) 1psiﻋﻨﺪ ﺍﻧﺨﻔﺎﺽ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻛﺎﻧﺖ ﺍﻟﻜﺘﻠﺔ ﺍﳌﻮﻟﻴﺔ ﻣﻌﺮﻭﻓﺔ. ﺑﻤﻘﺪﺍﺭ ، 6˚Cﺍﺭﺳﻢ ﺭﺳ ﹰﲈ ﺑﻴﺎﻧ ﹰﹼﻴﺎ ﻳﻮﺿﺢ ﺍﻟﺘﻐﲑ ﰲ ﺍﻟﻀﻐﻂ ﺩﺍﺧﻞ ﺍﻹﻃﺎﺭ، ﻋﻨﺪﻣﺎ ﺗﺘﻐﲑ ﺩﺭﺟﺎﺕ ﺍﳊﺮﺍﺭﺓ ﻣﻦ 20˚Cﺇﱃ ) -20˚Cﺍﻓﱰﺽ ﺃﻥ ﺍﻟﻀﻐﻂ ﺗﺴﻠﻚ ﺍﻟﻐﺎﺯﺍﺕ ﺍﳊﻘﻴﻘﻴﺔ ﻋﻨﺪ ﺍﻟﻀﻐﻂ ﺍﻟﻌﺎﱄ ﻭﺩﺭﺟـﺎﺕ ﺍﳊـﺮﺍﺭﺓ ﺍﳌﻨﺨﻔﻀﺔ ﻳﺴﺎﻭﻱ 30 Psiﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ .(20.0˚C ﺳﻠﻮ ﹰﻛﺎ ﻣﻐﺎﻳ ﹰﺮﺍ ﻟﺴﻠﻮﻙ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ. 108
7-3اﻟﺤﺴﺎﺑﺎت اﻟﻤﺘﻌﻠﻘﺔ ﺑﺎﻟﻐﺎزات Gas Stoichiometry ﻫﺪاف ا ﺍﻟـﻨـﺴـﺐ ﺍﳊـﺠـﻤـﻴـﺔ ﻟﻠﻐﺎﺯﺍﺕ ﺍﳌﺘـﻔـﺎﻋﻠـﺔ ﻭﺍﻟﻨﺎﺗـﺠﺔ اﻟﻔﻜﺮة اﻟﺮﺋﻴﺴﺔ ﻣﺴﺘﺨﺪ ﹰﻣﺎ ﺍﳌﻌﺎﻣﻼﺕ ﺍﳌﻮﺟﻮﺩﺓ ﻟﻜﻲ ﺗﻘﻮﻡ ﺑﺼﻨﺎﻋﺔ ﺍﻟﻜﻴﻚ ﻣﻦ ﺍﳌﻬﻢ ﺃﻥ ﺗﻀﻴﻒ ﺍﳌﻘﺎﺩﻳﺮ ﺑﻨﺴـﺐ ﺻﺤﻴﺤﺔ. ﰲ ﺍﳌﻌﺎﺩﻟﺔ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ. ﻗﻮﺍﻧﲔ ﺍﻟﻐﺎﺯﺍﺕ ﳊﺴﺎﺏ ﻭﺑﻄﺮﻳﻘﺔ ﻣﺸـﺎﲠﺔ ﻓﺈﻥ ﻧﺴ ﹰﺒﺎ ﺻﺤﻴﺤﺔ ﻣﻦ ﺍﳌﺘﻔﺎﻋﻼﺕ ﺗﻠﺰﻡ ﰲ ﺍﻟﺘﻔﺎﻋﻞ ﺍﻟﻜﻴﻤﻴﺎﺋﻲ ﻟﻠﺤﺼﻮﻝ ﻋﲆ ﻛﻤﻴﺎﺕ ﺍﻟـﻐـﺎﺯﺍﺕ ﺍﳌﺘﻔﺎﻋﻠﺔ ﺍﻟﻨﺘﺎﺋﺞ ﺍﳌﻄﻠﻮﺑﺔ. ﻭﺍﻟﻨﺎﲡﺔ ﰲ ﺍﻟﺘﻔﺎﻋﻞ ﺍﻟﻜﻴﻤﻴﺎﺋﻲ .اﻟﺤﺴﺎﺑﺎت اﻟﻜﻴﻤﻴﺎﺋﻴﺔ ﻟﻠﺘﻔﺎﻋﻼت اﻟﻤﺘﻀﻤﻨﺔ ﻟﻠﻐﺎزات Stoichiometry of Reactions Involving Gases ﻣﺮاﺟﻌﺔ اﻟﻤﻔﺮدات ﺍﻟﺮﻗﻢ ﺍﻟﺬﻱ ﻳﻜﺘﺐ ﺗﻄﺒﻖ ﻗﻮﺍﻧﲔ ﺍﻟﻐﺎﺯﺍﺕ ﰲ ﺣﺴﺎﺏ ﺍﳌﺘﻔﺎﻋﻼﺕ ﺃﻭ ﺍﻟﻨﻮﺍﺗﺞ ﺍﻟﻐﺎﺯﻳﺔ ﰲ ﺍﻟﺘﻔﺎﻋﻼﺕ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ.ﻋﻦ ﻳﺴﺎﺭ ﺍﳌﻮﺍﺩ ﺍﳌﺘﻔﺎﻋﻠﺔ ﺃﻭ ﺍﻟﻨﺎﲡﺔ ﺗﺬﻛﺮ ﺃﻥ ﺍﳌﻌﺎﻣﻼﺕ ﰲ ﺍﻟﺘﻔﺎﻋﻼﺕ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ ﲤﺜﻞ ﻋﺪﺩ ﻣﻮﻻﺕ ﺍﳌﻮﺍﺩ ﺍﳌﺸﺎﺭﻛﺔ ﰲ ﺍﻟﺘﻔﺎﻋﻞ .ﻋﲆ ﰲ ﺍﳌﻌﺎﺩﻟﺔ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ ﻭﺍﻟﺬﻱ ﳜﱪﻧﺎ ﺳﺒﻴﻞ ﺍﳌﺜﺎﻝ ﻳﺘﻔﺎﻋﻞ ﻏﺎﺯ ﺍﳍﻴﺪﺭﻭﺟﲔ ﻣﻊ ﻏﺎﺯ ﺍﻷﻛﺴﺠﲔ ﻹﻧﺘﺎﺝ ﺑﺨﺎﺭ ﺍﳌﺎﺀ. )2H2(g) + O2(g) → 2H O2 (g ﻋﻦ ﺃﻗﻞ ﻋﺪﺩ ﻣﻦ ﺟﺴﻴﲈﺕ ﺍﳌﺎﺩﺓﲣﱪﻙ ﺍﳌﻌﺎﺩﻟﺔ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ ﺍﳌﻮﺯﻭﻧﺔ ﺑﺎﻟﻨﺴﺐ ﺍﳌﻮﻟﻴﺔ ﻟﻠﻤﻮﺍﺩ ﰲ ﺍﻟﺘﻔﺎﻋﻞ؛ ﻓﻤﺜ ﹰﻼ ﺗﺒﲔ ﻣﻌﺎﺩﻟﺔ ﺍﳌﺘﻀﻤﻨﺔ ﰲ ﺍﻟﺘﻔﺎﻋﻞ.ﺍﻟﺘﻔﺎﻋﻞ ﺃﻋﻼﻩ ﺃ ﹼﻥ 2 molﻣﻦ ﻏﺎﺯ ﺍﳍﻴﺪﺭﻭﺟﲔ ﺗﺘﻔﺎﻋﻞ ﻣﻊ 1 molﻣﻦ ﻏﺎﺯ ﺍﻷﻛﺴﺠﲔ ﻭﻳﻨﺘﺞ 2 molﻣﻦ ﺑﺨﺎﺭ ﺍﳌﺎﺀ.ﻛﲈ ﻳﻨﺺ ﻣﺒﺪﺃ ﺃﻓﻮﺟﺎﺩﺭﻭ ﻋﲆ ﺃ ﹼﻥ ﺍﳊﺠﻮﻡ ﺍﳌﺘﺴﺎﻭﻳﺔ ﻣﻦ ﺍﻟﻐﺎﺯﺍﺕ ﻋﻨﺪ ﻧﻔﺲ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓﻭﺍﻟﻀﻐﻂ ﳍﺎ ﻋﺪﺩ ﺍﳉﺴﻴﲈﺕ ﻧﻔﺴﻪ ،ﻭﻫﻜﺬﺍ ﻓﺈﻥ ﻣﻌﺎﻣﻼﺕ ﺍﳌﻮﺍﺩ ﺍﻟﻐﺎﺯﻳﺔ ﰲ ﺍﳌﻌﺎﺩﻟﺔ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔﺍﳌﻮﺯﻭﻧﺔ ﻻﲤﺜﻞ ﻋﺪﺩ ﺍﳌﻮﻻﺕ ﻓﻘﻂ ،ﻭﺇﻧﲈ ﲤﺜﻞ ﺍﳊﺠﻮﻡ ﺍﻟﻨﺴﺒﻴﺔ ﺃﻳ ﹰﻀﺎ .ﳍﺬﺍ ﻓﺈﻥ 2 Lﻣﻦ ﻏﺎﺯ ﺍﳍﻴﺪﺭﻭﺟﲔ ﺳﺘﺘﻔﺎﻋﻞ ﻣﻊ 1 Lﻣﻦ ﻏﺎﺯ ﺍﻷﻛﺴﺠﲔ ﻹﻧﺘﺎﺝ 2 Lﻣﻦ ﺑﺨﺎﺭ ﺍﳌﺎﺀ. اﻟﺤﺴﺎﺑﺎت اﻟﻜﻴﻤﻴﺎﺋﻴﺔ :ﺣﺴﺎب اﻟﺤﺠﻢ Stoichiometry and Volume-Volume Problemsﻹﳚﺎﺩ ﺣﺠﻢ ﻏﺎﺯ ﻣﺘﻔﺎﻋﻞ ﺃﻭ ﻧﺎﺗﺞ ﰲ ﺍﻟﺘﻔﺎﻋﻞ ﺍﻟﻜﻴﻤﻴﺎﺋﻲ ﳚﺐ ﻋﻠﻴﻚ ﻣﻌﺮﻓﺔ ﺍﳌﻌﺎﺩﻟﺔ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔﺍﳌﻮﺯﻭﻧﺔ ﳍﺬﺍ ﺍﻟﺘﻔﺎﻋﻞ ﻭﺣﺠﻢ ﻏﺎﺯ ﺁﺧﺮ ﻣﺸﺎﺭﻙ ﰲ ﺍﻟﺘﻔﺎﻋﻞ ﻋﲆ ﺍﻷﻗﻞ .ﺍﻓﺤﺺ ﺍﻟﺘﻔﺎﻋﻞ ﰲﺍﻟﺸﻜﻞ 7-10ﻣﺜ ﹰﻼ ،ﻭﺍﻟﺬﻱ ﻳﻮﺿﺢ ﺍﺣﱰﺍﻕ ﻏﺎﺯ ﺍﳌﻴﺜﺎﻥ ،ﻭﻫﺬﺍ ﺍﻟﺘﻔﺎﻋﻞ ﻣﺄﻟﻮﻑ ﻟﻚ؛ ﺇﺫ ﳛﺪﺙ ﻛﻠﲈ ﺃﺷﻌﻠﺖ ﻣﻮﻗﺪ ﺑﻨﺰﻥ. + → + 7-10)CH4(g )+ 2O2(g → + )2H2O(g )CO2(g 1 mol 2 mol 1 mol 2 mol1 vol 2 vol 1 vol 2 vol 109
ﻭﻷ ﹼﻥ ﺍﳌﻌﺎﻣﻼﺕ ﲤﺜﻞ ﺍﻟﻨﺴﺐ ﺍﳊﺠﻤﻴﺔ ﻟﻠﻐﺎﺯﺍﺕ ﺍﳌﺸﺎﺭﻛﺔ ﰲ ﺍﻟﺘﻔﺎﻋﻞ ﻓﺈﻧﻪ ﻳﻤﻜﻨﻚ ﺃﻥ ﲢﺪﺩ ﺃﻧﻪ ﻳﻠﺰﻡ 2 Lﻣﻦ ﻏﺎﺯ ﺍﻷﻛﺴﺠﲔ ﻟﺘﺘﻔﺎﻋﻞ ﲤﺎ ﹰﻣﺎ ﻣﻊ 1 Lﻣﻦ ﻏﺎﺯ ﺍﳌﻴﺜﺎﻥ .ﻛﲈ ﺃ ﹼﻥ ﺍﻻﺣﱰﺍﻕ ﺍﻟﻜﺎﻣﻞ ﻟـ 1 Lﻣﻦ ﺍﳌﻴﺜﺎﻥ ﺳﻮﻑ ﻳﻨﺘﺞ 1 Lﻣﻦ ﺛﺎﲏ ﺃﻛﺴﻴﺪ ﺍﻟﻜﺮﺑﻮﻥ ﻭ 2 Lﻣﻦ ﺑﺨﺎﺭ ﺍﳌﺎﺀ.ﻻﺣﻆ ﺃﻧﻪ ﱂ ﻳﺘﻢ ﲢﺪﻳﺪ ﺃﻱ ﻣﻦ ﺍﻟﻈﺮﻭﻑ ﻣﺜﻞ ﺍﻟﻀﻐﻂ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ .ﻓﻼ ﺣﺎﺟﻪ ﺇﻟﻴﻬﺎ ﰲ ﺍﳊﺴﺎﺑﺎﺕﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ؛ ﻭﺫﻟﻚ ﻷﻧﻪ ﺑﻌﺪ ﺍﳋﻠﻂ ﺳﻴﻜﻮﻥ ﻛﻼ ﺍﻟﻐﺎﺯﻳﻦ ﰲ ﻧﻔﺲ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻭﺍﻟﻀﻐﻂ .ﻭﻳﻤﻜﻦﺃﻥ ﺗﺘﻐﲑ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﰲ ﺃﺛﻨﺎﺀ ﺍﻟﺘﻔﺎﻋﻞ ،ﻟﻜﻦ ﺍﻟﺘﻐﲑ ﰲ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻳﺆﺛﺮ ﰲ ﻛﻞ ﺍﻟﻐﺎﺯﺍﺕ ﺍﳌﻮﺟﻮﺩﺓ ﰲ ﺍﻟﺘﻔﺎﻋﻞ ﺑﻨﻔﺲ ﺍﻟﻄﺮﻳﻘﺔ .ﻟﺬﺍ ﻓﺈﻧﻚ ﻻ ﲢﺘﺎﺝ ﻷﺧﺬ ﺣﺎﻟﺘﻲ ﺍﻟﻀﻐﻂ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺑﻌﲔ ﺍﻻﻋﺘﺒﺎﺭ. 77 اﻟﻜﻴﻤﻴﺎء ﻓﻲ واﻗﻊ اﻟﺤﻴﺎةﻣﺎ ﺣﺠﻢ ﻏﺎﺯ ﺍﻷﻛﺴﺠﲔ ﺍﻟﻼﺯﻡ ﻹﺣﺮﺍﻕ 4.0 Lﻣﻦ ﻏﺎﺯ ﺍﻟﱪﻭﺑﺎﻥ C3H8 ﺣﺮ ﹰﻗﺎ ﻛﺎﻣ ﹰﻼ .ﺍﻓﱰﺽ ﺃﻥ ﺍﻟﻀﻐﻂ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺛﺎﺑﺘﺎﻥ. 1ﺗﺤﻠﻴﻞ اﻟﻤﺴﺄﻟﺔ ﺗـﻠـﺰﻡ ﻧﺴﺐﻟﻘﺪ ﺃﻋﻄﻴﺖ ﺣﺠﻢ ﺍﻟﻐﺎﺯ ﺍﳌﺘﻔﺎﻋﻞ ﰲ ﺍﳌﻌﺎﺩﻟﺔ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ .ﺗﺬﻛﺮ ﺃﻥ ﺍﳌﻌﺎﻣﻼﺕ ﰲ ﺍﳌﻌﺎﺩﻟﺔ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ ﺻﺤـﻴـﺤـﺔ ﻣـﻦ ﺍﻟـﻐـﺎﺯﺍﺕ ﰲ ﻛـﺜـﲑ ﻣﻦ ﺍﻟﺘـﻔـﺎﻋـﻼﺕ ﺍﳌﻮﺯﻭﻧﺔ ﺗﺰﻭﺩﻙ ﺑﺎﻟﻨﺴﺐ ﺍﳊﺠﻤﻴﺔ ﻟﻠﻐﺎﺯﺍﺕ ﺍﳌﺘﻔﺎﻋﻠﺔ ﻭﺍﻟﻨﺎﲡﺔ. ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ .ﻭﺭﻏﻢ ﺃﻥ ﻛﺜ ﹰﲑﺍ ﻣﻦ ﺃﻓـﺮﺍﻥ ﺻﻨﺎﻋﺔ ﺍﻟﻔﺨﺎﺭ ﻳﺘﻢ ﺗﻐﺬﻳﺘﻬﺎ ﺑﻐﺎﺯ ﺍﳌﻴﺜﺎﻥ ﻓﺈﻥ VC3H8 = 4.00 L ﻣﺰ ﹰﳚﺎ ﳏـﺪ ﹰﺩﺍ ﻣﻦ ﺍﻟﱪﻭﺑﺎﻥ V02 = ? L ﻭﺍﳍﻮﺍﺀ ﻳﻤﻜﻦ ﺃﻥ ﻳﺴﺘﺨﺪﻡ ﻭﻗﻮ ﹰﺩﺍ ﰲ ﻫﺬﻩ ﺍﻷﻓﺮﺍﻥ ﺇﻥ ﱂ 2ﺣﺴﺎب اﻟﻤﻄﻠﻮب ﻳﺘﻮﺍﻓﺮ ﺍﳌﻴﺜﺎﻥ.ﺍﺳﺘﺨﺪﻡ ﺍﳌﻌﺎﺩﻟﺔ ﺍﳌﻮﺯﻭﻧﺔ ﻻﺣﱰﺍﻕ ،C3H8ﺛﻢ ﺟﺪ ﺍﻟﻨﺴﺒﺔ ﺍﳊﺠﻤﻴﺔ ﻟﻜﻞ ﻣﻦ C3H8ﻭ ،O2ﺛﻢ ﺟﺪ 110 ﺣﺠﻢ ﻏﺎﺯ O2)C3H8(g) + 5O2(g) → 3CO2(g) + 4H O2 (g _5 vol O2 O2C3H8 1 vol C3H8 _5 vol O2VO2 = (4.00 L )C3H8 × C3H8 1 vol C3H8 O2 = 20.0 L O2 3ﺗﻘﻮﻳﻢ ا ﺟﺎﺑﺔﺗﻮﺿﺢ ﺍﳌﻌﺎﻣﻼﺕ ﰲ ﻣﻌﺎﺩﻟﺔ ﺗﻔﺎﻋﻞ ﺍﻻﺣﱰﺍﻕ ﺃ ﹼﻥ ﺣﺠﻢ ﻏﺎﺯ O2ﺍﳌﺴﺘﺨﺪﻡ ﰲ ﺍﻟﺘﻔﺎﻋﻞ ﺃﻛﱪ ﻛﺜ ﹰﲑﺍﻣﻦ ﺣﺠﻢ ،C3H8ﻭﻫﺬﺍ ﻳﺘﻮﺍﻓﻖ ﻣﻊ ﺍﻹﺟﺎﺑﺔ ﺍﻟﺘﻲ ﺗﻢ ﺣﺴﺎﲠﺎ .ﻭﺣﺪﺓ ﺍﻹﺟﺎﺑﺔ ﻫﻲ) ،(Lﻭﻫﻮ ﻭﺣﺪﺓ ﺣﺠﻢ ،ﻭﻫﻨﺎﻙ ﺛﻼﺛﺔ ﺃﺭﻗﺎﻡ ﻣﻌﻨﻮﻳﺔ. .38ﻛﻢ ﻟ ﹰﱰﺍ ﻣﻦ ﻏﺎﺯ ﺍﻟﱪﻭﺑﺎﻥ C3H8ﻳﻠﺰﻡ ﻟﻜﻲ ﲢﱰﻕ ﺣﺮ ﹰﻗﺎ ﻛﺎﻣ ﹰﻼ ﻣﻊ 34.0 Lﻣﻦ ﻏﺎﺯ ﺍﻷﻛﺴﺠﲔ ؟ .39ﻣﺎ ﺣﺠﻢ ﻏﺎﺯ ﺍﳍﻴﺪﺭﻭﺟﲔ ﺍﻟﻼﺯﻡ ﻟﻠﺘﻔﺎﻋﻞ ﲤﺎ ﹰﻣﺎ ﻣﻊ 5.00 Lﻣﻦ ﻏﺎﺯ ﺍﻷﻛﺴﺠﲔ ﻹﻧﺘﺎﺝ ﺍﳌﺎﺀ؟ .40ﻣﺎ ﺣﺠﻢ ﻏﺎﺯ ﺍﻷﻛﺴﺠﲔ ﺍﻟﻼﺯﻡ ﻻﺣﱰﺍﻕ 2.36 Lﻣﻦ ﻏﺎﺯ ﺍﳌﻴﺜﺎﻥ CH4ﺣﺮ ﹰﻗﺎ ﻛﺎﻣ ﹰﻼ؟ .41ﻳﺘﻔﺎﻋﻞ ﻏﺎﺯﺍ ﺍﻟﻨﻴﱰﻭﺟﲔ ﻭﺍﻷﻛﺴﺠﲔ ﻹﻧﺘﺎﺝ ﻏﺎﺯ ﺃﻛﺴﻴﺪ ﺛﺎﲏ ﺍﻟﻨﻴﱰﻭﺟﲔ .N2Oﻣﺎ ﺣﺠﻢ ﻏﺎﺯ O2ﺍﻟﻼﺯﻡ ﻻﻧﺘﺎﺝ 34 Lﻣﻦ ﻏﺎﺯ N2O؟
7-11 اﻟﺤﺴﺎﺑﺎت اﻟﻜﻴﻤﻴﺎﺋﻴﺔ :ﺣﺴﺎﺑﺎت اﻟﺤﺠﻢ – اﻟﻜﺘﻠﺔ Stoichiometry and Problems ﺍﻟﻨﺴﺒﺔ ﻳﻤﻜﻨﻚ ﺗﻄﺒﻴﻖ ﻣﺎﺗﻌﻠﻤﺘﻪ ﻋﻦ ﺍﳊﺴﺎﺑﺎﺕ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ ﻋﲆ ﺇﻧﺘﺎﺝ ﺍﻷﻣﻮﻧﻴﺎ NH3ﻣﻦ ﻏﺎﺯ ﺍﻟﻨﻴﱰﻭﺟﲔ .N2ﻓﻤﺼﺎﻧﻊ ﺍﻷﺳﻤﺪﺓ ﺗﺴﺘﺨﺪﻡ ﺍﻷﻣﻮﻧﻴﺎ ﻟﺼﻨﺎﻋﺔ ﺍﻷﺳﻤﺪﺓ ﺍﻟﻌﻼﻗﺔ ﺍﻟﻜﻤﻴﺔ ﺑﲔ ﺷﻴﺌﲔ. ﺍﻟﻐﻨﻴﺔ ﺑﺎﻟﻨﻴﱰﻭﺟﲔ؛ ﻓﺎﻟﻨﻴﱰﻭﺟﲔ ﻋﻨﴫ ﻣﻬﻢ ﻟﻨﻤﻮ ﺍﻟﻨﺒﺎﺗﺎﺕ .ﻭﻳﻌﺪ ﺗﺜﺒﻴﺖ ﺍﻟﻨﺒﺎﺗﺎﺕ ﻟﻨﻴﱰﻭﺟﲔﺍﻟﻨﺴـﺒﺔ ﺑﲔ ﺍﳍﻴﺪﺭﻭﺟﲔ ﻭﺍﻷﻛﺴﺠﲔ ﺍﳉﻮ ﰲ ﺍﻟﱰﺑﺔ ،ﻭﲢﻠﻴﻞ ﺍﳌﻮﺍﺩ ﺍﻟﻌﻀﻮﻳﺔ ،ﻭﳐﻠﻔﺎﺕ ﺍﳊﻴﻮﺍﻧﺎﺕ ،ﻣﻦ ﺍﳌﺼﺎﺩﺭ ﺍﻟﻄﺒﻴﻌﻴﺔ ﻟﻠﻨﻴﱰﻭﺟﲔ ﰲ ﺍﻟﱰﺑﺔ .ﻫﺬﻩ ﺍﳌﺼﺎﺩﺭ ﻻ ﺗﻮﻓﺮ ﻣﺎ ﻳﻜﻔﻲ ﻣﻦ ﺍﻟﻨﻴﱰﻭﺟﲔ ﻟﺴﺪ ﺣﺎﺟﺔ ﺍﳌﺰﺭﻭﻋﺎﺕ .ﻳﻮﺿﺢ ﰲ ﺟﺰﻱﺀ ﺍﳌﺎﺀ ﻫﻲ2:1 ﺍﻟﺸﻜﻞ 7-11ﻣﺰﺍﺭ ﹰﻋﺎ ﻳﺴﻤﺪ ﺍﻷﺭﺽ ﺑﺴﲈﺩ ﻏﻨﻲ ﺑﺎﻟﻨﻴﱰﻭﺟﲔ ،ﻭﻫﺬﺍ ﳚﻌﻞ ﺍﳌﺰﺍﺭﻉ ﻗﺎﺩ ﹰﺭﺍ -ﺑﺈﺫﻥ ﺍﷲ -ﻋﲆ ﺇﻧﺘﺎﺝ ﻛﻤﻴﺎﺕ ﺃﻛﺜﺮ ﻣﻦ ﺍﳌﺤﺼﻮﻝ. ﻳﻮﺿﺢ ﺍﳌﺜﺎﻝ 7-8ﻛﻴﻒ ﻳﻤﻜﻦ ﺍﺳﺘﺨﺪﺍﻡ ﻏﺎﺯ ﺍﻟﻨﻴﱰﻭﺟﲔ ﰲ ﺇﻧﺘﺎﺝ ﻣﻘﺪﺍﺭ ﳏﺪﻭﺩ ﻣﻦ ﺍﻷﻣﻮﻧﻴﺎ. ﺗﺬﻛﺮ ﻋﻨﺪ ﺣﻞ ﻫﺬﺍ ﺍﳌﺜﺎﻝ ﺃﻥ ﺍﳌﻌﺎﺩﻟﺔ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ ﺍﳌﻮﺯﻭﻧﺔ ﺗﺒﲔ ﺃﻋﺪﺍﺩ ﺍﳌﻮﻻﺕ ﻭﺍﳊﺠﻮﻡ ﺍﻟﻨﺴﺒﻴﺔ ﻟﻠﻐﺎﺯﺍﺕ ﻓﻘﻂ ،ﻭﻟﻴﺲ ﻛﺘﻠﻬﺎ .ﻟﺬﺍ ﳚﺐ ﺃﻥ ﻳﺘﻢ ﲢﻮﻳﻞ ﻛﻞ ﺍﻟﻜﺘﻞ ﺍﳌﻌﻄﺎﺓ ﺇﱃ ﻣﻮﻻﺕ ﺃﻭ ﺣﺠﻮﻡ ﻗﺒﻞ ﺍﺳﺘﺨﺪﺍﻣﻬﺎ ﺟﺰ ﹰﺀﺍ ﻣﻦ ﺍﻟﻨﺴﺒﺔ .ﺗﺬﻛﺮ ﺃﻳ ﹰﻀﺎ ﺃﻥ ﻭﺣﺪﺓ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﳚﺐ ﺃﻥ ﺗﻜﻮﻥ ﺑﺎﻟﻜﻠﻔﻦ. 78 ﲢ ﹼﴬ ﺍﻷﻣﻮﻧﻴﺎ ﻣﻦ ﻏﺎﺯ ﺍﳍﻴﺪﺭﻭﺟﲔ ﻭﻏﺎﺯ ﺍﻟﻨﻴﱰﻭﺟﲔ ﻭﻓﻖ ﺍﳌﻌﺎﺩﻟﺔ : )N2(g) + 3H2(g) → 2NH3(gﺇﺫﺍ ﺗﻔﺎﻋﻞ 5.00 Lﻣﻦ ﻏﺎﺯ ﺍﻟﻨﻴﱰﻭﺟﲔ ﲤﺎ ﹰﻣﺎ ﻣﻊ ﻏﺎﺯ ﺍﳍﻴﺪﺭﻭﺟﲔ ﻋﻨﺪ ﺿﻐﻂ ﺟﻮﻱ 3.00 atmﻭﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ،298 Kﻓﲈ ﻛﻤﻴﺔ ﺍﻷﻣﻮﻧﻴﺎ ) (gﺍﻟﺘﻲ ﺗﻨﺘﺞ ﻋﻦ ﺍﻟﺘﻔﺎﻋﻞ؟ 1ﺗﺤﻠﻴﻞ اﻟﻤﺴﺄﻟﺔﻟﻘﺪ ﺃﻋﻄﻴﺖ ﺍﳊﺠﻢ ﻭﺍﻟﻀﻐﻂ ،ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻟﻌﻴﻨﺔ ﻣﻦ ﺍﻟﻐﺎﺯ ،ﻛﲈ ﺃﻥ ﺍﻟﻨﺴﺒﺔ ﺍﳊﺠﻤﻴﺔ ﻭﺍﳌﻮﻟﻴﺔ ﻟﻠﻐﺎﺯﺍﺕ ﺍﳌﺘﻔﺎﻋﻠﺔ ﻭﺍﻟﻨﺎﲡﺔ ﻣﻌﻄﺎﺓﻣﻦ ﺧﻼﻝ ﻣﻌﺎﻣﻼﲥﺎ ﰲ ﺍﳌﻌﺎﺩﻟﺔ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ ﺍﳌﻮﺯﻭﻧﺔ .ﻳﻤﻜﻦ ﲢﻮﻳﻞ ﺍﳊﺠﻢ ﺇﱃ ﻣﻮﻻﺕ ﺑﺎﺳﺘﺨﺪﺍﻡ ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ ،ﻭﻣﻦ ﺛﻢ ﺣﺴﺎﺏ ﺍﻟﻜﺘﻠﺔ ﺑﺎﺳﺘﺨﺪﺍﻡ ﺍﻟﻜﺘﻠﺔ ﺍﳌﻮﻟﻴﺔ. mNH3 = ? g VN2 = 5.00 L P = 3.00 atm T = 298 K111
2ﺣﺴﺎب اﻟﻤﻄﻠﻮب ﺣﺪﺩ ﻋﺪﺩ ﻟﱰﺍﺕ ﻏﺎﺯ ﺍﻷﻣﻮﻧﻴﺎ ﺍﻟﺘﻲ ﻳﻤﻜﻦ ﺃﻥ ﺗﻨﺘﺞ ﻋﻦ 5.00 Lﻣﻦ ﻏﺎﺯ ﺍﻟﻨﻴﱰﻭﺟﲔ. _1 vol N2 NH3N2 ( ) 2 vol NH3 NH3 N25.00 L N2 _2 vol NH3 = 10.0 L NH3 1 vol N2 ﺍﺳﺘﺨﺪﻡ ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ ﻹﳚﺎﺩ ﻗﻴﻤﺔ .nﻭﻣﻦ ﺛﻢ ﺍﺣﺴﺐ ﻋﺪﺩ ﻣﻮﻻﺕ NH3 PV = nRT n = _PV n V5.00LP3.0atmT298K RT = )_(3.00 atm_)(10.0 L ( )n 0.0821 _L·atm (298 )K mol·K )_(3.00 atm_)(10.0 L( )n = = 1.23 mol NH3 _L·atm 0.0821 (298 )K mol·K= ( ) ( )M1_N atom ×_14.01 amu + 3_H atoms ×_1.01 amu NH3 1 N atom 1 H atom = 17.04 amu gmol M = 17.04 g/mol ﺣﻮﻝ ﻣﻮﻻﺕ ﺍﻷﻣﻮﻧﻴﺎ ﺇﱃ ﺟﺮﺍﻣﺎﺕ ﺍﻷﻣﻮﻧﻴﺎ 1.23 mol NH3 × _17.04 g NH3 = 21.0 g NH3 1 mol NH3 3ﺗﻘﻮﻳﻢ ا ﺟﺎﺑﺔﻟﺘﻔﺤﺺ ﺇﺟﺎﺑﺘﻚ ،ﺍﺣﺴﺐ ﺣﺠﻢ ﺍﻟﻨﻴﱰﻭﺟﲔ ﺍﳌﺘﻔﺎﻋﻞ ﻋﻨﺪ ) ،(STPﺛﻢ ﺍﳊﺠﻢ ﺍﳌﻮﱄ ﻭﺍﻟﻨﺴﺒﺔ ﺍﳌﻮﻟﻴﺔ ﺑﲔ N2 ،NH3؛ ﻟﺘﺤﺪﻳﺪ ﻋﺪﺩ ﻣﻮﻻﺕ NH3ﺍﻟﻨﺎﲡﺔ .ﻭﺣﺪﺓ ﺍﻹﺟﺎﺑﺔ ﻫﻲ ﺍﳉﺮﺍﻡ ،ﻭﻫﻲ ﻭﺣﺪﺓ ﻗﻴﺎﺱ ﺍﻟﻜﺘﻠﺔ ،ﻭﻫﻨﺎﻙ ﺛﻼﺛﺔ ﺃﺭﻗﺎﻡ ﻣﻌﻨﻮﻳﺔ. .42ﻧﱰﺍﺕ ﺍﻷﻣﻮﻧﻴﻮﻡ ﻣﻜﻮﻥ ﺷﺎﺋﻊ ﰲ ﺍﻷﺳﻤﺪﺓ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ .ﺍﺳﺘﺨﺪﻡ ﺍﻟﺘﻔﺎﻋﻞ ﺍﻟﺘﺎﱄ ﳊﺴﺎﺏ ﻛﺘﻠﺔ ﻧﱰﺍﺕ ﺍﻷﻣﻮﻧﻴﻮﻡ ﺍﻟﺼﻠﺒﺔ ﺍﻟﺘﻲ ﳚﺐ ﺃﻥ ﺗﺴﺘﺨﺪﻡ ﻟﻠﺤﺼﻮﻝ ﻋﲆ 0.100 Lﻣﻦ ﻏﺎﺯ ﺛﺎﲏ ﺃﻛﺴﻴﺪ ﺍﻟﻨﻴﱰﻭﺟﲔ. )NH4NO3(s) → N2O(g) + 2H2O(g .43ﻋﻨﺪ ﺗﺴﺨﲔ ﻛﺮﺑﻮﻧﺎﺕ ﺍﻟﻜﺎﻟﺴﻴﻮﻡ CaCO3ﺗﺘﺤﻠﻞ ﻟﺘﻜﻮﻥ ﺃﻛﺴﻴﺪ ﺍﻟﻜﺎﻟﺴﻴﻮﻡ CaOﺍﻟﺼﻠﺐ ﻭﻏﺎﺯ ﺛﺎﲏ ﺃﻛﺴﻴﺪ ﺍﻟﻜﺮﺑﻮﻥ . CO2 ﻣﺎ ﻋﺪﺩ ﻟﱰﺍﺕ ﺛﺎﲏ ﺃﻛﺴﻴﺪ ﺍﻟﻜﺮﺑﻮﻥ ﺍﻟﺘﻲ ﺗﺘﻜﻮﻥ ﻋﻨﺪ STPﺇﺫﺍ ﲢﻠﻞ 2.38 Kgﻣﻦ ﻛﺮﺑﻮﻧﺎﺕ ﺍﻟﻜﺎﻟﺴﻴﻮﻡ ﲤﺎ ﹰﻣﺎ؟ .44ﻋﻨﺪﻣﺎ ﻳﺼﺪﺃ ﺍﳊﺪﻳﺪ ﻳﻜﻮﻥ ﻗﺪ ﺗﻔﺎﻋﻞ ﻣﻊ ﺍﻷﻛﺴﺠﲔ ﻟﻴﻜﻮﻥ ﺃﻛﺴﻴﺪ ﺍﳊﺪﻳﺪ)(II )4Fe(s) + 3O2(g) → 2Fe2O3(s ﺍﺣﺴﺐ ﺣﺠﻢ ﻏﺎﺯ ﺍﻷﻛﺴﺠﲔ ﻋﻨﺪ STPﺍﻟﻼﺯﻡ ﻟﻴﺘﻔﺎﻋﻞ ﻣﻊ 52.0 gﻣﻦ ﺍﳊﺪﻳﺪ ﲤﺎ ﹰﻣﺎ. .45ﺃﺿﻴﻔﺖ ﻛﻤﻴﺔ ﻓﺎﺋﻀﺔ ﻣﻦ ﲪﺾ ﺍﻷﺳﻴﺘﻴﻚ ﺇﱃ 28gﻣﻦ ﻛﺮﺑﻮﻧﺎﺕ ﺍﻟﺼﻮﺩﻳﻮﻡ ﺍﳍﻴﺪﺭﻭﺟﻴﻨﻴﺔ ﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ،25 °Cﻭﺿﻐﻂ 1atmﻭﰲ ﺃﺛﻨﺎﺀ ﺍﻟﺘﻔﺎﻋﻞ ﺑﺮﺩ ﺍﻟﻐﺎﺯ ﺑﺤﻴﺚ ﺃﺻﺒﺤﺖ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺗﻪ ) .(20 °Cﻣﺎ ﺣﺠﻢ ﻏﺎﺯ ﺛﺎﲏ ﺃﻛﺴﻴﺪ ﺍﻟﻜﺮﺑﻮﻥ ﺍﻟﻨﺎﺗﺞ؟ )NaHCO3(aq) + CH3COOH(aq) → NaCH3COO(aq) + CO2(g) + H2O(l 112
7-12 ﺗﻌﺘﻤﺪ ﺍﻟﻌﻤﻠﻴﺎﺕ ﺍﻟﺼﻨﺎﻋﻴﺔ ﻋﲆ ﺍﳊﺴﺎﺑﺎﺕ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ ﺍﻟﺘﻲ ﺩﺭﺳﺘﻬﺎ ﰲ ﺍﻷﻣﺜﻠﺔ ﺍﻟﺴﺎﺑﻘﺔ؛ ﻓﻐﺎﺯ ﺍﻹﻳﺜﲔ C2H4ﻣﺜ ﹰﻼ ،ﻭﺍﻟﺬﻱ ﻳﺪﻋﻰ ﺃﻳ ﹰﻀﺎ ﺍﻹﺛﻴﻠﲔ ،ﻫﻮ ﺍﳌﺎﺩﺓ ﺍﳋﺎﻡ ﻟﺼﻨﺎﻋﺔ ﻣﺒﻠﻤﺮ ﺍﻟﺒﻮﱄ ﺇﻳﺜﻴﻠﲔ .ﻳﻨﺘﺞ ﺍﻟﺒﻮﱄ ﺇﺛﻴﻠﲔ ﻋﻨﺪﻣﺎ ﺗﺘﺤﺪ ﳎﻤﻮﻋﺔ ﻛﺒﲑﺓ ﻣﻦ ﺍﻟﻮﺣﺪﺍﺕ ﺍﻷﺳﺎﺳﻴﺔ )ﺟﺰﻳﺌﺎﺕ ﺍﻹﻳﺜﲔ (-CH2-CH2-ﰲ ﺻﻮﺭﺓ ﻧﻤﻂ ﻣﺘﻜﺮﺭ ﰲ ﺳﻼﺳﻞ .ﻭﺗﺴﺘﺨﺪﻡ ﻫﺬﻩ ﺍﳌﺒﻠﻤﺮﺍﺕ ﰲ ﺻﻨﺎﻋﺔ ﺍﻟﻜﺜﲑ ﻣﻦ ﻣﺴﺘﻠﺰﻣﺎﺕ ﺍﳊﻴﺎﺓ ﺍﻟﻴﻮﻣﻴﺔ ،ﻛﲈ ﻳﺒﲔ ﺍﻟﺸﻜﻞ .7-12ﻭﺍﳌﻌﺎﺩﻟﺔ ﺍﻟﺘﺎﻟﻴﺔ ﺗﻮﺿﺢ ﺍﻟﺼﻴﻐﺔ ﺍﻟﻌﺎﻣﺔ ﻟﺘﻔﺎﻋﻞ ﺍﻟﺒﻠﻤﺮﺓ ،ﺣﻴﺚ ﲤﺜﻞ nﻋﺪﺩ ﺍﻟﻮﺣﺪﺍﺕ ﺍﳌﺘﻜﺮﺭﺓ. —)n(C2H )4 (g) → —(CH2 –CH2)n(s ﻟﻮ ﻛﻨﺖ ﻣﻬﻨﺪ ﹰﺳﺎ ﰲ ﻣﺼﻨﻊ ﻟﺼﻨﺎﻋﺔ ﺍﻟﺒﻮﱄ ﺇﺛﻴﻠﲔ ﻓﺈﻧﻚ ﺳﺘﺤﺘﺎﺝ ﳌﻌﺮﻓﺔ ﺑﻌﺾ ﺧﺼﺎﺋﺺ ﻏﺎﺯ ﺍﻹﺛﻴﻠﲔ ،ﻭﻣﻌﺮﻓﺔ ﺗﻔﺎﻋﻼﺕ ﺍﻟﺒﻠﻤﺮﺓ ﺃﻳ ﹰﻀﺎ ،ﻭﺳﺘﺴﺎﻋﺪﻙ ﺍﳌﻌﻠﻮﻣﺎﺕ ﺍﳌﺘﻌﻠﻘﺔ ﺑﻘﻮﺍﻧﲔ ﺍﻟﻐﺎﺯﺍﺕ ﻋﲆ ﺣﺴﺎﺏ ﻛﺘﻠﺔ ﻭﺣﺠﻢ ﺍﳌﺎﺩﺓ ﺍﳋﺎﻡ ﺍﻟﻼﺯﻣﺔ ﲢﺖ ﺩﺭﺟﺎﺕ ﺣﺮﺍﺭﺓ ﻭﺿﻐﻂ ﳐﺘﻠﻔﺔ ﻟﺼﻨﺎﻋﺔ ﺃﻧﻮﺍﻉ ﳐﺘﻠﻔﺔ ﻣﻦ ﺍﻟﺒﻮﱄ ﺇﺛﻴﻠﲔ. .46اﻟﻔﻜﺮة اﻟﺮﺋﻴﺴﺔ ﻓﴪﻋﻨﺪﻣﺎﻳﺘﻔﺎﻋﻞﻏﺎﺯﺍﻟﻔﻠﻮﺭﻣﻊﺑﺨﺎﺭﺍﳌﺎﺀﳛﺪﺙﺍﻟﺘﻔﺎﻋﻞﺍﻵﰐ: اﻟﺘﻘﻮﻳﻢ 7-3 )2F2(g) + 2H O2 (g) → O2(g) + 4HF(g اﻟﺨﻼﺻﺔ ﲢـﺪﺩ ﺍﻟـﻤﻌﺎﻣـﻼﺕ ﰲ ﺍﳌﻌﺎﺩﻟـﺔﻓﺈﺫﺍ ﺑﺪﺃ ﺍﻟﺘﻔﺎﻋﻞ ﺑـ 2 Lﻣﻦ ﻏﺎﺯ ﺍﻟﻔﻠﻮﺭ ﻓﲈ ﺣﺠﻢ ﺑﺨﺎﺭ ﺍﳌﺎﺀ ) (Lﺍﻟﻼﺯﻡ ﻟﻠﺘﻔﺎﻋﻞ ﺍﻟﻜﻴﻤﻴﺎﺋﻴـﺔ ﺍﳌـﻮﺯﻭﻧــﺔ ﺍﻟﻨﺴـ ﹶﺐﻣﻊ ﻏﺎﺯ ﺍﻟﻔﻠﻮﺭ؟ ﻭﻣﺎ ﺣﺠﻢ ﻏﺎﺯ ﺍﻷﻛﺴﺠﲔ ﻭﻏﺎﺯ ﻓﻠﻮﺭﻳﺪ ﺍﳍﻴﺪﺭﻭﺟﲔ ﺍﻟﻨﺎﲡﲔ؟ ﺍﳊﺠـﻤـﻴـﺔ ﻟﻠﻐــﺎﺯﺍﺕ ﺍﳌﺘﻔﺎﻋﻠﺔ .47ﺣﻠﻞﻫﻞﻳﺘﻨﺎﺳﺐﺣﺠﻢﺍﻟﻐﺎﺯﺗﻨﺎﺳ ﹰﺒﺎﻃﺮﺩ ﹼﹰﻳﺎﺃﻭﻋﻜﺴ ﹰﹼﻴﺎﻣﻊﻋﺪﺩﻣﻮﻻﺕﺍﻟﻐﺎﺯﻋﻨﺪﺩﺭﺟﺔ ﻭﺍﻟﻨﺎﲡﺔ. ﺣﺮﺍﺭﺓ ﻭﺿﻐﻂ ﺛﺎﺑﺘﲔ؟ ﻓﴪ ﺇﺟﺎﺑﺘﻚ. ﻳﻤﻜﻦ ﺃﻥ ﺗﺴﺘﺨﺪﻡ ﻗﻮﺍﻧﲔ ﺍﻟﻐﺎﺯﺍﺕ .48ﺍﺣﺴﺐﻳﺸﻐﻞ 1molﻣﻦﺍﻟﻐﺎﺯﺣﺠ ﹰﲈﻣﻘﺪﺍﺭﻩ 22.4Lﻋﻨﺪ،STPﺍﺣﺴﺐﺩﺭﺟﺔﺍﳊﺮﺍﺭﺓ ﻣﻊ ﺍﳌﻌﺎﺩﻻﺕ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ ﺍﳌﻮﺯﻭﻧﺔ ﻭﺍﻟﻀﻐﻂ ﺍﻟﻼﺯﻣﲔ ﻹﺩﺧﺎﻝ 2 molﻣﻦ ﺍﻟﻐﺎﺯ ﰲ ﺣﺠﻢ 22.4 L ﳊﺴﺎﺏ ﻛﻤﻴﺎﺕ ﺍﻟﻐﺎﺯﺍﺕ ﺍﳌﺘﻔﺎﻋﻠﺔ .49ﻓﴪ ﺍﻟﺒﻴﺎﻧﺎﺕ ﻳﺘﻔﺎﻋﻞ ﻏﺎﺯ ﺍﻹﻳﺜﲔ C2H4ﻣﻊ ﻏﺎﺯ ﺍﻷﻛﺴﺠﲔ ﻟﻴﻜﻮﻧﺎ ﻏﺎﺯ ﺛﺎﲏ ﺃﻭ ﺍﻟﻨﺎﲡﺔ ﻋﻦ ﺍﻟﺘﻔﺎﻋﻞ.ﺃﻛﺴﻴﺪ ﺍﻟﻜﺮﺑﻮﻥ ﻭﺍﳌﺎﺀ .ﺍﻛﺘﺐ ﺍﳌﻌﺎﺩﻟﺔ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ ﺍﳌﻮﺯﻭﻧﺔ ﳍﺬﺍ ﺍﻟﺘﻔﺎﻋﻞ ،ﺛﻢ ﺟﺪ ﺍﻟﻨﺴﺒﺔ ﺍﳌﻮﻟﻴﺔ ﻟﻠﻤﻮﺍﺩ ﺍﳌﻮﺟﻮﺩﺓ ﻋﲆ ﻛﻞ ﺟﻬﺔ ﻣﻦ ﺍﳌﻌﺎﺩﻟﺔ.113
� ��� ﺗﻌﻴـﺶ ﺣﻴﺎﺗﻚ ﺍﻟﻴﻮﻣﻴﺔ ﻭﺗﻌﻤﻞ ﻭﺗﻠﻌـﺐ ﰲ ﺍﳍﻮﺍﺀ ﺣﻴﺚ ﻳﻜﻮﻥ ﺍﻟﻀﻐـﻂ 1atmﺗﻘﺮﻳ ﹰﺒـﺎ ،ﻭﻧﺴـﺒﺔ ﺍﻷﻛﺴـﺠﲔ ، 21%ﻓﻬـﻞ ﺗﺴـﺎﺀﻟﺖ ﻳﻮ ﹰﻣﺎ :ﻣـﺎﺫﺍ ﻳﻤﻜﻦ ﺃﻥ ﳛﺪﺙ ﻟﻮ ﻛﺎﻥ ﺍﻟﻀﻐﻂ ﻭﻧﺴـﺒﺔ ﺍﻷﻛﺴـﺠﲔ ﰲ ﺍﳍـﻮﺍﺀ ﺃﻛﺜﺮ؟ ﻫﻞ ﻛﻨﺖ ﺳـﺘﺘﻌﺎﰱ ﻣﻦ ﺍﳌﺮﺽ ﺃﻭ ﺍﻟﺸﻜﻞ 2ﺗﺒﺎﺩﻝ ﺍﻟﻐﺎﺯﺍﺕ ﺑﲔ ﺍﻟﺮﺋﺘﲔ ﻭﺟﻬﺎﺯ ﺍﻟﺪﻭﺭﺍﻥ. ﺍﳉﺮﻭﺡ ﺑﴪﻋﺔ؟ ﻫﺬﻩ ﺍﻷﺳﺌﻠﺔ ﻫﻲ ﺟﻮﻫﺮ ﺍﻟﻌﻼﺝ ﺑﺎﻷﻛﺴﺠﲔ ﺍﺳﺘﺨﺪﻡ ﺍﻟﺸﻜﻞ 2ﳌﻌﺮﻓﺔ ﺍﳌﻀﻐﻮﻁ.ﻛﻴﻒ ﻳﺴﺎﻋﺪ ) (HBOTﻋﲆ ﻋﻼﺝ ﺍﻟﺘﺴﻤﻢ ﺑﻐﺎﺯ ﺃﻭﻝ ﺃﻛﺴﻴﺪ Hyperbaric medicine ﺇﻥ ﻛﻠﻤـﺔ ) (hyperﺗﻌﻨﻲ ﻋﺎﻟ ﹰﻴـﺎ ﺃﻭ ﺯﺍﺋ ﹰﺪﺍ .ﻭ) (barﻫﻲ ﻭﺣﺪﺓ ﺍﻟﻜﺮﺑﻮﻥ. ﺍﻟﻀﻐـﻂ ،ﻭﺗﺴـﺎﻭﻱ ،100 KPaﻭﻫﺬﺍ ﺗﻘﺮﻳ ﹰﺒـﺎ ﺍﻟﻀﻐﻂ ﺍﳉﻮﻱ ﺍﻟﻄﺒﻴﻌﻲ .ﳍـﺬﺍ ﻓﺈﻥ ﺍﳌﺼﻄﻠﺢ hyperbaricﻳﺸـﲑ ﺇﱃ ﺿﻐﻂ ﻳﻨﺘﻘﻞ ﻏﺎﺯ O2ﻣـﻦ ﺍﻟﺮﺋﺘﲔ ﺇﱃ ﺍﻟﺪﻡ، ﺃﻋـﲆ ﻣﻦ ﺍﻟﻀﻐـﻂ ﺍﻟﻄﺒﻴﻌﻲ .ﻳﺘﻌﺮﺽ ﺍﳌـﺮﴇ ﺍﻟﺬﻳﻦ ﻳﻌﺎﳉﻮﻥ ﺑﺎﻷﻛﺴـﺠﲔ ﺍﳌﻀﻐـﻮﻁ ﻟﻀﻐﻂ ﺃﻋﲆ ﻣﻦ ﺍﻟﻀﻐـﻂ ﺍﳉﻮﻱ ﻋﻨﺪﻭﻳﺮﺗﺒـﻂ ﻣiﻊ.aﻫﻴ7ﻤ3ﻮ6ﺟﻠ4ﻮﺑ87ﲔ-ﺍﻟAـﺪ5ﻡ-0ﰲ3ﺧ1ﻼCﻳﺎ ﺍﻟﺪﻡ ﺍﳊﻤﺮﺍﺀ ،ﻓﻴﺘﺤﺮﺭ ﺛﺎﲏ ﺃﻛﺴﻴﺪ ﺍﻟﻜﺮﺑﻮﻥ bCeO2ﻛﲈ ﻳﻈﻬﺮ ﻋﻨﺪ ﺍﳌﻮﺿﻊ . A ﻣﺴﺘﻮ ﺳﻄﺢ ﺍﻟﺒﺤﺮ. ﻳﺮﺗﺒـﻂ ﺍﺭﺗﻔﺎﻉ ﺍﻟﻀﻐـﻂ ﻏﺎﻟ ﹰﺒﺎ ﻣـﻊ ﺍﺭﺗﻔﺎﻉ ﺇﺫﺍ ﺩﺧﻞ ﺃﻭﻝ ﺃﻛﺴـﻴﺪ ﺍﻟﻜﺮﺑﻮﻥ ﺇﱃ ﺗﺮﻛﻴـﺰ ﺍﻷﻛﺴـﺠﲔ ﺍﻟـﺬﻱ ﻳﺘﻠﻘـﺎﻩ ﺍﳌـﺮﴇ .ﻭﻳﺸـﲑ ﺍﻟﻌـﻼﺝ ﺑﺎﻷﻛﺴﺠﲔ ﺍﳌﻀﻐﻮﻁ ) (HBOTﺇﱃ ﻋﻼﺝ ﺑﻮﺳﺎﻃﺔ ﺃﻛﺴﺠﲔﺍﻟـﺪﻡ ﻛﲈ ﻳﻮﺿﺤﻪ ﺍﻟﺮﻣـﺰ ،Bﻋﻮ ﹰﺿﺎ ﻋﻦ ﺍﻷﻛﺴـﺠﲔ ﻓﺈﻧﻪ ﻳﺮﺗﺒﻂ ﺗﺮﻛﻴـﺰﻩ .100%ﻭﻳﺒﲔ ﺍﻟﺸـﻜﻞ 1ﻏﺮﻓﺔ ﺍﳌﻌﺎﳉﺔ ﺑﺎﻷﻛﺴـﺠﲔﻣﻊ ﺍﳍﻴﻤﻮﺟﻠﻮﺑﲔ ،ﻭﺗﺒﺪﺃ ﺧﻼﻳﺎ ﺍﳉﺴﻢ ﲤﻮﺕ ﻧﺘﻴﺠﺔ ﺣﺮﻣﺎﳖﺎ ﻣﻦ ﺍﳌﻀﻐـﻮﻁ؛ ﺣﻴﺚ ﻳﻤﻜـﻦ ﺃﻥ ﻳﺼﻞ ﺍﻟﻀﻐﻂ ﰲ ﻫـﺬﻩ ﺍﻟﻐﺮﻓﺔ ﺇﱃ ﲬﺴﺔ ﺃﻭ ﺳﺘﺔ ﺃﺿﻌﺎﻑ ﺍﻟﻀﻐﻂ ﺍﻟﻌﺎﺩﻱ .ﻭﺗﺴﺘﺨﺪﻡ HBOTﰲ ﺍﻷﻛﺴﺠﲔ. ﻣﻌﺎﳉﺔ ﺍﻟﻜﺜـﲑ ﻣﻦ ﺍﳊﺎﻻﺕ ،ﻭﻣﻨﻬﺎ ﺍﳊﺮﻭﻕ ﻭﺍﻟﺪﻭﺍﺭ ﻭﺍﳉﺮﻭﺡ ﺑﺎﻹﺿﺎﻓﺔ ﺇﱃ ﺍﻷﻛﺴـﺠﲔ ﺍﻟﺬﻱ ﺍﻟﺘﻲ ﻻ ﺗﻠﺘﺌﻢ ﺑﴪﻋﺔ ﻭﺍﻷﻧﻴﻤﻴﺎ ﻭﺑﻌﺾ ﺍﻷﻣﺮﺍﺽ ﺍﳌﻌﺪﻳﺔ.ﳛﻤﻠـﻪ ﺍﳍﻴﻤﻮﺟﻠﻮﺑﲔ ﻳﺬﻭﺏ ﺍﻷﻛﺴـﺠﲔ ﰲ ﺑﻼﺯﻣﺎ ﺍﻟﺪﻡ ﻛﲈ ﻫﻮﻣﺒﲔ ﰲ .Cﻭﺗﺴـﺎﻋﺪ ﺍﳌﻌﺎﳉﺔ ﺑﺎﻷﻛﺴﺠﲔ ) (HBOTﻋﲆ ﺯﻳﺎﺩﺓﺗﺮﻛﻴـﺰ ﺍﻷﻛﺴـﺠﲔ ﺍﳌﺬﺍﺏ ﺇﱃ ﺍﳌﻘـﺪﺍﺭ ﺍﻟﺬﻱ ﳛﺎﻓﻆ ﻋﲆ ﺍﳉﺴـﻢ ﺳﻠﻴ ﹰﲈ . ﻳﺴـﺎﻋﺪ ﺍﻷﻛﺴـﺠﲔﺍﳌﻀﻐـﻮﻁ ﻋـﲆ ﺍﻟﺘﺨﻠﺺ ﻣﻦ ﺃﻭﻝ ﺃﻛﺴـﻴﺪ ﺍﻟﻜﺮﺑـﻮﻥ ﺍﳌﺮﺗﺒﻂ ﻣﻊ ﺍﳍﻴﻤﻮﺟﻠﻮﺑﲔ ،ﻛﲈ ﻫﻮ ﻣﻮﺿﺢ ﰲ .D ﺃﻋﺪ ﻛﺘﻴﺐ ﻣﻌﻠﻮﻣﺎﺕ ﺣﻮﻝ 1ﻳﺴﺘﻠﻘﻲ ﺍﳌﺮﻳﺾﰲﻏﺮﻓﺔ ﺍﻟﻌﻼﺝﰲﺃﺛﻨﺎﺀ)،(HBOTﺍﺳـﺘﺨﺪﺍﻡ ) (HBOTﻟﻌـﻼﺝ ﺍﳉـﺮﻭﺡ ﺍﻟﺘـﻲ ﻻ ﺗﻠﺘﺌﻢ ﻭﻳﺘﺤﻜﻢ ﺍﻟﻔﻨﻲ ﰲ ﺍﻟﻀﻐﻂ ﻭﻧﺴﺒﺔ ﺍﻷﻛﺴﺠﲔ. ﺑﴪﻋﺔ. 114
ﻋﻨﺪﻣـﺎ ﻳﻜـﻮﻥ ﺿﻐـﻂ ﺑﺨﺎﺭ ﺍﳌـﺎﺀ ﺩﺍﺧﻞ ﺣﺒﺎﺕ ﺍﻟﻔﺸـﺎﺭ ﻛﺒ ﹰﲑﺍ ﺑﺸـﻜﻞ ﻛﺎ ﹴﻑ ،ﺗﺘﺤﻮﻝ ﺍﳊﺒﺎﺕ ﺇﱃ ﻓﻮﺷـﺎﺭ ﻭﺗﻄﻠﻖ ﺑﺨﺎﺭ ﻣﺎﺀ .ﻭﻳﻤﻜﻦ ﺍﺳـﺘﺨﺪﺍﻡ ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ ﰲ ﺇﳚﺎﺩ ﺍﻟﻀﻐﻂ ﰲ ﻫﺬﻩ ﺍﳊﺒﺎﺕ ﻋﻨﺪ ﺍﻧﻔﺠﺎﺭﻫﺎ. ﻣﺎ ﻣﻘﺪﺍﺭ ﺍﻟﻀﻐﻂ ﺍﻟﻼﺯﻡ ﻟﻨﻔﺶ ﺣﺒﺎﺕ ﺍﻟﻔﺸﺎﺭ؟ .12ﻗﺲ ﺍﻟﻜﺘﻠﺔ ﺍﻟﻨﻬﺎﺋﻴﺔ ﻟﻠﻜﺄﺱ ﻭﺍﻟﺰﻳﺖ ﻭﺍﻟﻔﺸﺎﺭ. ﳐﺒﺎﺭ ﻣﺪﺭﺝ 10 ml ﺣﺒﺎﺕ ﻓﺸﺎﺭ )(20-18 ﻛﺄﺱ ﺯﺟﺎﺟﻴﺔ 250 ml ﺯﻳﺖ ﻧﺒﺎﰐ 1.5 ml .13ﲣﻠﺺ ﻣﻦ ﺣﺒﺎﺕ ﻣﺎﺳﻚ ﻛﺄﺱ ﺷﺒﻜﺔ ﺗﺴﺨﲔ ﻣﺮﺑﻌﺔ 2 ﺍﻟﺬﺭﺓ ﻭﺍﻟﺰﻳﺖ ﺑﺎﺗﺒﺎﻉ ﺗﻌﻠﻴﲈﺕ ﻣﻌﻠﻤﻚ .ﻧ ﹼﻈﻒ ﺍﻷﺩﻭﺍﺕ ﻣﻴﺰﺍﻥ ﻣﻮﻗﺪ ﺑﻨﺰﻥ ﺍﳌﺨﺘﱪﻳﺔ ﻭﺿﻌﻬﺎ ﰲ ﺃﻣﺎﻛﻨﻬﺎ. ﻣﺎﺀ ﻣﻘﻄﺮ ﺣﺎﻣﻞ ﺣﻠﻘﺔ ﻭﺭﻕ ﺗﻨﺸﻴﻒ ﺣﻠﻘﺔ ﺣﺪﻳﺪﻳﺔ ﺻﻐﲑﺓCC ﺇﳚﺎﺩ ﺧﻼﻝ ﻣﻦ ﻭﺫﻟﻚ ﺑﺎﻟﻠﱰ، ﺍﻟﺬﺭﺓ ﺣﺒﺎﺕ ﺣﺠﻢ LLCECMMDF.D1NN EGAEOO FHBFPP GCIG HJDH AIKEI BJLFJ PHPL IM CKMGK DNLHLMOEMINPFJNOGKO DD EE FF GG HH A II B JJACA KKBDB ﺍﻟﻔﺮﻕ ﺑﲔ ﺣﺠﻢ ﺍﳌﺎﺀ ﺍﳌﻘﻄﺮ ﰲ ﺍﳌﺨﺒﺎﺭ ﻗﺒﻞ ﺇﺿﺎﻓﺔ ﺍﻟﺬﺭﺓ ﻭﺑﻌﺪﻩ. .1ﺍﻗﺮﺃ ﺗﻌﻠﻴﲈﺕ ﺍﻟﺴﻼﻣﺔ ﰲ ﺍﳌﺨﺘﱪ. .2ﺍﻟﻜﺘﻠﺔ ﺍﻟﻜﻠﻴﺔ ﻟﺒﺨﺎﺭ ﺍﳌﺎﺀ ﺍﳌﻨﻄﻠﻖ ﻣﺴﺘﺨﺪ ﹰﻣﺎ .2ﺍﻋﻤﻞ ﺟﺪﻭ ﹰﻻ ﻟﺘﺴﺠﻴﻞ ﺍﻟﺒﻴﺎﻧﺎﺕ. .3ﺿﻊ 5mlﺗﻘﺮﻳ ﹰﺒﺎ ﻣﻦ ﺍﳌﺎﺀ ﺍﳌﻘﻄﺮ ﰲ ﳐﺒﺎﺭ ﻣﺪﺭﺝ ،ﻭﺳﺠﻞ ﻗﻴﺎﺳﺎﺕ ﻛﺘﻞ ﺍﻟﻜﺄﺱ ﻭﺍﻟﺰﻳﺖ ﻭﺣﺒﺎﺕ ﺍﻟﺬﺭﺓ ﻗﺒﻞ ﺍﻟﻨﻔﺶ ﻭﺑﻌﺪﻩ. ﺣﺠﻤﻪ. .4ﺿﻊ 20 -18ﺣﺒﺔ ﻓﺸﺎﺭ ﰲ ﺍﳌﺨﺒﺎﺭ ﺍﳌﺪﺭﺝ ﻣﻊ ﺍﳌﺎﺀ ،ﻭﺣ ﹼﺮﻙ .3ﺍﺳﺘﺨﺪﻡ ﺍﻟﻜﺘﻠﺔ ﺍﳌﻮﻟﻴﺔ ﻟﻠﲈﺀ؛ ﻹﳚﺎﺩ ﻋﺪﺩ ﻣﻮﻻﺕ ﺍﳌﺨﺒﺎﺭ ﺍﳌﺪﺭﺝ ﺑﻠﻄﻒ؛ ﻟﺘﺠﱪ ﻓﻘﺎﻗﻴﻊ ﺍﳍﻮﺍﺀ ﻋﲆ ﺍﳋﺮﻭﺝ ،ﺍﳌﺎﺀ ﺍﳌﺘﺤﺮﺭﺓ. ﺛﻢ ﺳﺠﻞ ﺣﺠﻢ ﺍﳌﺎﺀ ﻭﺣﺒﺎﺕ ﺍﻟﺬﺭﺓ ﻣ ﹰﻌﺎ. .4ﺍﻋـﺘـﱪ ﺃﻥ ﺩﺭﺟـﺔ ﺣﺮﺍﺭﺓ ﺍﻟﺰﻳﺖ .5ﺃﺧﺮﺝ ﺍﳊﺒﺎﺕ ﻣﻦ ﺍﳌﺨﺒﺎﺭ ﺍﳌﺪﺭﺝ ﻭﺟﻔﻔﻬﺎ. ﺍﳌـﻐـﲇ 225˚Cﻫﻲ ﺩﺭﺟﺔ ﺣـﺮﺍﺭﺓ ﺍﻟـﻐـﺎﺯ ،ﻭﺍﺣﺴـﺐ .6ﺿﻊ ﺍﳊﺒﺎﺕ ﺍﳉﺎﻓﺔ ﻣﻊ 1.0 – 1.5 mlﻣﻦ ﺍﻟﺰﻳﺖ ﺍﻟﻨﺒﺎﰐ ﺿﻐـﻂ ﺍﻟﻐـﺎﺯ ﺑﺎﺳﺘﺨﺪﺍﻡ ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ. ﰲ ﻛﺄﺱ ﺯﺟﺎﺟﻴﺔ. .5ﺑﲔ ﺍﻟﻀﻐﻂ ﺍﳉﻮﻱ ﻭﺿﻐﻂ ﺑﺨﺎﺭ ﺍﳌﺎﺀ ﰲ ﺍﳊﺒﺎﺕ. .7ﻗﺲ ﺍﻟﻜﺘﻠﺔ ﺍﻟﻜﻠﻴﺔ ﻟﻠﻜﺄﺱ ﻭﺍﻟﺰﻳﺖ ﻭﺣﺒﺎﺕ ﺍﻟﺬﺭﺓ. .6ﳌﺎﺫﺍ ﱂ ﺗﻨﻔﺶ ﺣﺒﺎﺕ ﺍﻟﺬﺭﺓ ﲨﻴﻌﻬﺎ؟ .7ﺣ ﹼﺪﺩ ﻣﺼﺎﺩﺭ ﺍﳋﻄﺄ ﰲ ﻫﺬﻩ ﺍﻟﺘﺠﺮﺑﺔ، .8ﺭﻛﺐ ﺍﳉﻬﺎﺯ ،ﻛﲈ ﻳﻈﻬﺮ ﰲ ﺍﻟﺼﻮﺭﺓ. ﻭﺍﻗﱰﺡ ﻃﺮﻳﻘﺔ ﻟﺘﺼﺤﻴﺤﻬﺎ. .9ﺳﺨﻦ ﺍﻟﻜﺄﺱ ﲠﺪﻭﺀ ﺑﺎﺳﺘﺨﺪﺍﻡ ﺍﳌﻮﻗﺪ ،ﻭﺣ ﹼﺮﻙ ﺍﳌﻮﻗﺪ ﺇﱃ ﺍﻷﻣﺎﻡ ﻭﺍﳋﻠﻒ ﻟﺘﺴﺨﲔ ﺍﻟﺰﻳﺖ ﺑﺎﻟﺘﺴﺎﻭﻱ. .10ﻻﺣﻆ ﺍﻟﺘﻐﲑﺍﺕ ﰲ ﺣﺒﺎﺕ ﺍﻟﺬﺭﺓ ﰲ ﺃﺛﻨﺎﺀ ﺍﻟﺘﺴﺨﲔ ،ﺛﻢ ﻻﺧﺘﺒﺎﺭ ﻣﻘﺪﺍﺭ ﺍﻟﻀﻐﻂ ﺍﻟﻼﺯﻡ ﻟﻔﺮﻗﻌﺔ ﺃﻃﻔﺊ ﺍﳌﻮﻗﺪ ﻋﻨﺪﻣﺎ ﺗﺘﻔﺮﻗﻊ ﺣﺒﺎﺕ ﺍﻟﺬﺭﺓ. ﺃﻧﻮﺍﻉ ﳐﺘﻠﻔﺔ ﻣﻦ ﺣﺒﻮﺏ ﺍﻟﺬﺭﺓ. .11ﺍﺳﺘﺨﺪﻡ ﻣﺎﺳﻚ ﺍﻟﻜﺄﺱ ﻹﺑﻌﺎﺩ ﺍﻟﻜﺄﺱ ﻋﻦ ﺍﳊﻠﻘﺔ ،ﻭﺍﺗﺮﻛﻪ ﺣﺘﻰ ﻳﱪﺩ ﲤﺎ ﹰﻣﺎ. 115
اﻟﻔﻜﺮة اﻟﻌﺎﻣﺔ ﺗﺴﺘﺠﻴﺐ ﺍﻟﻐﺎﺯﺍﺕ ﻟﺘﻐﲑﺍﺕ ﻛﻞ ﻣﻦ ﺍﻟﻀﻐﻂ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻭﺍﳊﺠﻢ ﻭﻋﺪﺩ ﺍﳉﺴﻴﲈﺕ ﺑﻄﺮﺍﺋﻖ ﻳﻤﻜﻦ ﺍﻟﺘﻨﺒﺆ ﲠﺎ. 71 ﺇﺫﺍ ﺗﻐـﲑ ﺿﻐﻂ ﺃﻱ ﻛﻤﻴﺔ ﺛﺎﺑﺘـﺔ ﻣﻦ ﻏﺎﺯ ﺃﻭ ﺩﺭﺟﺔ • ﻳﻨﺺ ﻗﺎﻧﻮﻥ ﺑﻮﻳﻞ ﻋﲆ ﺃﻥ ﺣﺠﻢ ﻣﻘﺪﺍﺭ ﳏ ﹼﺪﺩ ﻣﻦ ﺍﻟﻐﺎﺯ ﻳﺘﻨﺎﺳﺐ ﻋﻜﺴ ﹼﹰﻴﺎ ﻣﻊ ﺿﻐﻄﻪ ﻋﻨﺪ ﺣﺮﺍﺭﲥﺎ ﺃﻭ ﺣﺠﻤﻬﺎ ﻓﺴﻮﻑ ﻳﺘﺄﺛﺮ ﺛﺒﻮﺕ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓP1V1 = P2V2 . ﺍﳌﺘﻐﲑﺍﻥ ﺍﻵﺧﺮﺍﻥ.• ﻳﻨﺺ ﻗﺎﻧﻮﻥ ﺷﺎﺭﻝ ﻋﲆ ﺃﻥ ﺣﺠﻢ ﻣﻘﺪﺍﺭ ﳏ ﹼﺪﺩ ﻣﻦ ﺍﻟﻐﺎﺯ ﻳﺘﻨﺎﺳﺐ ﻃﺮﺩ ﹰﹼﻳﺎ ﻣﻊ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺗﻪ _V1 = _V2 ﺍﳌﻄﻠﻘﺔ ﻋﻨﺪ ﺛﺒﻮﺕ ﺍﻟﻀﻐﻂ. • ﻗﺎﻧﻮﻥ ﺑﻮﻳﻞ T1 T2 • • ﺍﻟﺼﻔﺮ ﺍﳌﻄﻠﻖﻳﻨﺺ ﻗﺎﻧﻮﻥ ﺟﺎﻱ -ﻟﻮﺳﺎﻙ ﻋﲆ ﺃﻥ ﺿﻐﻂ ﻣﻘﺪﺍﺭ ﳏ ﹼﺪﺩ ﻣﻦ ﺍﻟﻐﺎﺯ ﻳﺘﻨﺎﺳﺐ ﻃﺮﺩ ﹰﹼﻳﺎ ﻣﻊ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺗﻪ ﺍﳌﻄﻠﻘﺔ ﻋﻨﺪ ﺛﺒﺎﺕ ﺍﳊﺠﻢ. • ﻗﺎﻧﻮﻥ ﺷﺎﺭﻝ • ﻗﺎﻧﻮﻥ ﺟﺎﻱ -ﻟﻮﺳﺎﻙ _P1 = _P2 • ﺍﻟﻘﺎﻧﻮﻥ ﺍﻟﻌﺎﻡ ﻟﻠﻐﺎﺯﺍﺕ T1 T2• ﻳﺮﺑﻂ ﺍﻟﻘﺎﻧﻮﻥ ﺍﻟﻌﺎﻡ ﻟﻠﻐﺎﺯﺍﺕ ﻛ ﹼﹰﻼ ﻣﻦ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻭﺍﻟﻀﻐﻂ ﻭﺍﳊﺠﻢ ﰲ ﻣﻌﺎﺩﻟﺔ ﻭﺍﺣﺪﺓ. _P1V1 = _P2V2 T1 T2 72 ﻳﺮﺑـﻂ ﻗﺎﻧـﻮﻥ ﺍﻟﻐـﺎﺯ ﺍﳌﺜﺎﱄ ﻋﺪﺩ ﺍﳉﺴـﻴﲈﺕ ﻣﻊ • ﻳﻨﺺ ﻣﺒﺪﺃ ﺃﻓﻮﺟﺎﺩﺭﻭ ﻋﲆ ﺃﻥ ﺍﳊﺠﻮﻡ ﺍﳌﺘﺴﺎﻭﻳﺔ ﻣﻦ ﺍﻟﻐﺎﺯﺍﺕ ﻋﻨﺪ ﻧﻔﺲ ﺍﻟﻀﻐﻂ ﻭﺩﺭﺟﺔ ﻛﻞ ﻣـﻦ ﺍﻟﻀﻐﻂ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺍﳊﺮﺍﺭﺓ ﲢﺘﻮﻱ ﻋﲆ ﺍﻟﻌﺪﺩ ﻧﻔﺴﻪ ﻣﻦ ﺍﳉﺴﻴﲈﺕ. • ﻳﺮﺑﻂ ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ ﻛﻤﻴﺔ ﺍﻟﻐﺎﺯ ﻣﻊ ﺿﻐﻄﻪ ﻭﺩﺭﺟﺔ ﺣﺮﺍﺭﺗﻪ ﻭﺣﺠﻤﻪ. ﻭﺍﳊﺠﻢ. PV = nRT • ﻳﻤﻜﻦ ﺍﺳﺘﺨﺪﺍﻡ ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ ﻹﳚﺎﺩ ﺍﻟﻜﺘﻠﺔ ﺍﳌﻮﻟﻴﺔ ﻟﻠﻐﺎﺯ ﺇﺫﺍ ﻛﺎﻧﺖ ﻛﺘﻠﺔ ﺍﻟﻐﺎﺯ ﻣﻌﺮﻭﻓﺔ، • ﻣﺒﺪﺃ ﺃﻓﻮﺟﺎﺩﺭﻭ • ﺍﳊﺠﻢ ﺍﳌﻮﱄ ﻭﻳﻤﻜﻦ ﺍﺳﺘﺨﺪﺍﻣﻪ ﺃﻳ ﹰﻀﺎ ﻹﳚﺎﺩ ﻛﺜﺎﻓﺔ ﺍﻟﻐﺎﺯ ﺇﺫﺍ ﻛﺎﻧﺖ ﻛﺘﻠﺘﻪ ﺍﳌﻮﻟﻴﺔ ﻣﻌﺮﻭﻓﺔ . _mRT _MP • ﺛﺎﺑﺖ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ M = D = • ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ PV RTﻣﻐﺎﻳ ﹰﺮﺍ ﺳﻠﻮ ﹰﻛﺎ ﺍﳌﻨﺨﻔﻀﺔ ﻋﻨﺪ ﺍﻟﻀﻐﻂ ﺍﻟﻌﺎﱄ ﻭﺩﺭﺟﺎﺕ ﺍﳊﺮﺍﺭﺓ ﺍﳊﻘﻴﻘﻴﺔ ﺍﻟﻐﺎﺯﺍﺕ ﺗﺴﻠﻚ • ﻟﺴﻠﻮﻙ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ. 73 ﻋﻨﺪﻣـﺎ ﺗﺘﻔﺎﻋﻞ ﺍﻟﻐـﺎﺯﺍﺕ ﻓـﺈﻥ ﺍﳌﻌﺎﻣـﻼﺕ ﰲ • ﲢﺪﺩ ﺍﳌﻌﺎﻣﻼﺕ ﰲ ﺍﳌﻌﺎﺩﻻﺕ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ ﺍﳌﻮﺯﻭﻧﺔ ﺍﻟﻨﺴﺐ ﺍﳊﺠﻤﻴﺔ ﻟﻠﻐﺎﺯﺍﺕ ﺍﳌﺘﻔﺎﻋﻠﺔ ﺍﳌﻌـﺎﺩﻻﺕ ﺍﻟﻜﻴﻤﻴﺎﺋﻴـﺔ ﺍﳌﻮﺯﻭﻧـﺔ ﻭﺍﻟﻨﺎﲡﺔ.ﺍﻟﺘﻲ ﲤﺜﻞ ﻫﺬﻩ ﺍﻟﺘﻔﺎﻋﻼﺕ ﺗﺸـﲑ • ﻳﻤﻜﻦ ﺃﻥ ﺗﺴﺘﺨﺪﻡ ﻗﻮﺍﻧﲔ ﺍﻟﻐﺎﺯﺍﺕ ﻣﻊ ﺍﳌﻌﺎﺩﻟﺔ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ ﺍﳌﻮﺯﻭﻧﺔ ﳊﺴﺎﺏ ﻛﻤﻴﺎﺕ ﺇﱃ ﺃﻋـﺪﺍﺩ ﺍﳌـﻮﻻﺕ ﻭﺍﳊﺠـﻮﻡ ﺍﻟﻐﺎﺯﺍﺕ ﺍﳌﺘﻔﺎﻋﻠﺔ ﺃﻭ ﺍﻟﻨﺎﲡﺔ ﻋﻦ ﺍﻟﺘﻔﺎﻋﻞ. ﺍﻟﻨﺴﺒﻴﺔ ﻟﻠﻐﺎﺯﺍﺕ. 116
.57ﺍﺳﺘﻌﻤﻞ ﻗﻮﺍﻧﲔ ﺑﻮﻳﻞ ﻭﺷﺎﺭﻝ ﻭﺟﺎﻱ -ﻟﻮﺳﺎﻙ ﳊﺴﺎﺏ ml 7-1 ﺍﻟﻘﻴﻢ ﺍﳌﻔﻘﻮﺩﺓ ﰲ ﻛﻞ ﳑﺎ ﻳﺄﰐ: V1 = 2.0 L, P1 = 0.82 atm, V2 = 1.0 L، P2 .a .50ﺍﺫﻛﺮ ﻧﺼﻮﺹ ﻗﻮﺍﻧﲔ ﺑﻮﻳﻞ ،ﻭﺷﺎﺭﻝ ،ﻭﺟﺎﻱ -ﻟﻮﺳﺎﻙ ?= ﻭﺍﻟﻘﺎﻧﻮﻥ ﺍﻟﻌﺎﻡ ﻟﻠﻐﺎﺯﺍﺕ ،ﻭﺍﻛﺘﺐ ﻣﻌﺎﺩﻻﲥﺎ.V 1 = 250 mL, T 1 = ?, V 2 = 400 mL, .b .51ﺇﺫﺍ ﺗﻨﺎﺳﺐ ﻣﺘﻐﲑﺍﻥ ﺗﻨﺎﺳ ﹼﹰﺒﺎ ﻋﻜﺴ ﹰﹼﻴﺎ ﻓﲈﺫﺍ ﳛﺪﺙ ﻷﺣﺪﳘﺎ ﺇﺫﺍ ﺯﺍﺩ ﺍﻵﺧﺮ؟ T2 = 298 K .52ﺇﺫﺍ ﺗﻨﺎﺳﺐ ﻣﺘﻐﲑﺍﻥ ﺗﻨﺎﺳ ﹰﹼﺒﺎ ﻃﺮﺩ ﹼﹰﻳﺎ ﻓﲈﺫﺍ ﳛﺪﺙ ﻷﺣﺪﳘﺎ ﺇﺫﺍV 1 = 0.55 L, P 1 =740 mm Hg, V 2 = 0.80 L, .c ﺯﺍﺩ ﺍﻵﺧﺮ؟ ? = P2 .53ﻣﺎ ﺍﻟﻈﺮﻭﻑ ﺍﳌﻌﻴﺎﺭﻳﺔ ﺍﳌﺴﺘﺨﺪﻣﺔ ﰲ ﺣﺴﺎﺑﺎﺕ ﺍﻟﻐﺎﺯﺍﺕ؟ .58ﺇﺫﺍ ﻛﺎﻥ ﺣﺠﻢ ﻋﻴﻨﺔ ﻣﻦ ﺍﳍﻮﺍﺀ .54ﺣ ﹼﺪﺩ ﻭﺣﺪﺍﺕ ﺍﻟﻀﻐﻂ ﻭﺍﳊﺠﻢ ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺍﻷﻛﺜﺮ ﺍﺳﺘﻌﲈ ﹰﻻ. 2.5 Lﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ،22.0˚Cﻓﻜﻢ ﻳﺼﺒﺢ ﺣﺠﻢ ﻫﺬﻩﺍﻟﻌﻴﻨﺔ ﺇﺫﺍ ﻧﻘﻠﺖ ﺇﱃ ﺑﺎﻟﻮﻥ ﻫﻮﺍﺀ ﺳﺎﺧﻦ ،ﺣﻴﺚ ﺗﺒﻠﻎ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ 43.0˚C؟ ﺍﻓﱰﺽ ﺃﻥ ﺍﻟﻀﻐﻂ ﺛﺎﺑﺖ ﺩﺍﺧﻞ ﺍﻟﺒﺎﻟﻮﻥ. .55ﺍﺳﺘﻌﻤﻞ ﻗﺎﻧﻮﻥ ﺷﺎﺭﻝ ﻟﺘﺤﺪﻳﺪ ﺻﺤﺔ ﺑﻴﺎﻧﺎﺕ ﺍﻟﺸﻜﻞ .7-13 .59ﻣﺎ ﺿﻐﻂ ﺣﺠﻢ ﺛﺎﺑﺖ ﻣﻦ ﻏﺎﺯ ﺍﳍﻴﺪﺭﻭﺟﲔ ﻋﻨﺪ ﺩﺭﺟﺔﺣ ـﺮﺍﺭﺓ ،30.0˚Cﺇﺫﺍ ﻛﺎﻥ ﺿﻐﻂ ﻏﺎﺯ ﺍﳍﻴﺪﺭﻭﺟﲔ 1.11 atmﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ﻣﻘﺪﺍﺭﻫﺎ 15.0˚C؟ 800 700 .60ﻧﻘﻠﺖ ﻛﻤﻴﺔ ﻣﻦ ﻏﺎﺯ ﺍﻟﻨﻴﱰﻭﺟﲔ ﻣﻦ ﻭﻋﺎﺀ ﺻﻐﲑ ﺇﱃ ﻭﻋﺎﺀﺃﻛﱪ ﻣﻨﻪ ،ﻛﲈ ﻫﻮ ﻣﺒﲔ ﰲ ﺍﻟﺸﻜﻞ .7-14ﻣﺎ ﻣﻘﺪﺍﺭ ﺿﻐﻂ )(300 K, 600 ml 600 ﻏﺎﺯ ﺍﻟﻨﻴﱰﻭﺟﲔ ﰲ ﺍﻟﻮﻋﺎﺀ ﺍﻟﺜﺎﲏ؟ 500 )400 (200 K, 400 ml N2 300 N2 )200 (100 K, 200 ml 100 V1 = 500 ml V2 = 750 ml P1 = 108 KPa T2 = 21.0°C 00 50 100 150 200 250 300 350 400 T1 = 10.0°C K ﺍﻟﺸﻜﻞ 7-14 ﺍﻟﺸﻜﻞ 7-13 7-2 .56ﺃﻃﻠﻖ ﺑﺎﻟﻮﻥ ﻃﻘﺲ ،ﻭﻛﺎﻥ ﺣﺠﻤﻪ 5.0 X 104 Lﻋﻨﺪﻣﺎ ﻛﺎﻥ ﺿﻐﻄﻪ ،0.995 atmﻭﺩﺭﺟﺔ .61ﺍﺫﻛﺮ ﻧﺺ ﻣﺒﺪﺃ ﺃﻓﻮﺟﺎﺩﺭﻭ. ﺣﺮﺍﺭﺓ ﺍﳌﺤﻴﻂ ، 32.0˚Cﻭﺑﻌﺪ ﺇﻃﻼﻗﻪ ﺍﺭﺗﻔﻊ ﺇﱃ ﻋﻠﻮ ﻛﺎﻥ ﺍﻟﻀﻐﻂ ﻋﻨﺪﻩ 0.720 atmﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ – .12.0˚C .62ﺍﺫﻛﺮ ﻧﺺ ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ. ﺍﺣﺴﺐ ﺣﺠﻢ ﺍﻟﺒﺎﻟﻮﻥ ﻋﻨﺪ ﻫﺬﺍ ﺍﻻﺭﺗﻔﺎﻉ.117
.72ﺣ ﹼﺪﺩ ﻛﺜﺎﻓﺔ ﻏﺎﺯ ﺍﻟﻜﻠﻮﺭ ﻋﻨﺪ ﺩﺭﺟﺔ 22.0˚Cﻭﺿﻐﻂ .63ﻣﺎ ﺣﺠﻢ 1molﻣﻦ ﺍﻟﻐﺎﺯ ﰲ ﺍﻟﻈﺮﻭﻑ ﺍﳌﻌﻴﺎﺭﻳﺔ؟ ﻭﻣﺎ ﺟﻮﻱ ).(1.00 atm ﺣﺠﻢ 2molﻣﻦ ﺍﻟﻐﺎﺯ ﰲ ﺍﻟﻈﺮﻭﻑ ﺍﳌﻌﻴﺎﺭﻳﺔ؟ .73ﺃﻱ ﺍﻟﻐﺎﺯﺍﺕ ﰲ ﺍﻟﺸﻜﻞ 7-15ﻳﺸﻐﻞ ﺍﳊﺠﻢ ﺍﻷﻛﱪ ﰲ ﺍﻟﻈﺮﻭﻑ ﺍﳌﻌﻴﺎﺭﻳﺔ STP؟ ﻓﴪ ﺇﺟﺎﺑﺘﻚ. .64ﻣﺎ ﺍﳌﻘﺼﻮﺩ ﺑﺎﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ؟ ﻭﳌﺎﺫﺍ ﻻ ﻳﻮﺟﺪ ﻣﺜﻞ ﻫﺬﺍ ﺍﻟﻐﺎﺯ .74ﺇﺫﺍ ﺍﺣﺘﻮ ﻛﻞ ﻣﻦ ﺍﻟﻮﻋﺎﺋﲔ ﰲ ﺍﻟﺸﻜﻞ 7-15ﻋﲆ 4.0L ﰲ ﺍﻟﻄﺒﻴﻌﺔ؟ﻣﻦ ﺍﻟﻐﺎﺯ ﻓﲈ ﻣﻘﺪﺍﺭ ﺍﻟﻀﻐﻂ ﰲ ﻛﻞ ﻣﻨﻬﲈ؟ ﺍﻓﱰﺽ ﺃﻥ .65ﻣﺎ ﺍﻟﴩﻃﺎﻥ ﺍﻟﻠﺬﺍﻥ ﻻ ﻳﻤﻜﻦ ﺃﻥ ﻳﻜﻮﻥ ﺳﻠﻮﻙ ﺍﻟﻐﺎﺯ ﻋﻨﺪﳘﺎ ﺍﻟﻐﺎﺯﺍﺕ ﻣﺜﺎﻟﻴﺔ. ﻣﺜﺎﻟ ﹰﹼﻴﺎ؟ .66ﻣﺎ ﻭﺣﺪﺍﺕ ﺍﳊﺮﺍﺭﺓ ﰲ ﻣﻌﺎﺩﻟﺔ ﻗﺎﻧﻮﻥ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ؟ ﻓﴪ ﺫﻟﻚ.C3H8 N2 .67ﻳﺴـﺘﻌﻤﻞ ﻏـﺎﺯ ﺍﻟﱪﻭﺑـﺎﻥ C3H8ﻓـﻲ ﺍﳌﻨـﺎﺯﻝ ﻷﻏﺮﺍﺽ ﺍﻟﻄﻬﻲ ﻭﺍﻟﺘﺪﻓﺌﺔ .C3H8 N2 .aﺍﺣﺴـﺐ ﺣﺠـﻢ 0.540 molﻣﻦ ﺍﻟﱪﻭﺑﺎﻥ ﰲ ﺍﻟﻈﺮﻭﻑ ﺍﳌﻌﻴﺎﺭﻳﺔ. ﺍﻟﺸﻜﻞ 7-15 .bﻓﻜﺮ ﰲ ﺣﺠﻢ ﻫﺬﻩ ﺍﻟﻜﻤﻴﺔ ﻭﻣﻘﺪﺍﺭ ﺍﻟﱪﻭﺑﺎﻥ ﺍﳌﻮﺟﻮﺩ .75ﹸﻣﻠﺊ ﺩﻭﺭﻕ ﺣﺠﻤﻪ 2.00 Lﺑﻐﺎﺯ ﺍﻹﻳﺜﺎﻥ C2H6ﻣﻦ ﻓﻴﻬﺎ ،ﺛﻢ ﻓﴪ ﳌﺎﺫﺍ ﻳﺘﺤﻮﻝ ﻏﺎﺯ ﺍﻟﱪﻭﺑﺎﻥ ﺇﱃ ﺳﺎﺋﻞ ﻗﺒﻞﺃﺳﻄﻮﺍﻧﺔ ﺻﻐﲑﺓ ،ﻛﲈ ﻳﻈﻬﺮ ﰲ ﺍﻟﺸﻜﻞ .7-16ﻣﺎ ﻛﺘﻠﺔ ﻧﻘﻠﻪ؟ﺍﻹﻳﺜﺎﻥ ﰲ ﺍﻟﺪiﻭaﺭ7.ﻕ3؟C13-14A-8746 P = b11.50e.80n°aCtm .68ﻗﺎﺱ ﻛﻴﻤﻴﺎﺋﻲ ﺃﻗﻞ ﺿﻐﻂ ﻳﻤﻜﻦ T = ﺍﻟﻮﺻﻮﻝ ﺇﻟﻴﻪ ﰲ ﺍﳌﺨﺘﱪ ﻓﻜﺎﻥ ،1.0 X 10-15 mm Hg 2.0 3.0 ﻣﺎ ﻋﺪﺩ ﺟﺴﻴﲈﺕ ﻏﺎﺯ ﺣﺠﻤﻪ 1.00 Lﻭﺩﺭﺟﺔ ﺣﺮﺍﺭﺗﻪ 0.0 1.0 Atm 4.0 5.0 22.0˚Cﻋﻨﺪ ﻫﺬﺍ ﺍﻟﻀﻐﻂ؟ .69ﺍﺣﺴﺐ ﻋﺪﺩ ﻣﻮﻻﺕ O2ﺍﳌﻮﺟﻮﺩﺓ ﰲ ﻭﻋﺎﺀ ﻣﻐﻠﻖ ﺣﺠﻤﻪ 2.00 L ﻭﺩﺭﺟـﺔ ﺣـﺮﺍﺭﺗـﻪ ،25.0˚Cﺇﺫﺍ ﻛـﺎﻥ ﺿﻐﻄﻪ ).(3.50 atm ﺍﻟﺸﻜﻞ 7-16 ﻣﺎ ﻋﺪﺩ ﺍﳌﻮﻻﺕ ﺍﳌﻮﺟﻮﺩﺓ ﰲ ﺍﻟﻮﻋﺎﺀ ﺇﺫﺍ ﺍﺭﺗﻔﻌﺖ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﺇﱃ 49.0˚Cﻭﺑﻘﻲ ﺍﻟﻀﻐﻂ ﺛﺎﺑ ﹰﺘﺎ؟ .76ﻣﺎ ﻛـﺜـﺎﻓـﺔ ﻋﻴﻨﺔ ﻣﻦ ﻏﺎﺯ ﺍﻟﻨـﻴـﺘـﺮﻭﺟـﲔ ،N2ﺿﻐـﻄـﻬﺎi 5.30 atmﰲ.aﻭ7ﻋ3ﺎﺀ46ﺣ87ﺠ-ﻤAﻪ 3C.1530-1L0ﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ .70ﻳﻮﺟﺪ ﻣﺮﻛﺐ ﺟﲑﺍﻧﻴﻮﻝ ﰲ ﺯﻳﺖ ﺍﻟﻮﺭﺩ ﺍﳌﺴﺘﺨﺪﻡ ﻣﻘﺪﺍﺭﻫﺎ 125˚C؟ ben ﰲ ﺻﻨﺎﻋﺔ ﺍﻟﻌﻄﻮﺭ .ﻣﺎ ﺍﻟﻜﺘﻠﺔ ﺍﳌﻮﻟﻴﺔ ﻟﻠﺠﲑﺍﻧﻴﻮﻝ ﺇﺫﺍ ﻛﺎﻧﺖ ﻛﺜﺎﻓﺔ ﺑﺨﺎﺭﻩ ، 0.480 g/Lﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ 260.0˚C .77ﻣﺎ ﻋﺪﺩ ﻣﻮﻻﺕ ﻏﺎﺯ ﺍﳍﻴﻠﻴﻮﻡ Heﺍﻟﻼﺯﻣﺔ ﻟﺘﻌﺒﺌﺔ ﻭﻋﺎﺀﺣﺠﻤﻪ ،22 Lﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ، 35.0˚Cﻭﺿﻐﻂ ،ﻭﺿﻐﻂ ﺟﻮﻱ ﻣﻘﺪﺍﺭﻩ 0.140 atm؟ ﺟﻮﻱ ﻣﻘﺪﺍﺭﻩ 3.1 atm؟ .71ﺟﺪ ﺣﺠﻢ 42 gﻣﻦ ﻏﺎﺯ ﺃﻭﻝ ﺃﻛﺴﻴﺪ ﺍﻟﻜﺮﺑﻮﻥ ﰲ ﺍﻟﻈﺮﻭﻑ ﺍﳌﻌﻴﺎﺭﻳﺔ.STP 118
.78ﹶﺗﺸﺎﺭﻙ ﻏﺎﺯﺍﻥ ﻗﺒﻞ ﺍﻟﺘﻔﺎﻋﻞ ﰲ ﻭﻋﺎﺀ ﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ .86ﺍﺩﺭﺱ ﺍﻟﺘﻔﺎﻋﻞ ﺍﳌﺒﲔ ﺃﺩﻧﺎﻩ ﺛﻢ ﺃﺟﺐ ﻋﻦ ﺍﻷﺳﺌﻠﺔ ﺍﻟﺘﻲ ﺗﻠﻴﻪ: )2CO(g)+2NO(g) →N2(g)+2CO2(g ،200 Kﻭﺑﻌﺪ ﺍﻟﺘﻔﺎﻋﻞ ﺑﻘﻲ ﺍﻟﻨﺎﺗﺞ ﰲ ﺍﻟﻮﻋﺎﺀ ﻧﻔﺴﻪ ﻋﻨﺪ ﺩﺭﺟﺔ ،400 Kﻓﺈﺫﺍ ﻛﺎﻥ ﻛﻞ ﻣﻦ Vﻭ Pﺛﺎﺑﺘﲔ ،ﻓﲈ ﻗﻴﻤﺔ n .aﻣﺎ ﻧﺴﺒﺔ ﺣﺠﻢ ﺃﻭﻝ ﺃﻛﺴﻴﺪ ﺍﻟﻜﺮﺑﻮﻥ ﺇﱃ ﺣﺠﻢ ﺛﺎﲏ ﺃﻛﺴﻴﺪ ﺍﻟﻜﺮﺑﻮﻥ ﰲ ﺍﳌﻌﺎﺩﻟﺔ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ ﺍﳌﻮﺯﻭﻧﺔ. ﺍﳊﻘﻴﻘﻴﺔ؟ .bﺇﺫﺍ ﺗﻔﺎﻋﻞ 42.7 g CO2ﲤﺎ ﹰﻣﺎ ﻋﻨﺪ STPﻓﲈ ﺣﺠﻢ ﻏﺎﺯ 7-3 ﺍﻟﻨﻴﱰﻭﺟﲔ ﺍﻟﻨﺎﺗﺞ؟ .87ﻋﻨﺪﻣﺎ ﳛﱰﻕ 3.00 Lﻣﻦ ﻏﺎﺯ ﺍﻟﱪﻭﺑﺎﻥ ﲤﺎ ﹰﻣﺎ ﻹﻧﺘﺎﺝ ﺑﺨﺎﺭﺍﳌﺎﺀ ﻭﻏﺎﺯ ﺛﺎﲏ ﺃﻛﺴﻴﺪ ﺍﻟﻜﺮﺑﻮﻥ ﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ﺗﺴﺎﻭﻱ .79ﳌﺎﺫﺍ ﻳﻌﺪ ﻣﻦ ﺍﻟﴬﻭﺭﻱ ﻣﻮﺍﺯﻧﺔ ﺍﳌﻌﺎﺩﻟﺔ ﻗﺒﻞ ﺍﺳﺘﺨﺪﺍﻣﻬﺎ ﰲ 350°Cﻭﺿﻐﻂ ﺟﻮﻱ 0.990 atmﻓﲈ ﻛﺘﻠﺔ ﺑﺨﺎﺭ ﺍﳌﺎﺀ ﲢﺪﻳﺪ ﺣﺠﻮﻡ ﺍﻟﻐﺎﺯﺍﺕ ﺍﳌﺘﻀﻤﻨﺔ ﰲ ﺍﻟﺘﻔﺎﻋﻞ؟ ﺍﻟﻨﺎﲡﺔ؟ .80ﻟﻴﺲ ﻣﻦ ﺍﻟﴬﻭﺭﻱ ﺃﺧﺬ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻭﺍﻟﻀﻐﻂ ﺑﻌﲔ ﺍﻻﻋﺘﺒﺎﺭ ﻋﻨﺪ ﺍﺳﺘﺨﺪﺍﻡ ﺍﳌﻌﺎﻟﺔ ﺍﳌﻮﺯﻭﻧﺔ ﻟﺘﺤﺪﻳﺪ ﺍﳊﺠﻢ .88ﻋﻨﺪ ﺗﺴﺨﲔ ﻛﻠﻮﺭﺍﺕ ﺍﻟﺒﻮﺗﺎﺳﻴﻮﻡ ﺍﻟﺼﻠﺒﺔ KClO3ﻓﺈﳖﺎ ﺗﺘﺤﻠﻞ ﻟﺘﻨﺘﺞ ﻛﻠﻮﺭﻳﺪ ﺍﻟﺒﻮﺗﺎﺳﻴﻮﻡ ﺍﻟﺼﻠﺐ ﻭﻏﺎﺯ ﺍﻟﻨﺴﺒﻲ ﻟﻠﻐﺎﺯ .ﳌﺎﺫﺍ؟ﺍﻷﻛﺴﺠﲔ .ﻓﺈﺫﺍ ﲢﻠﻞ 20.8 gﻣﻦ ﻛﻠﻮﺭﺍﺕ ﺍﻟﺒﻮﺗﺎﺳﻴﻮﻡ،ﻓﲈ ﻋﺪﺩ ﻟﱰﺍﺕ ﻏﺎﺯ ﺍﻷﻛﺴﺠﲔ ﺍﻟﺘﻲ ﺳﺘﻨﺘﺞ ﰲ ﺍﻟﻈﺮﻭﻑ .81ﻓﴪ ﳌﺎﺫﺍ ﻻ ﲤﺜﻞ ﺍﳌﻌﺎﻣﻼﺕ ﰲ ﺍﳌﻌﺎﺩﻟﺔ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ ﺍﳌﻮﺯﻭﻧﺔ ﺃﻋﺪﺍﺩ ﺍﳌﻮﻻﺕ ﻓﻘﻂ ،ﻭﺇﻧﲈ ﺃﻳ ﹰﻀﺎ ﺍﳊﺠﻮﻡ ﺍﻟﻨﺴﺒﻴﺔ ﻟﻠﻐﺎﺯﺍﺕ؟ ﺍﳌﻌﻴﺎﺭﻳﺔ STP؟ .82ﻫﻞ ﲤﺜﻞ ﺍﳌﻌﺎﻣﻼﺕ ﰲ ﺍﳌﻌﺎﺩﻟﺔ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ ﺍﳌﻮﺯﻭﻧﺔ ﺍﳊﺠﻮﻡ ﺍﻟﻨﺴﺒﻴﺔ ﻟﻠﺴﻮﺍﺋﻞ ﻭﺍﳌﻮﺍﺩ ﺍﻟﺼﻠﺒﺔ؟ ﻓﴪ ﺇﺟﺎﺑﺘﻚ. .89ﺍﺣﺴﺐ ﺍﻟﻀﻐﻂ ﺩﺍﺧﻞ ﺃﻧﺒﻮﺏ ﺍﻟﺼﻮﺭﺓ ﰲ ﺍﻟﺘﻠﻔﺎﺯ، ﺇﺫﺍ ﻛﺎﻥ ﺣﺠﻤﻪ ،3.50Lﻭﳛﺘﻮﻱ ﻋﲆ 2.00X10-5 gﻣﻦ .83ﺗﺘﻜﻮﻥ ﺍﻷﻣﻮﻧﻴﺎ ﻣﻦ ﺗﻔﺎﻋﻞ ﻏﺎﺯ ﺍﻟﻨﻴﱰﻭﺟﲔ ﻏﺎﺯ ﺍﻟﻨﻴﱰﻭﺟﲔ ﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ﺗﺴﺎﻭﻱ ).(22.0°C ﻣﻊ ﻏﺎﺯ ﺍﳍﻴﺪﺭﻭﺟﲔ .ﻣﺎ ﻋﺪﺩ ﻟﱰﺍﺕ ﻏﺎﺯ ﺍﻷﻣﻮﻧﻴﺎ ﺍﻟﺘﻲ .90ﻋﺪﺩ ﺍﻟﻠﱰﺍﺕ ﺍﻟﺘﻲ ﻳﻤﻜﻦ ﺃﻥ ﺗﺸﻐﻠﻬﺎ ﻛﺘﻠﺔ ﻣﻘﺪﺍﺭﻫﺎ ﻳﻤﻜﻦ ﺇﻧﺘﺎﺟﻬﺎ ﻣﻦ 13.7 Lﻣﻦ ﻏﺎﺯ ﺍﳍﻴﺪﺭﻭﺟﲔ ﻋﻨﺪ 8.80 gﻣﻦ ﻏﺎﺯ ﺛﺎﲏ ﺃﻛﺴﻴﺪ ﺍﻟﻜﺮﺑﻮﻥ ﺍﳌﻮﺟﻮﺩﺓ ﻋﻨﺪ: 93.0°Cﻭﺿﻐﻂ ﻣﻘﺪﺍﺭﻩ 40.0 kPa؟ STP .a .84ﻋﻴﻨﺔ ﻣﻦ ﻏﺎﺯ ﻛﱪﻳﺘﻴﺪ ﺍﳍﻴﺪﺭﻭﺟﲔ ﺣﺠﻤﻬﺎ ،6.5 Lﲤﺖ ﻣﻌﺎﳉﺘﻬﺎ ﻣﻊ ﳏﻔﺰ ﻟﺘﴪﻳﻊ ﺍﻟﺘﻔﺎﻋﻞ ﺍﻵﰐ: 3.00 atm .bﻭ160°C )2H2S(g)+O2(g) → 2H2O(g)+2S(s 288 K .cﻭ 118 Kpa ﻓﺈﺫﺍ ﺗﻔﺎﻋﻞ H2Sﲤﺎ ﹰﻣﺎ ﻋﻨﺪ ﺿﻐﻂ 2.0 atmﻭﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ .91ﺇﺫﺍ ﺍﺣﱰﻕ 2.33 Lﻣﻦ ﻏﺎﺯ ﺍﻟﱪﻭﺑﺎﻥ ﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ﻣﻘﺪﺍﺭﻫﺎ 290 Kﻓﲈ ﻛﺘﻠﺔ) (gﺑﺨﺎﺭ ﺍﳌﺎﺀ ﺍﻟﻨﺎﺗﺞ. 24°Cﻭﺿﻐﻂ ﺟﻮﻱ 67.2 Kpaﺍﺣﱰﺍ ﹰﻗﺎ ﺗﺎ ﹰﹼﻣﺎ ﰲ ﻛﻤﻴﺔﻓﺎﺋﻀﺔ ﻣﻦ ﺍﻷﻛﺴﺠﲔ ،ﻓﲈ ﻋﺪﺩ ﻣﻮﻻﺕ ﺛﺎﲏ ﺃﻛﺴﻴﺪ .85ﻣﺎ ﻋﺪﺩ ﻟﱰﺍﺕ ﻏﺎﺯ ﺍﻟﻨﻴﱰﻭﺟﲔ ﻭﻏﺎﺯ ﺍﻷﻛﺴﺠﲔ ﺍﻟﻼﺯﻣﺔ ﻹﻧﺘﺎﺝ 15.4 Lﻣﻦ ﺃﻛﺴﻴﺪ ﺍﻟﻨﻴﱰﻭﺟﲔ ﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ﺍﻟﻜﺮﺑﻮﻥ ﺍﻟﺘﻲ ﺗﻨﺘﺞ؟ 310 Kﻭﺿﻐﻂ ﺟﻮﻱ 2.0 atm؟119
.92ﻳﺘﻨﻔﺲ ﺍﻹﻧﺴﺎﻥ 0.50 Lﻣﻦ ﺍﳍﻮﺍﺀ ﺗﻘﺮﻳ ﹰﺒﺎ ﺧﻼﻝ .97ﻋـﻨﺪﻣـﺎ ﻳﺘﻔﻜﻚ ﺍﻟﻨﻴﱰﻭﺟﻠـﴪﻳﻦ C3H5N3O9ﻓﺈﻧﻪﺍﻟﺘﻨﻔﺲ ﺍﻟﻄﺒﻴﻌﻲ .ﺍﻓﱰﺽ ﺃﻥ ﺫﻟﻚ ﻳﺘﻢ ﰲ ﺍﻟﻈﺮﻭﻑ ﻳﺘﺤﻠﻞ ﺇﱃ ﺍﻟﻐﺎﺯﺍﺕ ﺍﻵﺗﻴﺔ .CO2 ،N2، NO، H2O :ﻣﺎﺣﺠﻢ ﻣﺰﻳﺞ ﺍﻟﻐﺎﺯﺍﺕ ﺍﻟﻨﺎﲡﺔ ﻋﻨﺪ ﺿﻐﻂ 1.00 atmﻭﺩﺭﺟﺔ ﺍﻟﻄﺒﻴﻌﻴﺔ .STPﺣﺮﺍﺭﺓ 2678 °Cﺇﺫﺍ ﺗﻔﻜﻚ 239 gﻣﻦ ﺍﻟﻨﻴﱰﻭﺟﻠﴪﻳﻦ ؟ .aﻣﺎﺣﺠﻢﺍﻟﻨﻔﺲﺍﻟﻮﺍﺣﺪﰲﻳﻮﻡﺑﺎﺭﺩﻋﲆﻗﻤﺔﺟﺒﻞﺇﻓﺮﺳﺖﺇﺫﺍ ﻛﺎﻧﺖﺩﺭﺟﺔﺍﳊﺮﺍﺭﺓ،-60°Cﻭﺍﻟﻀﻐﻂ253mmHg؟ .98ﻣـﺎ ﺍﻟﻘﻴﻤـﺔ ﺍﻟﺮﻗﻤﻴـﺔ ﻟﺜﺎﺑـﺖ ﺍﻟﻐـﺎﺯ ﺍﳌﺜـﺎﱄ ) (Rﰲ _cm3·Pa .bﳛﺘﻮﻱ ﺍﳍﻮﺍﺀ ﺍﻟﻄﺒﻴﻌﻲ ﻋﲆ 21%ﺃﻛﺴﺠﲔ ،ﻓﺈﺫﺍ ﻛﺎﻥ ؟ ﺍﳌﻌﺎﺩﻟﺔ ﳛﺘﻮﻱ ﻋﲆ 14%ﻣﻦ ﺍﻷﻛﺴﺠﲔ ﻓﻮﻕ ﻗﻤﺔ ﺇﻓﺮﺳﺖ، K·mol .99ﻫﻞ ﻳﻜﻮﻥ ﺍﻟﻀﻐﻂ ﺍﳌﺤﺴﻮﺏ ﻣﻦ ﺧﻼﻝ ﻗﺎﻧﻮﻥﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ ﺃﻋﲆ ﺃﻡ ﺃﻗﻞ ﻣﻦ ﻗﻴﻤﺔ ﺍﻟﻀﻐﻂ ﺍﳊﻘﻴﻘﻲ ﻓﲈ ﺣﺠﻢ ﺍﳍﻮﺍﺀ ﺍﻟﺬﻱ ﳛﺘﺎﺝ ﺇﻟﻴﻪ ﺍﻹﻧﺴﺎﻥ ﻟﺘﺰﻭﻳﺪ ﺍﳉﺴﻢﺍﻟﺬﻱ ﲢﺪﺛﻪ ﻋﻴﻨﺔ ﻣﻦ ﺍﻟﻐﺎﺯ؟ ﻭﻛﻴﻒ ﻳﻜﻮﻥ ﺿﻐﻂ ﺍﻟﻐﺎﺯ ﺑﺎﳌﻘﺪﺍﺭ ﻧﻔﺴﻪ ﻣﻦ ﺍﻷﻛﺴﺠﲔ؟ﺍﳌﺤﺴﻮﺏ ﺑﺎﳌﻘﺎﺭﻧﺔ ﺑﺎﻟﻀﻐﻂ ﺍﳊﻘﻴﻘﻲ ﻋﻨﺪ ﺩﺭﺟﺎﺕ .93ﳛﱰﻕ ﻏﺎﺯ ﺍﳌﻴﺜﺎﻥ CH4ﻛﺎﻣ ﹰﻼ ﻋﻨﺪ ﺗﻔﺎﻋﻠﻪ ﻣﻊ ﻏﺎﺯ ﺣﺮﺍﺭﺓ ﻣﻨﺨﻔﻀﺔ؟ ﻓﴪ ﺇﺟﺎﺑﺘﻚ. ﺍﻷﻛﺴﺠﲔ ﻟﻴﻜﻮﻥ ﺛﺎﲏ ﺃﻛﺴﻴﺪ ﺍﻟﻜﺮﺑﻮﻥ ﻭﺑﺨﺎﺭ ﺍﳌﺎﺀ. .aﺍﻛﺘﺐ ﺍﳌﻌﺎﺩﻟﺔ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ ﺍﳌﻮﺯﻭﻧﺔ ﳍﺬﺍ ﺍﻟﺘﻔﺎﻋﻞ. .100ﻳﺴـﺘﺨﺪﻡ ﺃﺣـﺪ ﺍﳋﺒﺎﺯﻳـﻦ ﺻـﻮﺩﺍ ﺍﳋﺒـﺰ ﻟﻨﻔـﺦ .bﺍﻛﺘﺐ ﺍﻟﻨﺴﺒﺔ ﺍﳊﺠﻤﻴﺔ ﺑﲔ ﺍﳌﻴﺜﺎﻥ ﻭﺍﳌﺎﺀ ﰲ ﻫﺬﺍ ﺍﻟﺘﻔﺎﻋﻞ.ﺍﻟﻜﻌـﻚ ،ﻭﺗﺘﺤﻠـﻞ ﺻـﻮﺩﺍ ﺍﳋﺒـﺰ ﰲ ﺃﺛﻨـﺎﺀ ﺫﻟـﻚ ﻭﻓ ﹰﻘـﺎ ﻟﻠﺘﻔﺎﻋﻠﲔ ﺍﻵﺗﻴﲔ: .94ﳚﺐ ﺃﻥ ﻳﻜﻮﻥ ﺣﺠﻢ ﺑﺎﻟﻮﻥ ﻣﻦ ﺍﳍﻴﻠﻴﻮﻡ 3.8L )2NaHCO3(s) → Na2CO3(s) + H O2 (l) + CO2(g)NaHCO3(s + H+ → )H O2 (l + )CO2(g + Na + ﻋﲆ ﺍﻷﻗﻞ ﻟﲑﺗﻔﻊ ﰲ ﺍﳍﻮﺍﺀ ،ﻭﻋﻨﺪ ﺇﺿﺎﻓﺔ 0.1molﻣﻦ )(aq )(aqﺍﺣﺴﺐ ﺣﺠﻢ CO2ﺍﳌﺘﻜﻮﻥ ﻟﻜﻞ ﺟﺮﺍﻡ ﻣﻦ NaHCO3 ﺍﳍﻴﻠﻴﻮﻡ ﺇﱃ ﺍﻟﺒﺎﻟﻮﻥ ﺍﻟﻔﺎﺭﻍ ﺃﺻﺒﺢ ﺣﺠﻤﻪ ) .(2.8Lﻣﺎ ﻋﺪﺩﺟﺮﺍﻣﺎﺕ Heﺍﻟﺘﻲ ﳚﺐ ﺇﺿﺎﻓﺘﻬﺎ ﺇﱃ ﺍﻟﺒﺎﻟﻮﻥ ﺣﺘﻰ ﻳﺮﺗﻔﻊ؟ ﰲ ﻛﻼ ﺍﻟﺘﻔﺎﻋﻠﲔ .ﺍﻓﱰﺽ ﺃﻥ ﺍﻟﺘﻔﺎﻋﻞ ﳛﺪﺙ ﻋﻨﺪ 210°C ﺍﻓﱰﺽ ﺃﻥ ﻛ ﹰﹼﻼ ﻣﻦ T، Pﺛﺎﺑﺘﺎﻥ. ﻭﺿﻐﻂ ﺟﻮﻱ ﻣﻘﺪﺍﺭﻩ 0.985 atm .95ﻳﺴﺘﺨﺪﻡ ﻣﺼﻨﻊ ﻟﻸﻟﻌﺎﺏ ﺗﱰﺍﻓﻠﻮﺭﻭ ﺇﻳﺜﺎﻥ C2H2F4ﻋﻨﺪ ﺩﺭﺟ ـﺔ ﺣــﺮﺍﺭﺓ ﻋﺎﻟﻴﺔ ﳌـﻞﺀ ﺍﻟﻘﻮﺍﻟﺐ .101ﺣﻮﻝ ﻛﻞ ﻛﺘﻠﺔ ﳑﺎ ﻳﺄﰐ ﺇﱃ ﻣﺎ ﻳﻜﺎﻓﺌﻬﺎ ﺑـ : Kg 7.23 mg .c 247 g .a ﺍﻟﺒﻼﺳﺘﻴﻜﻴﺔ. .aﻣﺎ ﻛﺜﺎﻓﺔ C2H2F4ﺑﻮﺣﺪﺓ g\Lﰲ ﺍﻟﻈﺮﻭﻑ ﺍﳌﻌﻴﺎﺭﻳﺔ 975 mg .d 53 mg .b STP؟ .102ﺃﻱ ﺟﺴﻴﲈﺕ ﺍﻟﻐﺎﺯﺍﺕ ﺍﻵﺗﻴﺔ ﳍﺎ ﺃﻋﲆ ﻣﺘﻮﺳﻂ ﴎﻋﺔ، .bﺃﻭﺟﺪ ﻋﺪﺩ ﺍﳉﺰﺋﻴﺎﺕ ﰲ ﻟﱰ ﻣﻦ C2H2F4ﻋﻨﺪ ﺩﺭﺟﺔ ﻭﺃﳞﺎ ﳍﺎ ﺃﻗﻞ ﻣﺘﻮﺳﻂ ﴎﻋﺔ؟ ﺣﺮﺍﺭﺓ 220°Cﻭ 1atmﺿﻐﻂ ﺟﻮﻱ. .aﺃﻭﻝ ﺃﻛﺴﻴﺪ ﺍﻟﻜﺮﺑﻮﻥ ﻋﻨﺪ 90°C .96ﻳـﺰﻥ ﻣﻜﻌﺐ ﺻﻠـﺐ ﻣـﻦ ﺍﳉﻠﻴﺪ ﺍﳉـﺎﻑ 0.75 Kg .bﺛﺎﻟﺚ ﻓﻠﻮﺭﻳﺪ ﺍﻟﻨﻴﱰﻭﺟﲔ ﻋﻨﺪ 30°C ) (CO2ﺗﻘﺮﻳ ﹰﺒـﺎ ،ﻓﲈ ﺣﺠﻢ ﻏـﺎﺯ CO2ﰲ ﺍﻟﻈﺮﻭﻑ ﺍﳌﻌﻴﺎﺭﻳﺔ .cﺍﳌﻴﺜﺎﻥ ﻋﻨﺪ 90°C ﻋﻨﺪﻣﺎ ﻳﺘﺴﺎﻣﻲ ﺍﳌﻜﻌﺐ ﻛﻠ ﹼﹰﻴﺎ؟ .dﺃﻭﻝ ﺃﻛﺴﻴﺪ ﺍﻟﻜﺮﺑﻮﻥ ﻋﻨﺪ 30°C 120
.103ﺍﻛﺘﺐ ﺍﻟﺘﻮﺯﻳﻊ ﺍﻹﻟﻜﱰﻭﲏ ﻟﻜﻞ ﺫﺭﺓ ﻓﻴﲈ ﻳﺄﰐ : ﺗﺴـﺘﺨﺪﻡ ﺍﻷﻣﻮﻧﻴﺎ NH٣ﻓـﻲ ﻋﻤﻠﻴﺔ ﺻﻨﺎﻋﺔ .dﺍﻟﻜﺮﺑﺘﻮﻥ .aﺍﻟﻴﻮﺩﺍﻷﺳـﻤﺪﺓ ﻭﺍﻟﻤﺒـﺮﺩﺍﺕ ﻭﺍﻷﺻﺒـﺎﻍ ﻭﺍﻟﺒﻼﺳـﺘﻴﻚ .ﻭﻋﻤﻠﻴـﺔﻫﺎﺑـﺮ ﻃﺮﻳﻘﺔ ﻹﻧﺘـﺎﺝ ﺍﻷﻣﻮﻧﻴﺎ ﻣﻦ ﺧﻼﻝ ﺗﻔﺎﻋـﻞ ﺍﻟﻨﻴﺘﺮﻭﺟﻴﻦ .eﺍﻟﻜﺎﻟﺴﻴﻮﻡ .bﺍﻟﺒﻮﺭﻭﻥﻭﺍﻟﻬﻴﺪﺭﻭﺟﻴـﻦ .ﻭﺗﻤﺜـﻞ ﺍﻟﻤﻌﺎﺩﻟـﺔ ﺍﻵﺗﻴـﺔ ﻣﻌﺎﺩﻟـﺔ ﺍﻟﺘﻔﺎﻋﻞ .fﺍﻟﻜﺎﺩﻣﻴﻮﻡ .cﺍﻟﻜﺮﻭﻡ ﺍﻟﻤﻨﻌﻜﺲ: .104ﺍﺫﻛﺮ ﻋﺪﺩ ﺍﻹﻟﻜﱰﻭﻧﺎﺕ ﰲ ﻛﻞ ﻣﺴﺘﻮ ﻣﻦ ﻣﺴﺘﻮﻳﺎﺕ N2(g) + 3H2(g) 2NH3(g) + 92 kJ ﺍﻟﻄﺎﻗﺔ ،ﺛﻢ ﺍﻛﺘﺐ ﺍﻟﺒﻨﺎﺀ ﺍﻹﻟﻜﱰﻭﲏ ﺍﻟﻨﻘﻄﻲ ﻟﻜﻞ ﻋﻨﴫﻳﻮ ﹼﺿﺢ ﺍﻟﺸﻜﻞ 7-17ﺃﺛﺮ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻭﺍﻟﻀﻐﻂ ﰲ ﻣﻘﺪﺍﺭ ﻣﻦ ﺍﻟﻌﻨﺎﴏ ﺍﻵﺗﻴﺔ: ﺍﻷﻣﻮﻧﻴﺎ ﺍﻟﻨﺎﲡﺔ ﺧﻼﻝ ﻋﻤﻠﻴﺔ ﻫﺎﺑﺮ. B .d kr .a Br .e Sr .b Se .f P .c 70 350°C .105ﺇﺫﺍ ﺃﻋﻄﻴﺖ ﳏﻠﻮﻟﲔ ﺷﻔﺎﻓﲔ ﻋﺪﻳﻤﻲ ﺍﻟﻠﻮﻥ ،ﻭﻛﺎﻥ 60 400°C 50 ﺃﺣﺪﳘﺎ ﳛﺘﻮﻱ ﻣﺮﻛ ﹰﺒﺎ ﺃﻳﻮﻧ ﹰﹼﻴﺎ ،ﻭﺍﻵﺧﺮ ﻣﺮﻛ ﹰﺒﺎ ﺗﺴﺎﳘ ﹰﹼﻴﺎ، 40 450°C ﻓﻜﻴﻒ ﻳﻤﻜﻨﻚ ﲢﺪﻳﺪ ﺃﻱ ﺍﳌﺤﻠﻮﻟﲔ ﺃﻳـﻮﲏ ،ﻭﺃﳞﲈ 30 500°C 20 550°C ﺗﺴﺎﳘﻲ؟ 10 .106ﺍﻛﺘﺐ ﻣﻌﺎﺩﻟﺔ ﻛﻴﻤﻴﺎﺋﻴﺔ ﻣﻮﺯﻭﻧﺔ ﻟﻜﻞ ﺗﻔﺎﻋﻞ ﻣﻦ ﺍﻟﺘﻔﺎﻋﻼﺕ ﺍﻵﺗﻴﺔ: 0 0 100 atm200 300 400 .aﺇﺣﻼﻝ ﺍﻟﺰﻧﻚ ﻣﻜﺎﻥ ﺍﻟﻔﻀﺔ ﰲ ﳏﻠﻮﻝ ﻛﻠﻮﺭﻳﺪ ﺍﻟﻔﻀﺔ. ﺍﻟﺸﻜﻞ 7-17 .bﺗﻔﺎﻋﻞ ﻫﻴﺪﺭﻭﻛﺴﻴﺪ ﺍﻟﺼﻮﺩﻳﻮﻡ ﻭﲪﺾ ﺍﻟﻜﱪﻳﺘﻴﻚ .109ﻓﴪ ﻛﻴﻒ ﻧﺴﺒﺔ ﺍﳌﺮﺩﻭﺩ ﺍﳌﺌﻮﻳﺔ ﻟﻸﻣﻮﻧﻴﺎ ﺑﺎﻟﻀﻐﻂ ﻟﺘﻜﻮﻳﻦ ﻛﱪﻳﺘﺎﺕ ﺍﻟﺼﻮﺩﻳﻮﻡ ﻭﺍﳌﺎﺀ. ﻭﺩﺭﺟﺔ ﺍﳊﺮﺍﺭ7ﺓ؟C13-11A-87463 .110ﺗﺘﻢ ﻋﻤﻠﻴﺔ ﻫﺎﺑﺮ ﻋﻨﺪ ﺿﻐﻂ ﻣﻘﺪﺍﺭﻩ ،200 atm ﻭﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ،450˚Cﺣﻴﺚ ﺃﺛﺒﺘﺖ ﻫﺬﻩ ﺍﻟﻈﺮﻭﻑﺇﻣﻜﺎﻧﻴﺔ ﺇﻧﺘﺎﺝ ﻛﻤﻴﺔ ﻛﺒﲑﺓ ﻣﻦ ﺍﻷﻣﻮﻧﻴﺎ ﺧﻼﻝ ﺯﻣﻦ ﻗﺼﲑ. .107ﺣﻠﻢ ﻛﺜﲑﻭﻥ ﻓﻴﲈ ﻣﴣ .aﻣﺎﺃﺛﺮﺇﺟﺮﺍﺀﺍﻟﺘﻔﺎﻋﻞﻋﻨﺪﺿﻐﻂﺃﻋﲆﻣﻦ،200atm ﺑﺎﻟﻘﻴﺎﻡ ﺑﺮﺣﻠﺔ ﺣﻮﻝ ﺍﻟﻌﺎﱂ ﺑﺒﺎﻟﻮﻥ ﻫﻮﺍﺀ ﺳﺎﺧﻦ ،ﻭﻫﻮ ﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ﺍﻟﻮﻋﺎﺀ ﺍﻟﺬﻱ ﻳﺘﻢ ﻓﻴﻪ ﺍﻟﺘﻔﺎﻋﻞ؟ ﺣﻠﻢ ﱂ ﻳﺘﺤﻘﻖ ﺣﺘﻰ ﻋﺎﻡ 1999ﻡ .ﺍﻛﺘﺐ ﺗﺼﻮﺭﺍﺗﻚ .bﺗﺮ ،ﻛﻴﻒ ﻳﺆﺛﺮ ﺗﻘﻠﻴﻞ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ﺍﻟﺘﻔﺎﻋﻞ ﺇﱃ 450˚Cﻋﲆ ﺍﻟﺰﻣﻦ ﺍﻟﻼﺯﻡ ﻹﻧﺘﺎﺝ ﺍﻷﻣﻮﻧﻴﺎ؟ ﻋﻦ ﺍﻟﺮﺣﻠﺔ ،ﻭﺻﻒ ﻛﻴﻒ ﻳﺘﺤﻜﻢ ﺗﻐﲑ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ﺍﻟﺒﺎﻟﻮﻥ ﰲ ﺍﺭﺗﻔﺎﻉ ﺍﻟﺒﺎﻟﻮﻥ؟ .108ﺍﺑﺤﺚ ﰲ ﺃﺛﺮ ﻣﻨﻈﲈﺕ ﺍﻟﻐﺎﺯ ﺍﳌﻮﺟﻮﺩﺓ ﻋﲆ ﺃﺳﻄﻮﺍﻧﺎﺕ ﺍﳍﻮﺍﺀ ﺍﻟﺘﻲ ﻳﺴﺘﺨﺪﻣﻬﺎ ﺍﻟﻐﻮﺍﺻﻮﻥ ،ﻭﺍﴍﺣﻪ.121
.4ﻳﻌﺪ ﻫﻴﺪﺭﻭﻛﺴﻴﺪ ﺍﻟﺼﻮﺩﻳﻮﻡ NaOHﻗﺎﻋﺪﺓ ﻗﻮﻳﺔ، ﺗﺴﺘﺨﺪﻡ ﰲ ﻓﺘﺢ ﻣﺼﺎﺭﻑ ﺍﻟﴫﻑ ﺍﻟﺼﺤﻲ .ﻣﺎ ﻧﺴﺐ ﻣﻜﻮﻧﺎﺕ ﻫﻴﺪﺭﻭﻛﺴﻴﺪ ﺍﻟﺼﻮﺩﻳﻮﻡ؟ ﺍﺳﺘﺨﺪﻡ ﺍﻟﺮﺳﻢ ﺍﻟﺒﻴﺎﲏ ﺍﻵﰐ ﻟﻺﺟﺎﺑﺔ ﻋﻦ ﺍﻟﺴﺆﺍﻟﲔ :2 ، 157.48% Na, 60.00% O, 2.52% H .a 2.52% Na, 40.00% O, 57.48% H .b57.48% Na, 40.00% O, 2.52% H .c Kpa1200 A 40.00% Na, 2.52% O, 57.48% H .d 1000 B 800 .5ﻣﻠﺊ ﻣﻨﻄﺎﺩ ﺻﻐﲑ ﻭﻫــﻮ ﻋـﲆ ﺳﻄﺢ ﺍﻷﺭﺽ ﺑـ 600 C 5.66×106 Lﻣﻦ ﻏـﺎﺯ ﺍﳍـﻴﻠـﻴﻮﻡ ، Heﻭﻛﺎﻥ ﺍﻟﻀﻐـﻂﺩﺍﺧـﻞ ﺍﳌﻨـﻄﺎﺩ ،1.10 atmﻋﻨﺪ ﺩﺭﺟﺔ ﺣﺮﺍﺭﺓ ،25˚C 400 D ﻓﺈﺫﺍ ﺑﻘﻲ ﺍﻟﻀﻐﻂ ﺩﺍﺧﻞ ﺍﳌﻨﻄﺎﺩ ﺛﺎﺑ ﹰﺘﺎ ،ﻓﻜﻢ ﻳﻜﻮﻥ ﺣﺠﻤﻪ 200 ﻋﻨﺪ ﺍﺭﺗﻔﺎﻉ 2300 mﺣﻴﺚ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ 12˚C؟ 0 200 250 300 350 400 450 K 2.72 × 106 L .a .1ﺃﻱ ﳑﺎ ﻳﺄﰐ ﻳﻮﺿﺤﻪ ﺍﻟﺮﺳﻢ ﺍﻟﺒﻴﺎﲏ ﺃﻋﻼﻩ: 5.40 × 610 L .b 5.66 × 610 L .c .aﻋﻨﺪﻣﺎ ﺗﺰﺩﺍﺩ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ﻳﻘﻞ ﺍﻟﻀﻐﻂ. .d 5.92 × 610 L .bﻋﻨﺪﻣﺎ ﻳﺰﻳﺪ ﺍﻟﻀﻐﻂ ﻳﻘﻞ ﺍﳊﺠﻢ. . 3 .6ﻳﻮﺿﺢ ﺍﻟﺮﺳﻢ ﺍﻟﺒﻴﺎﲏ ﻧﺘﺎﺋﺞ ﲡﺮﺑﺔ ﺗﻢ ﻓﻴﻬﺎ ﲢﻠﻴﻞ ﻋﻋﻨﻨﺪﺪﻣﻣﺎﺎ 8ﻳﺗ0ﻘﺰ-ﻳ8ﻞﺪﺍ7ﻟﺩ3ﺭﻀn8ﺟﻐe2ﺔb8ﺍﻂ-ﺗﳊCﻘﺮ6ﺍﻞﺭ1ﺩﺓ-ﺭﻳ4ﻘ1ﺟﺔﻞCﺍﻋﳊﺪﺮﺩﺍ ﺍﺭﳌﺓ.ﻮﻻﺕ. .c .dﺍﻟﻌﻼﻗﺔ ﺑﲔ ﺩﺭﺟﺔ ﺍﳊـﺮﺍﺭﺓ ﻭﻛﺜﺎﻓﺔ ﺍﳍـﻮﺍﺀ .ﻣﺎ ﺍﳌﺘﻐﲑ .2ﺃﻱ ﺍﻟﻐﺎﺯﺍﺕ ﺍﻵﺗﻴﺔ ﻳﺴﻠﻚ ﺳﻠﻮﻙ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ؟ ﺍﳌﺴﺘﻘﻞ ﰲ ﻫﺬﻩ ﺍﻟﺘﺠﺮﺑﺔ؟ .aﺍﻟﻐﺎﺯ A .bﺍﻟﻐﺎﺯ B .cﺍﻟﻐﺎﺯ C .dﺍﻟﻐﺎﺯ D°C 200 160 .3ﻳﺴﺘﺨﺪﻡ ﲪﺾ ﺍﳍﻴﺪﺭﻭﻓﻠﻮﺭﻳﻚ HFﰲ ﺻﻨﺎﻋﺔ ﺍﻷﺩﻭﺍﺕ 120 1.00 1.20 1.40 ﺍﻹﻟﻜﱰﻭﻧﻴﺔ ،ﻭﻫﻮ ﻳﺘﻔﺎﻋﻞ ﻣﻊ ﺳﻠﻴﻜﺎﺕ ﺍﻟﻜﺎﻟﺴﻴﻮﻡ 80 ،CaSiO3ﺍﻟﺬﻱ ﻳﻌ ﹼﺪ ﺃﺣﺪ ﻣﻜﻮﻧﺎﺕ ﺍﻟﺰﺟﺎﺝ .ﻣﺎ ﺍﳋﺎﺻﻴﺔ 40 )(kg/m3 ﺍﻟﺘﻲ ﲢﻮﻝ ﺩﻭﻥ ﻧﻘﻞ ﲪﺾ ﺍﳍﻴﺪﺭﻭﻓﻠﻮﺭﻳﻚ ﺃﻭ ﲣﺰﻳﻨﻪ ﰲ 0 ﺃﻭﻋﻴﺔ ﺯﺟﺎﺟﻴﺔ؟ 0.80 .aﺧﺎﺻﻴﺔ ﻛﻴﻤﻴﺎﺋﻴﺔ .aﺍﻟﻜﺜﺎﻓﺔ .bﺧﺎﺻﻴﺔ ﻓﻴﺰﻳﺎﺋﻴﺔ ﻛﻤﻴﺔ .bﺍﻟﻜﺘﻠﺔ .cﺧﺎﺻﻴﺔ ﻓﻴﺰﻳﺎﺋﻴﺔ ﻧﻮﻋﻴﺔ .cﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ .dﺍﻟﺰﻣﻦ .dﺧﺎﺻﻴﺔ ﻛﻤﻴﺔ 122
.7ﺃﻱ ﺍﻟﺮﺳﻮﻡ ﺍﻟﺒﻴﺎﻧﻴﺔ ﺗﻮﺿﺢ ﺍﻟﻌﻼﻗﺔ ﺑﲔ ﺣﺠﻢ ﺍﻟﻐﺎﺯ ﻭﺿﻐﻄﻪ ﻋﻨﺪ ﺛﺒﺎﺕ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ. ﺍﺳﺘﺨﺪﻡ ﺍﳉﺪﻭﻝ ﺍﻵﰐ ﻟﻺﺟﺎﺑﺔ ﻋﻦ ﺍﻟﺴﺆﺍﻝ : 1220052004 mJm3 mJm3 VV 0.05 2/05 0.15 8/04 P .D P .A 0.05 3/05 0.03 9/04 0.06 4/05 0.05 10/04 V V P 0.13 5/05 0.03 11/04 P .E .B 0.05 6/05 0.04 12/04 0.09 7/05 0.02 1/05 .12ﻳﻌﺪ ﻏﺎﺯ ﺍﻟﺮﺍﺩﻭﻥ ﻣﻦ ﺍﻟﻐﺎﺯﺍﺕ ﺍﳌﺸﻌﺔ ،ﻭﻳﻨﺘﺞ ﻋﻨﺪﻣﺎ Vﻳﺘﺤﻠﻞ ﺍﻟﺮﺍﺩﻳﻮﻡ ﰲ ﺍﻟﺼﺨﻮﺭ ﻭﺍﻟﱰﺑﺔ ،ﻭﻫﻮ ﻣﺎﺩﺓ ﻣﴪﻃﻨﺔ.ﺗﻮﺿﺢ ﺍﻟﺒﻴﺎﻧﺎﺕ ﺃﻋﻼﻩ ﻣﺴﺘﻮﻳﺎﺕ ﺍﻟﺮﺍﺩﻭﻥ ﺍﻟﺘﻲ ﺗﻢ ﻗﻴﺎﺳﻬﺎ P .Cﰲ ﻣﻨﻄﻘﺔ ﻣﻌﻴﻨﺔ .ﺍﺧﱰ ﻃﺮﻳﻘﺔ ﻟﺘﻤﺜﻴﻞ ﻫﺬﻩ ﺍﻟﺒﻴﺎﻧﺎﺕ ﺑﻴﺎﻧ ﹰﻴﺎ. ﻓﴪ ﺳﺒﺐ ﺍﺧﺘﻴﺎﺭﻙ ﳍﺬﻩ ﺍﻟﻄﺮﻳﻘﺔ ﻭﻣﺜﻞ ﺍﻟﺒﻴﺎﻧﺎﺕ ﺑﻴﺎﻧ ﹰﻴﺎ. .8ﻣﺎ ﻣﻘﺪﺍﺭ ﺍﻟﻀﻐﻂ ﺍﻟﺬﻱ ﳛﺪﺛﻪ 0.0468 gﻣﻦ ﺍﻷﻣﻮﻧﻴﺎ NH3ﻋﲆ ﺟﺪﺭﺍﻥ ﻭﻋﺎﺀ ﺣﺠﻤﻪ 4.00 Lﻋﻨﺪ ﺩﺭﺟﺔ ،35.0 °Cﻋﲆ ﺍﻓﱰﺍﺽ ﺃﻧﻪ ﻳﺴﻠﻚ ﺳﻠﻮﻙ ﺍﻟﻐﺎﺯ ﺍﳌﺜﺎﱄ؟ 0.278 atm .d 0.0174 aattmmS6-0..4baA-868204-08 0.0٫126 atm .e 0.00198 0.296 atm .c .9ﺻﻒ ﺍﳌﻼﺣﻈﺎﺕ ﺍﻟﺘﻲ ﺗﻘﺪﻡ ﺩﻟﻴ ﹰﻼ ﻋﲆ ﺣﺪﻭﺙ ﺍﻟﺘﻔﺎﻋﻞ ﺍﻟﻜﻴﻤﻴﺎﺋﻲ. .10ﺣ ﹼﺪﺩ ﺳﺒﻌﺔ ﺟﺰﻳﺌﺎﺕ ﺛﻨﺎﺋﻴﺔ ﺍﻟﺬﺭﺓ ﻣﻮﺟﻮﺩﺓ ﰲ ﺍﻟﻄﺒﻴﻌﺔ، ﻭﻓﴪ ﳌﺎﺫﺍ ﺗﺘﺸﺎﺭﻙ ﺫﺭﺍﺕ ﻫﺬﻩ ﺍﳉﺰﻳﺌﺎﺕ ﰲ ﺯﻭﺝ ﻣﻦ ﺍﻹﻟﻜﱰﻭﻧﺎﺕ؟ .11ﻳﻮﺿﺢ ﺍﻟﺮﺳﻢ ﺃﺩﻧﺎﻩ ﺑﻨﺎﺀ ﻟﻮﻳﺲ ﻷﻳﻮﻥ ﺍﻟﻨﱰﺍﺕ ﺍﳌﺘﻌﺪﺩ ﺍﻟﺬﺭﺍﺕ ).(NO3- ﻋﺮﻑ ﻣﻔﻬﻮﻡ ﻣﺘﻌﺪﺩ ﺍﻟﺬﺭﺍﺕ ،ﻭﺃﻋ ﹺﻂ ﺃﻣﺜﻠﺔ ﻋﲆ ﺃﻳﻮﻧﺎﺕ ﺃﺧﺮ ﻣﻦ ﻫﺬﺍ ﺍﻟﻨﻮﻉO . ONO123
اﻟﻤﺨﺎﻟﻴﻂ واﻟﻤﺤﺎﻟﻴﻞ Mixtures and Solutions اﻟﻔﻜﺮة اﻟﻌﺎﻣﺔ ﻳﻮﺟﺪ ﺍﳌﺤﻠﻮﻝ ﰲ ﺻﻮﺭﺓ ﻏﺎﺯ ﺃﻭ ﺳﺎﺋﻞﺃﻭﺻﻠﺐﺍﻋﺘﲈ ﹰﺩﺍﻋﲆﺍﳊﺎﻟﺔﺍﻟﻔﻴﺰﻳﺎﺋﻴﺔﻟﻠﻤﺬﻳﺐ. 1-1أﻧﻮاع اﻟﻤﺨﺎﻟﻴﻂ اﻟﻔﻜﺮة اﻟﺮﺋﻴﺴﺔ ﺍﳌﺨﺎﻟﻴﻂ ﺇﻣﺎ ﻣﺘﺠﺎﻧﺴﺔ ﺃﻭ ﻏﲑ ﻣﺘﺠﺎﻧﺴﺔ. 1-2ﺗﺮﻛﻴﺰ اﻟﻤﺤﺎﻟﻴﻞ اﻟﻔﻜﺮة اﻟﺮﺋﻴﺴﺔ ﻳﻤﻜـﻦ ﺍﻟﺘﻌﺒـﲑ ﻋـﻦ ﺍﻟﱰﻛﻴـﺰ ﺑﺎﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺃﻭ ﺑﺎﳌﻮﻻﺕ. 1-3اﻟﻌﻮاﻣﻞ اﻟﻤﺆﺛﺮة ﻓﻲ اﻟﺬوﺑﺎن اﻟﻔﻜﺮة اﻟﺮﺋﻴﺴﺔ ﻳﺘﺄﺛﺮ ﺗﻜـ ﹼﻮﻥ ﺍﳌﺤﻠﻮﻝ ﺑﻌﻮﺍﻣﻞ، ﻣﻨﻬﺎ ﺍﳊﺮﺍﺭﺓ ﻭﺍﻟﻀﻐﻂ ﻭﺍﻟﻘﻄﺒﻴﺔ. 1-4اﻟﺨﻮاص اﻟﺠﺎﻣﻌﺔ ﻟﻠﻤﺤﺎﻟﻴﻞ اﻟﻔﻜﺮة اﻟﺮﺋﻴﺴﺔ ﺗﻌﺘﻤـﺪ ﺍﳋـﻮﺍﺹ ﺍﳉﺎﻣﻌﺔ ﻋﲆ ﻋﺪﺩ ﺟﺴﻴﲈﺕ ﺍﳌﺬﺍﺏ ﰲ ﺍﳌﺤﻠﻮﻝ. ﺣﻘﺎﺋﻖ ﻛﻴﻤﻴﺎﺋﻴﺔ ﺣﻮﺍﱄ 42.3%ﻣﻦ ﺍﻟﻔﻮﻻﺫ ﺍﳌﻨﺘﺞ ﺳـﻨﻮ ﹰﹼﻳﺎ ﻳﺄﰐ • ﻣﻦ ﺇﻋﺎﺩﺓ ﺍﻟﺘﺪﻭﻳﺮ. • ﺍﳊﺪﻳﺪ ﻫﻮ ﺍﳌﻜﻮﻥ ﺍﻷﺳـﺎﳼ ﻟﻠﻔﻮﻻﺫ ،ﻟﻜﻦ ﻳﻤﻜﻦ • ﺇﺿﺎﻓـﺔ ﻋﻨﺎﴏ ﻣﺜـﻞ ﺍﻟﻨﻴـﻜﻞ ﻭﺍﳌﻨﺠﻨﻴـﺰ ﻭﺍﻟﻜﺮﻭﻡ • ﻭﺍﻟﻔﻨﺎﺩﻳـﻮﻡ ﻭﺍﻟﺘﻨﺠﺴـﺘﻮﻥ ﺣﺴـﺐ ﺍﳌﻮﺍﺻﻔـﺎﺕ ﺍﳌﻄﻠﻮﺑﺔ. ﻳﺴـﺘﻌﻤﻞ ﺍﻷﺳـﻤـﻨـﺖ ﰲ ﺻـﻨﺎﻋـﺔ ﺍﳋـﻠﻄـﺎﺕ ﺍﻷﺳـﻤﻨﺘﻴﺔ ﻭﻣﻮﺍﺩ ﺍﻟﺒﻨﺎﺀ ﻟﺘﻘﻮﻳﺘﻬﺎ ،ﻭﺟﻌﻠﻬﺎ ﺗﺘﺤﻤﻞ ﺍﻟﻌﻮﺍﻣﻞ ﺍﻟﺒﻴﺌﻴﺔ ﺍﻟﻌﺎﺩﻳﺔ. ﻳﻨﺘـﺞ ﻧﺤـﻮ 6ﺑﻼﻳـﲔ ﻣﱰ ﻣﻜﻌـﺐ ﻣـﻦ ﺍﳋﻠﻄﺎﺕ ﺍﻷﺳـﻤﻨﺘﻴﺔ ﺳـﻨﻮ ﹼﹰﻳﺎ .ﺃﻱ ﻣﺎ ﻳﻌـﺎﺩﻝ 1ﻣﱰ ﻣﻜﻌﺐ ) (1m3ﻟﻜﻞ ﺷﺨﺺ ﺳﻨﻮ ﹼﹰﻳﺎ. 6
ﺍﻋﻤـﻞ ﺍﳌﻄﻮﻳـﺔ ﺍﻵﺗﻴﺔ ﻟﺘﺴـﺎﻋﺪﻙ ﻋﲆ ﺗﻨﻈﻴﻢ ﺍﳌﻌﻠﻮﻣـﺎﺕ ﺣـﻮﻝ ﺗﺮﻛﻴـﺰ ﺗﺘﻐﲑ ﺍﻟﻄﺎﻗﺔ ﻋﻨﺪ ﺗﻜﻮﻳﻦ ﺍﳌﺤﻠﻮﻝ ﻧﺘﻴﺠﺔ ﺗﺄﺛﲑ ﻗﻮﺗﲔ :ﻗﻮﺓ ﺍﳉﺬﺏ ﺑﲔ ﺍﳉﺰﻳﺌﻴﺔ ﺑﲔ ﺟﺴﻴﲈﺕ ﻛﻞ ﻣﺎﺩﺓ ﰲ ﺍﳌﺤﻠﻮﻝ ،ﻭﻗﻮﺓ ﺍﻟﺘﺠﺎﺫﺏ ﺑﲔ ﺍﳌﺤﺎﻟﻴﻞ. 1ﺍﻃﻮ ﻭﺭﻗﺘﲔ ﺟﺴﻴﲈﺕﺍﳌﺬﺍﺏﻭﺍﳌﺬﻳﺐﻣ ﹰﻌﺎ.ﻓﻜﻴﻒﻳﻤﻜﻦﻣﻼﺣﻈﺔﻫﺬﺍﺍﻟﺘﻐﲑ؟ ﻣﻦ ﺍﳌﻨﺘﺼﻒ ﺃﻓﻘ ﹰﹼﻴﺎ. 2ﺍﻗﻄﻊ 3 cm ﻋـﲆ ﻃـﻮﻝ ﺧـﻂ ﺍﻟﺜﻨﻲ ﻹﺣـﺪ ﺍﻟﻮﺭﻗﺘـﲔ ﻣﻦ ﻛﻼ ﺍﳉﺎﻧﺒـﲔ .ﻭﻗـﺺA B C D ﺍﻟﻮﺭﻗﺔ ﺍﻟﺜﺎﻧﻴﺔ ﻋﲆ ﻃﻮﻝ B I BDC JCEADKDFBE L EGCFM FHDGN GIEHO JﰲKGﺍIﳌﺨPIﺘJFﱪH. OL O MP PN ACﺧـHﻂ AﺍBﻟﺜﻨGـﻲAﺃﻳFﹰﻀـﺎ E KN.1NPﺍOﻗMﺮﺃ ﺗJMﻌLNﻠﻴﲈILﺕKMﺍﻟﺴLHKﻼJﻣﺔ ﻣـﻦ ﻭﺳـﻄﻬﺎ ﻣـﻊ ﺗﺮﻙ 3cmﻣﻦ ﻛﻼ .2ﺯﻥ 10 gﻣـﻦ ﻛﻠﻮﺭﻳـﺪ ﺍﻷﻣﻮﻧﻴـﻮﻡ ،NH4Clﺛـﻢ ﺿﻌﻬـﺎ ﰲ ﺍﳉﺎﻧﺒﲔ ﺩﻭﻥ ﻗﺺ. ﻛﺄﺱ ﺳﻌﺘﻬﺎ .100 ml 3ﺃﺩﺧـﻞ .3ﻗـﺲ 30 mlﻣـﻦ ﺍﳌـﺎﺀ ﺑﻤﺨﺒـﺎﺭ ﻣـﺪﺭﺝ ﺳـﻌﺘﻪ ،50 mlﺛﻢ ﺍﻟﻮﺭﻗﺘـﲔ ﺇﺣﺪﺍﳘـﺎ ﺃﺿـﻒ ﺍﳌﺎﺀ ﺇﱃ NH4Clﰲ ﺍﻟﻜﺄﺱ ،ﻭﺣﺮﻙ ﺍﳌﺤﻠﻮﻝ ﺑﺴـﺎﻕ ﰲ ﺍﻷﺧـﺮ ﻟﻌﻤـﻞ ﺍﻟﺘﺤﺮﻳﻚ. ﻛﺘﺎﺏ ﻣﻦ ﺃﺭﺑﻊ ﺻﻔﺤﺎﺕ. .4ﲢﺴﺲ ﺃﺳﻔﻞ ﺍﻟﻜﺄﺱ ﻣﻦ ﺍﳋﺎﺭﺝ ،ﻭﺳﺠﻞ ﻣﻼﺣﻈﺎﺗﻚ.اﻟﻤﻄﻮﻳﺎت 1-2 .5ﻛﺮﺭ ﺍﳋﻄﻮﺍﺕ ﻣﻦ 2-4ﻣﺴﺘﻌﻤ ﹰﻼ ﻛﻠﻮﺭﻳﺪ ﺍﻟﻜﺎﻟﺴﻴﻮﻡ CaCl2 ﺑﺪ ﹰﻻ ﻣﻦ .NH4Clﰲ ﺃﺛﻨﺎﺀ ﻗﺮﺍﺀﺗﻚ ﳍﺬﺍ ﺍﻟﻘﺴﻢ .ﺍﺳﺘﻌﻤﻞ ﺍﳌﻄﻮﻳﺔ ﻟﺘﺴﺠﻴﻞ .6ﲣﻠﺺ ﻣﻦ ﺍﳌﺤﺎﻟﻴﻞ ﺑﺴﻜﺒﻬﺎ ﰲ ﺍﳌﻐﺴﻠﺔ.ﺍﻟﺘﻌﺒﲑ7ﻋ3ـ67ﻦ43ﺗ76ﺮ84ﻛﻴ7ـ8-ﺰAﺍ1-ﳌ0Aﺤﺎ1ﻟ-ﻴ40ﻞC1C4،-1 ﻣـﺎ ﺗﻌﻠﻤﺘﻪ ﻋـﻦ ﻃﺮﺍﺋـﻖ ﻣﺴﺘﻌﻴ ﹰﻨﺎ ﺑﺄﻣﺜﻠﺔ ﺣﺴﺎﺑﻴﺔ. .1ﺃﻱ ﺍﻟﻌﻤﻠﻴﺘﲔ ﺍﻟﺴـﺎﺑﻘﺘﲔ ﻛﺎﻧﺖ ﻃـﺎﺭﺩﺓ ﻟﻠﻄﺎﻗﺔ ،ﻭﺃﳞﲈ ﳌﺮﺍﺟﻌﺔ ﳏﺘﻮ ﻫﺬﺍ ﺍﻟﻔﺼﻞ ﻭﻧﺸـﺎﻃﺎﺗﻪ ﺍﺭﺟﻊ ﺇﱃ ﻛﺎﻧﺖ ﻣﺎﺻﺔ ﳍﺎ؟ ﺍﳌﻮﻗﻊ: .2ﺍﻛﺘﺐ ﺃﻣﺜﻠﺔ ﻣﻦ ﻭﺍﻗـﻊ ﺣﻴﺎﺗﻚ ﻋﲆ ﻋﻤﻠﻴﺎﺕ ﺫﻭﺑﺎﻥ www.obeikaneducation.com ﻃﺎﺭﺩﺓ ﻟﻠﻄﺎﻗﺔ ،ﻭﺃﺧﺮ ﻣﺎﺻﺔ ﳍﺎ؟ ﺇﺫﺍ ﺃﺭﺩﺕ ﺯﻳﺎﺩﺓ ﺍﻟﺘﻐـﲑ ﰲ ﺩﺭﺟﺔ ﺍﳊﺮﺍﺭﺓ ،ﻓﺄﳞﲈ ﳚﺐﺇﺿﺎﻓﺘﻪ ﺑﻜﻤﻴﺔ ﺃﻛﱪ :ﺍﳌﺬﺍﺏ ﺃﻡ ﺍﳌﺬﻳﺐ ؟ ﻓﴪ ﺇﺟﺎﺑﺘﻚ7 .
1-1Types of Mixturesأﻧﻮاع اﻟﻤﺨﺎﻟﻴﻂ ا ﻫﺪاف اﻟﻔﻜﺮة اﻟﺮﺋﻴﺴﺔ ﺑﲔ ﺧﺼﺎﺋﺺ ﺍﳌﺨﺎﻟﻴﻂ ﺇﺫﺍ ﻣﻸﺕ ﺩﻟ ﹰﻮﺍ ﺑﲈﺀ ﺍﻟﺒﺤﺮ ﻓﺴﻮﻑ ﺗﻼﺣﻆ ﺃﻥ ﺑﻌﺾ ﺍﳌﻮﺍﺩ ﺗﱰﺳﺐ ﰲ ﻗﺎﻉ ﺍﳌﻌﻠﻘﺔ ﻭﺍﳌﺨﺎﻟﻴﻂ ﺍﻟﻐﺮﻭﻳﺔ ﻭﺍﳌﺤﺎﻟﻴﻞ. ﺍﻟﺪﻟﻮ ،ﻭﻳﻈﻞ ﺍﳌﺎﺀ ﻣﺎ ﹰﳊﺎ ﹶﻣ ﹾﻬﲈ ﻣﺮ ﻣﻦ ﺍﻟﻮﻗﺖ .ﳌﺎﺫﺍ ﺗﱰﺳﺐ ﺑﻌﺾ ﺍﳌﻮﺍﺩ ﺩﻭﻥ ﻏﲑﻫﺎ؟ ﺃﻧﻮﺍﻉ ﺍﳌﺨﺎﻟﻴﻂ ﺍﻟﻐﺮﻭﻳﺔ ﻭﺃﻧﻮﺍﻉ ﺍﳌﺤﺎﻟﻴﻞ. ﺍﻟﻘﻮ ﺍﻟﻜﻬﺮﺳﻜﻮﻧﻴﺔ اﻟﻤﺨﺎﻟﻴﻂ ﻏﻴﺮ اﻟﻤﺘﺠﺎﻧﺴﺔ Heterogeneous Mixturesﻻ ﺑﺪ ﺃﻧﻚ ﺗﺘﺬﻛﺮ ﺃﻥ ﺍﳌﺨﻠﻮﻁ ﻣﺰﻳﺞ ﻣﻦ ﻣﺎﺩﺗﲔ ﻧﻘﻴﺘﲔ ﺃﻭ ﺃﻛﺜﺮ ،ﲢﺘﻔﻆ ﻓﻴﻪ ﻛﻞ ﻣﺎﺩﺓ ﺑﺨﺼﺎﺋﺼﻬﺎ ﰲ ﺍﳌﺨﺎﻟﻴﻂ ﺍﻟﻐﺮﻭﻳﺔ.ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ ،ﻭﺃﻥ ﺍﳌﺨﺎﻟﻴﻂ ﻏﲑ ﺍﳌﺘﺠﺎﻧﺴﺔ ﻻ ﲤﺘﺰﺝ ﻣﻜﻮﻧﺎﲥﺎ ﲤﺎﻣ ﹰﺎ ﻣ ﹰﻌﺎ؛ ﺃﻱ ﻳﻤﻜﻦ ﲤﻴﻴﺰ ﻛﻞ ﻣﻨﻬﺎ. ﻣﺮاﺟﻌﺔ اﻟﻤﻔﺮدات ﻣﺎﺩﺓ ﺗﺬﻭﺏ ﰲ ﺍﳌﺤﻠﻮﻝ .ﻭﻫﻨﺎﻙ ﻧﻮﻋﺎﻥ ﻣﻦ ﺍﳌﺨﺎﻟﻴﻂ ﻏﲑ ﺍﳌﺘﺠﺎﻧﺴﺔ ،ﳘﺎ ﺍﳌﻌﻠﻖ ﻭﺍﻟﻐﺮﻭﻱ. ﳐﻠﻮﻁ ﳛـﺘﻮﻱ ﻋﲆ ﺟـﺴـﻴﲈﺕ ﻳﻤﻜﻦ ﺃﻥ ﺗﱰﺳـﺐ -ﺑﺎﻟﱰﻭﻳـﻖ -ﺇﺫﺍ ﹸﺗﺮﻙ ﻓﱰﺓ ﺩﻭﻥ اﻟﻤﻔﺮدات اﻟﺠﺪﻳﺪة ﺍﳌﺨﻠﻮﻁ ﺍﳌﻌﻠﻖﲢﺮﻳـﻚ .ﺍﻧﻈــﺮ ﺍﻟﺸـﻜﻞ 1-1؛ ﻓﺎﻟﻮﺣﻞ ﺍﻟﺬﻱ ﺗﺸـﺎﻫﺪﻩ ﳐﻠﻮﻁ ﻣﻌﻠﻖ .ﻭﻋﻨـﺪ ﲤﺮﻳﺮ ﺍﳌﺨﻠﻮﻁﺍﳌﻌﻠﻖ ﺍﻟﺴـﺎﺋﻞ ﺧﻼﻝ ﻭﺭﻗﺔ ﺗﺮﺷـﻴﺢ ﹸﺗﻔﺼﻞ ﺍﳉﺴـﻴﲈﺕ ﺍﳌﻌﻠﻘﺔ .ﻭﻗﺪ ﺗﻨﻔﺼﻞ ﺑﻌﺾ ﺍﳌﺨﺎﻟﻴﻂ ﺍﳌﺨﻠﻮﻁ ﺍﻟﻐﺮﻭﻱﺍﳌﻌﻠﻘـﺔ ﺇﱃ ﻃﺒﻘﺘـﲔ ﻭﺍﺿﺤﺘـﲔ ﺇﺫﺍ ﺗﺮﻛﺖ ﻓﱰﺓ ﺩﻭﻥ ﲢﺮﻳﻚ؛ ﺍﳌﺎﺩﺓ ﺍﻟﺼﻠﺒﺔ ﰲ ﺍﻟﻘﺎﻉ ﻭﺍﻟﺴـﺎﺋﻞ ﺍﳊﺮﻛﺔ ﺍﻟﱪﺍﻭﻧﻴﺔﻓﻮﻗﻬﺎ ،ﻭﻟﻜﻦ ﻋﻨﺪ ﲢﺮﻳﻚ ﺍﳌﺨﻠﻮﻁ ﺍﳌﻌﻠﻖ ﴎﻋﺎﻥ ﻣﺎ ﺗﺒﺪﺃ ﺍﳌﺎﺩﺓ ﺍﻟﺼﻠﺒﺔ ﰲ ﺍﻻﻧﺴـﻴﺎﺏ ،ﻭﻛﺄﳖﺎﺳـﺎﺋﻞ .ﻭﺗﺴـﻤﻰ ﺍﳌﺎﺩﺓ ﺍﻟﺘﻲ ﺗﺴﻠﻚ ﻫﺬﺍ ﺍﻟﺴـﻠﻮﻙ ﺍﳌﺎﺩ ﹶﺓ ﺍﻟﺘﻲ ﺗﺘﻤﻴﻊ ﺑﺎﳍﺰ ﺃﻭ ﺍﻟﺘﺤﺮﻳﻚ .ﻭﻫﻨﺎﻙ ﺗﺄﺛﲑ ﺗﻨﺪﺍﻝﺃﻧـﻮﺍﻉ ﻣـﻦ ﺍﻟﻄـﲔ ﺗﺘﻤﻴﻊ ﺟﺴـﻴﲈﲥﺎ ﺑﴪﻋﺔ؛ ﺍﺳـﺘﺠﺎﺑﺔ ﻟﻠﻬـﺰ ﺃﻭ ﺍﳊﺮﻛﺔ؛ ﺗﺴـﺘﺨﺪﻡ ﰲ ﻣﻨﺎﻃﻖ ﺍﳌﺎﺩﺓ ﻏﲑ ﺍﻟﺬﺍﺋﺒﺔﺍﻟﺰﻻﺯﻝ ﺍﻷﺭﺿﻴﺔ ،ﻓﺘﺸ ﱠﻴﺪ ﺍﳌﺒﺎﲏ ﻓﻮﻗﻬﺎ. ﺍﳌﺎﺩﺓ ﺍﻟﺬﺍﺋﺒﺔ 1-1 8
11 ﺻﻠﺐ ﺻﻠﺐ ﺍﻷﺣﺠﺎﺭ ﺍﻟﻜﺮﻳﻤﺔ ﺍﳌﻠﻮﻧﺔ ﺳﺎﺋﻞ ﺻﻠﺐ ﺻﻠﺐ ﺳﺎﺋﻞ ﺍﻟﺪﻡ ،ﺍﳉﻴﻼﺗﲔ ﺳﺎﺋﻞ ﺳﺎﺋﻞ ﺍﻟﺰﺑﺪ ،ﺍﳉﺒﻦ ﺻﻠﺐ ﻏﺎﺯ ﻏﺎﺯ ﺻﻠﺐ ﺍﳊﻠﻴﺐ ،ﺍﳌﺎﻳﻮﻧﻴﺰ ﺍﻟﺼﺎﺑﻮﻥ ﺍﻟﺬﻱ ﻳﻄﻔﻮ ،ﺣﻠﻮ ﺍﳋﻄﻤﻲ ﻏﺎﺯ ﺍﻟﺪﺧﺎﻥ ،ﺍﻟﻐﺒﺎﺭ ﰲ ﺍﳍﻮﺍﺀ ﺍﻟﻐﻴﻮﻡ ،ﺍﻟﻀﺒﺎﺏ ،ﺭﺫﺍﺫ ﻣﺰﻳﻞ ﺍﻟﻌﺮﻕ ﺳﺎﺋﻞ 1-2 ﻷﻥ ﺣﺠﻮﻡ ﺟﺴـﻴﲈﺕ ﺍﳌﺨﻠـﻮﻁ ﺍﳌﻌﻠﻖ ﺃﻛـﱪ ﻣﻦ ﺣﺠﻮﻡ ﺍﻟـﺬﺭﺍﺕ ﻓﺈﳖﺎ ﻳﻤﻜﻦ ﺃﻥ ﺗﱰﺳـﺐ ﰲ ﺍﳌﺨﻠﻮﻁ .ﻭﻳﺴـﻤﻰ ﺍﳌﺨﻠـﻮﻁ ﻏﲑ ﺍﳌﺘﺠﺎﻧﺲ ﺍﻟﺬﻱ ﻳﺘﻜﻮﻥ ﻣﻦ ﺟﺴـﻴﲈﺕ ﻣﺘﻮﺳـﻄﺔ ﺍﳊﺠﻢ ﺍﳌﺨﻠﻮﻁ ﺍﻟﻐـﺮﻭﻱ.ﻭ ﺗﱰﺍﻭﺡ ﺃﻗﻄﺎﺭ ﺍﳉﺴـﻴﲈﺕ ﰲ ﺍﳌﺨﻠـﻮﻁ ﺍﻟﻐﺮﻭﻱ ﺑـﲔ 1 nmﻭ ،1000 nmﻭﻻ ﺗﱰﺳـﺐ .ﻓﻌﲆ ﺳـﺒﻴﻞ ﺍﳌﺜـﺎﻝ ،ﻳﻌـﺪ ﺍﳊﻠﻴـﺐ ﳐﻠﻮ ﹰﻃﺎ ﻏﺮﻭ ﹰﹼﻳـﺎ ﻻ ﻳﻤﻜﻦ ﻓﺼـﻞ ﻣﻜﻮﻧﺎﺗﻪ ﺍﳌﺘﺠﺎﻧﺴـﺔ ﺑﺎﻟﱰﻭﻳﻖ ﺃﻭ ﺍﻟﱰﺷﻴﺢ. ﺗﺴـﻤﻰ ﺍﳌﺎﺩﺓ ﺍﻷﻛﺜﺮ ﺗﻮﺍﻓـﹰﺮﺍ ﰲ ﺍﳌﺨﻠﻮﻁ ﺍﳌﺬﻳﺐ .ﻭﺗﺼﻨـﻒ ﺍﳌﺨﺎﻟﻴﻂ ﺍﻟﻐﺮﻭﻳﺔ ﺗﺒ ﹰﻌﺎ ﻟﻠﺤﺎﻟـﺔ ﺍﻟﻔﻴﺰﻳﺎﺋﻴﺔ ﻟـﻜﻞ ﻣﻦ ﺍﳌﺬﻳﺐ ﻭﺍﳌـﺬﺍﺏ .ﻓﺎﳊﻠﻴﺐ ﻣﺴـﺘﺤﻠﺐ ﻏﺮﻭﻱ؛ ﻷﻥ ﺟﺴﻴﲈﺕ ﺍﳌﺬﺍﺏ ﺍﻟﺴﺎﺋﻞ ﺗﻨﺘﴩ ﺑﲔ ﺟﺴﻴﲈﺕ ﺍﳌﺬﻳﺐ ﺍﻟﺴﺎﺋﻞ .ﻭﻳﻈﻬﺮ ﺍﳉﺪﻭﻝ 1-1 ﻭﺻﻒ ﺃﻧﻮﺍﻉ ﺃﺧﺮ ﻣﻦ ﺍﳌﺨﺎﻟﻴﻂ ﺍﻟﻐﺮﻭﻳﺔ. ﹸﲤﻨﻊ ﺟﺴﻴﲈﺕ ﺍﳌﺬﺍﺏ ﻣﻦ ﺍﻟﱰﺳﺐ ﰲ ﺍﳌﺨﺎﻟﻴﻂ ﺍﻟﻐﺮﻭﻳﺔ؛ ﻭﺫﻟﻚ ﻟﻮﺟﻮﺩ ﳎﻤﻮﻋﺎﺕ ﺫﺭﻳﺔ ﺃﻭ ﻗﻄﺒﻴﺔ ﻣﺸـﺤﻮﻧﺔ ﻋﲆ ﺳـﻄﺤﻬﺎ ،ﺗﻘﻮﻡ ﺑﺠﺬﺏ ﺍﳌﻨﺎﻃﻖ ﺍﳌﻮﺟﺒﺔ ﺃﻭ ﺍﻟﺴـﺎﻟﺒﺔ ﳉﺴﻴﲈﺕ ﺍﳌﺬﻳﺐ ،ﳑﺎ ﻳﻨﺘـﺞ ﻋﻨﻪ ﺗﻜـﻮﻥ ﻃﺒﻘـﺎﺕ ﻛﻬﺮﺳـﻜﻮﻧﻴﺔ ﺣـﻮﻝ ﺍﳉﺴﻴﲈﺕ، ﻛـﲈ ﻫـﻮ ﻣﻮﺿـﺢ ﰲ ﺍﻟﺸـﻜﻞ ،1-2ﳑﺎ ﳚﻌـﻞ ﺍﻟﻄﺒﻘﺎﺕ ﺗﺘﻨﺎﻓـﺮ ﺑﻌﻀﻬﺎ ﻣﻊ ﺑﻌﺾ ﻋﻨﺪﻣـﺎ ﺗﺼﻄﺪﻡ ﺟﺴـﻴﲈﺕ ﺍﳌﺬﺍﺏ ﻣ ﹰﻌﺎ ،ﻟﺬﺍ ﺗﺒﻘﻰ ﺍﳉﺴـﻴﲈﺕ ﰲ ﺍﳌﺨﻠﻮﻁ ﺍﻟﻐﺮﻭﻱ ﻭﻻ ﺗﱰﺳﺐ. ﻭﺇﺫﺍ ﺗﺪﺧﻠﻨﺎ ﰲ ﺍﻟﻄﺒﻘﺎﺕ ﺍﻟﻜﻬﺮﺳـﻜﻮﻧﻴﺔ ﻓﺴـﻮﻑ ﺗﱰﺳـﺐ ﺟﺴـﻴﲈﺕ ﺍﳌﺬﺍﺏ ﻣﻦ ﺍﳌﺨﻠﻮﻁ ﺍﻟﻐﺮﻭﻱ .ﻓﻌﻨﺪ ﲢﺮﻳﻚ ﻣﺎﺩﺓ ﻛﻬﺮﻟﻴﺔ )ﺇﻟﻜﱰﻭﻟﻴﺖ( ﰲ ﳐﻠﻮﻁ ﻏﺮﻭﻱ ﻣﺜ ﹰﻼ ﺗﺘﺠﻤﻊ ﺟﺴـﻴﲈﺕ ﺍﳌﺬﺍﺏ ﻣ ﹰﻌﺎ ،ﻭﺗﺘﻠﻒ ﺍﳌﺨﻠﻮﻁ ﺍﻟﻐﺮﻭﻱ .ﻛﲈ ﺃﻥ ﺍﻟﺘﺴـﺨﲔ ﺃﻳ ﹰﻀﺎ ﻳﺘﻠـﻒ ﺍﳌﺨﻠﻮﻁ ﺍﻟﻐـﺮﻭﻱ؛ ﻷﻥ ﺍﳊﺮﺍﺭﺓ ﺗﻌﻄﻲ ﺍﳉﺴـﻴﲈﺕ ﺍﳌﺘﺼﺎﺩﻣﺔ ﻃﺎﻗﺔ ﺣﺮﻛﻴﺔ ﻛﺎﻓﻴﺔ ﻟﻠﺘﻐﻠﺐ ﻋﲆ ﺍﻟﻘﻮ ﺍﻟﻜﻬﺮﺳﻜﻮﻧﻴﺔ ،ﺛﻢ ﺗﺮﺳﺒﻬﺎ ﰲ ﺍﳌﺨﻠﻮﻁ.9
ﺗﺘﺤـﺮﻙ ﺟﺴـﻴﲈﺕ ﺍﳌـﺬﺍﺏ ﰲ ﺍﳌﺨﺎﻟﻴـﻂ ﺍﻟﻐﺮﻭﻳﺔ ﺍﻟﺴـﺎﺋﻠﺔ 1-3 ﺣﺮﻛﺔ ﻋﺸﻮﺍﺋﻴﺔ ﻭﻋﻨﻴﻔﺔ ﺗﺴﻤﻰ ﺍﳊﺮﻛﺔ ﺍﻟﱪﺍﻭﻧﻴﺔ .ﻻﺣﻆ ﻋﺎﱂ ﺍﻟﻨﺒﺎﺕ ﺍﻷﺳﻜﺘﻠﻨﺪﻱ ﺭﻭﺑـﺮﺕ ﺑـﺮﻭﺍﻥ ) (1773 – 1858ﻫـﺬﻩ ﺍﳊﺮﻛﺔ ﺃﻭﻝ ﻣﺮﺓ ،ﺣﻴـﺚ ﻻﺣﻆ ﺍﳊﺮﻛﺔ ﺍﻟﻌﺸﻮﺍﺋﻴﺔ ﳊﺒﻮﺏ ﺍﻟﻠﻘﺎﺡ ﺍﳌﺘﻨﺎﺛﺮﺓ ﰲ ﺍﳌﺎﺀ ،ﻓﺴ ﱢﻤﻴﺖ ﺑﺎﺳﻤﻪ. ﺗﻨﺘﺞ ﺍﳊﺮﻛﺔ ﺍﻟﱪﺍﻭﻧﻴﺔ ﻋﻦ ﺗﺼﺎﺩﻡ ﺟﺴـﻴﲈﺕ ﺍﳌﺬﻳﺐ ﻣﻊ ﺟﺴﻴﲈﺕ ﺍﳌﺬﺍﺏ؛ ﺑﺤﻴﺚ ﲤﻨﻊ ﻫﺬﻩ ﺍﻟﺘﺼﺎﺩﻣﺎﺕ ﺟﺴﻴﲈﺕ ﺍﳌﺬﺍﺏ ﻣﻦ ﺍﻟﱰﺳﺐ ﰲ ﺍﳌﺨﻠﻮﻁ. ﺳﺒﺒﲔ ﻟﻌﺪﻡ ﺗﺮﺳﺐ ﺟﺴﻴﲈﺕ ﺍﳌﺨﻠﻮﻁ ﺍﻟﻐﺮﻭﻱ. ﻳﻈﻬﺮ ﺍﳌﺨﻠﻮﻁ ﺍﻟﻐﺮﻭﻱ ﺍﳌﺮﻛﺰ ﻋﺎﺩ ﹰﺓ ﻣﻌﺘـﹰﲈ ﺃﻭ ﻣﻌﻜ ﹰﺮﺍ ،ﻭﻟﻜﻦ ﺍﳌﺨﻠﻮﻁﺍﻟﻐـﺮﻭﻱ ﺍﳌﺨﻔﻒ ﻳﻈﻬـﺮ ﺃﺣﻴﺎ ﹰﻧﺎ ﺻﺎﻓ ﹰﻴﺎ ﻛﺎﳌﺤﺎﻟﻴـﻞ .ﻭﺗﺒﺪﻭ ﺍﳌﺨﺎﻟﻴـﻂ ﺍﻟﻐﺮﻭﻳﺔ ﺍﳌﺨﻔﻔﺔﻛﺎﳌﺤﺎﻟﻴـﻞ ﺍﳌﺘﺠﺎﻧﺴـﺔ؛ ﻷﻥ ﺟﺴـﻴﲈﺕ ﺍﳌـﺬﺍﺏ ﻓﻴﻬﺎ ﺻﻐـﲑﺓ ﺟﺪﹼﹰﺍ ،ﺇﻻ ﺃﳖـﺎ ﺗﻌﻤﻞ ﻋﲆ ﺗﺸﺘﻴﺖ ﺍﻟﻀﻮﺀ ،ﻭﺗﺴﻤﻰ ﻫﺬﻩ ﺍﻟﻈﺎﻫﺮﺓ ﺗﺄﺛﲑ ﺗﻨﺪﺍﻝ.ﻳﻈﻬﺮ ﺍﻟﺸـﻜﻞ 1-3ﻣﺮﻭﺭ ﺣﺰﻣﺔ ﻣﻦ ﺍﻟﻀﻮﺀ ﻣـﻦ ﺧﻼﻝ ﳐﻠﻮﻃﲔ ﳎﻬﻮﻟﲔ .ﻭﻳﻤﻜﻨﻚﻣﻼﺣﻈﺔ ﻛﻴﻒ ﺗﻌﻤﻞ ﺟﺴـﻴﲈﺕ ﺍﳌﺬﺍﺏ ﰲ ﺍﳌﺨﻠﻮﻁ ﺍﻟﻐﺮﻭﻱ ﻋﲆ ﺗﺸﺘﻴﺖ ﺍﻟﻀﻮﺀ ،ﻋﲆﺧـﻼﻑ ﺟﺴـﻴﲈﺕ ﺍﳌﺤﻠﻮﻝ .ﻭ ﹸﺗﻈﻬﺮ ﺍﳌﺨﺎﻟﻴـﻂ ﺍﳌﻌﻠﻘﺔ ﺃﻳ ﹰﻀﺎ ﺗﺄﺛﲑ ﺗﻨـﺪﺍﻝ ،ﺃﻣﺎ ﺍﳌﺤﺎﻟﻴﻞﻓـﻼ ﻳﻤﻜـﻦ ﺃﻥ ﺗﻈﻬﺮ ﻫـﺬﻩ ﺍﻟﻈﺎﻫﺮﺓ .ﻛﲈ ﻳﻤﻜﻨـﻚ ﻣﻼﺣﻈﺔ ﺗﺄﺛﲑ ﺗﻨﺪﺍﻝ ﻋﻨﺪﻣﺎ ﺗﺸـﺎﻫﺪﻣﺮﻭﺭ ﺃﺷـﻌﺔ ﺍﻟﺸـﻤﺲ ﺧﻼﻝ ﺍﳍﻮﺍﺀ ﺍﳌﺸـﺒﻊ ﺑﺎﻟﺪﺧﺎﻥ ،ﺃﻭ ﻣﺮﻭﺭ ﺿﻮﺀ ﺧﻼﻝ ﺍﻟﻀﺒﺎﺏ. ﻭﻳﺴﺘﺨﺪﻡ ﺗﺄﺛﲑ ﺗﻨﺪﺍﻝ ﰲ ﲢﺪﻳﺪ ﻛﻤﻴﺔ ﺍﳌﺬﺍﺏ ﰲ ﺍﳌﺨﻠﻮﻁ ﺍﳌﻌﻠﻖ.اﻟﻤﺨﺎﻟﻴﻂ اﻟﻤﺘﺠﺎﻧﺴﺔ Homogeneous Mixturesﺗﻈﻬﺮ ﺑﻌﺾ ﺍﳌﺤﺎﻟﻴﻞ -ﻭﻣﻨﻬﺎ ﺍﳍﻮﺍﺀ ﺍﳉﻮﻱ ﻭﻣﺎﺀ ﺍﳌﺤﻴﻂ ﻭﺍﻟﻔﻮﻻﺫ -ﻏﲑ ﻣﺘﺸـﺎﲠﺔ،ﺇ ﹼﻻ ﺃﳖـﺎ ﲨﻴ ﹰﻌﺎ ﺗﺸـﱰﻙ ﰲ ﺧﺼﺎﺋـﺺ ﻣﻌﻴﻨﺔ .ﻟﻘﺪ ﺗﻌﻠﻤﺖ ﺳـﺎﺑ ﹰﻘﺎ ﺃﻥ ﺍﳌﺤﺎﻟﻴﻞ ﳐﺎﻟﻴﻂﻣﺘﺠﺎﻧﺴـﺔ ﲢﺘﻮﻱ ﻋﲆ ﻣﺎﺩﺗﲔ ﺃﻭ ﺃﻛﺜﺮ ،ﺗﺴـﻤﻰ ﺍﳌﺬﺍﺏ ﻭﺍﳌﺬﻳﺐ .ﻭﺍﳌﺬﺍﺏ ﻫﻮ ﺍﳌﺎﺩﺓﺍﻟﺘﻲ ﺗﺬﻭﺏ .ﺃﻣﺎ ﺍﳌﺬﻳﺐ ﻓﻬﻮ ﺍﻟﻮﺳـﻂ ﺍﻟﺬﻱ ﻳﺬﻳﺐ ﺍﳌﺬﺍﺏ .ﻭﻻ ﻳﻤﻜﻨﻚ ﺍﻟﺘﻤﻴﻴﺰ ﺑﲔ ﺍﳌﺬﺍﺏ ﻭﺍﳌﺬﻳﺐ ﻋﻨﺪ ﺍﻟﻨﻈﺮ ﺇﱃ ﺍﳌﺤﻠﻮﻝ. ﻗﺪ ﻳﻮﺟﺪ ﺍﳌﺤﻠﻮﻝ ﰲ ﺻﻮﺭﺓ ﻏﺎﺯ ﺃﻭ ﺳﺎﺋﻞ ﺃﻭ ﺻﻠﺐ ،ﺍﻋﺘﲈ ﹰﺩﺍ ﻋﲆﺍﳊﺎﻟـﺔ ﺍﻟﻔﻴﺰﻳﺎﺋﻴﺔ ﻟﻠﻤﺬﻳﺐ ،ﻛـﲈ ﻫﻮ ﻣﻮﺿﺢ ﰲ ﺍﳉﺪﻭﻝ .1-2ﺍﳍﻮﺍﺀ ﳏﻠﻮﻝ ﻏﺎﺯﻱﻭﺍﳌﺬﻳﺐ ﻓﻴﻪ ﻫﻮ ﻏﺎﺯ ﺍﻟﻨﻴﱰﻭﺟﲔ .ﻭﻗﺪ ﺗﻜﻮﻥ ﺃﺳﻼﻙ ﺗﻘﻮﻳﻢ ﺍﻷﺳﻨﺎﻥ ﺍﻟﺘﻲ ﺗﻀﻌﻬﺎﻋﲆ ﺃﺳـﻨﺎﻧﻚ ﻣﺼﻨﻮﻋﺔ ﻣـﻦ ﺍﻟﻨﻴﺘﻴﻨﻮﻝ ،ﻭﻫـﻮ ﳏﻠﻮﻝ ﺻﻠﺐ ﻳﺘﻜﻮﻥ ﻣـﻦ ﺍﻟﺘﻴﺘﺎﻧﻴﻮﻡﺍﳌﺬﺍﺏ ﰲ ﺍﻟﻨﻴﻜﻞ .ﺇﻻ ﺃﻥ ﻣﻌﻈﻢ ﺍﳌﺤﺎﻟﻴﻞ ﺗﻜﻮﻥ ﰲ ﺍﳊﺎﻟﺔ ﺍﻟﺴﺎﺋﻠﺔ .ﻟﻘﺪ ﺗﻌﻠﻤﺖ ﺃﻥﺍﻟﺘﻔﺎﻋـﻼﺕ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﺔ ﲢﺪﺙ ﰲ ﺍﳌﺤﺎﻟﻴﻞ ﺍﳌﺎﺋﻴﺔ ،ﻭﻫـﻲ ﺍﳌﺤﺎﻟﻴﻞ ﺍﻟﺘﻲ ﻳﻜﻮﻥ ﻓﻴﻬﺎﺍﳌﺎﺀ ﻣﺬﻳ ﹰﺒﺎ .ﻓﺎﳌﺎﺀ ﺃﻛﺜﺮ ﺍﳌﺬﻳﺒﺎﺕ ﺷـﻴﻮ ﹰﻋﺎ ﰲ ﺍﳌﺤﺎﻟﻴﻞ ﺍﻟﺴـﺎﺋﻠﺔ .ﻭﻗﺪ ﺗﻮﺟﺪ ﺍﳌﺤﺎﻟﻴﻞﰲ ﺃﺷﻜﺎﻝ ﳐﺘﻠﻔﺔ ،ﻭﻗﺪ ﺗﻜﻮﻥ ﺍﳌﻮﺍﺩ ﺍﻟﺬﺍﺋﺒﺔ ﰲ ﺍﳌﺤﺎﻟﻴﻞ ﻏﺎﺯﻳﺔ ﺃﻭ ﺳﺎﺋﻠﺔ ﺃﻭ ﺻﻠﺒﺔ. 10
ﻣﺨﺘﺒﺮ ﺗﺤﻠﻴﻞ اﻟﺒﻴﺎﻧﺎت .1ﺣـ ﹼﺪﺩ ﺍﳌﺘﻐـﲑﺍﺕ ﺍﻟﺘـﻲ ﻳﻤﻜـﻦ ﺃﻥ ﺗﺴـﺘﺨﺪﻡ ﻟﻠﺮﺑـﻂ ﺗﺼﻤﻴﻢ ﺗﺠﺮﺑﺔ ﺑﲔ ﻗـﺪﺭﺓ ﺍﻟﻀـﻮﺀ ﻋﲆ ﺍﳌـﺮﻭﺭ ﺧﻼﻝ ﺍﻟﺴـﺎﺋﻞ ﻭﻋﺪﺩ ﺗﻀﻊ ﺍﻟﻠﻮﺍﺋﺢ ﺍﻟﻮﻃﻨﻴﺔ ﳌﻴﺎﻩ ﺍﻟﴩﺏ ﳎﻤﻮﻋـﺔ ﻣﻦ ﺍﳌﻌﺎﻳﲑ ﻭﺍﳌﻮﺍﺻﻔﺎﺕ ﻟﻀﲈﻥ ﺳـﻼﻣﺘﻬﺎ .ﻭﻣﻦ ﺍﳉﺴﻴﲈﺕ ﰲ ﺍﳌﺨﻠﻮﻁ ﺍﻟﻐﺮﻭﻱ. ﺍﳌﻮﺍﺻﻔﺎﺕ ﺍﻟﺘﻲ ﻳﺘﻢ ﻣﺮﺍﻗﺒﺘﻬﺎ ﺍﻟﺘﻌﻜﺮ ﻭﻫﻮ ﻣﻘﻴﺎﺱ ﻟﺪﺭﺟﺔ ﺍﻟﻀﺒﺎﺑﻴﺔ ﰲ ﺍﳌﺎﺀ ،ﻭﺍﻟﻨﺎﲡﺔ ﻋﻦ ﺍﳌﻮﺍﺩ ﺍﻟﺼﻠﺒﺔ ﺍﳌﻌﻠﻘﺔ ﺍﳌﻮﺟﻮﺩﺓ ﰲ .2ﺍﺭﺑـﻂ ﺑـﲔ ﺍﳌﺘﻐـﲑﺍﺕ ﺍﻟﺘـﻲ ﺍﺳـﺘﺨﺪﻣﺘﻬﺎ ﰲ ﺍﻟﺘﺠﺮﺑﺔ ﺍﳌﺎﺀ ،ﻭﺍﻟﺘﻲ ﻏﺎﻟ ﹰﺒﺎ ﻣﺎ ﺗﻜﻮﻥ ﻣﺮﺗﺒﻄﺔ ﻣﻊ ﺍﻟﺘﻠﻮﺙ ﻭﻣﻊ ﺍﻟﻔﲑﻭﺳﺎﺕ ﻭﺍﻟﻌﺪﺩ ﺍﳊﻘﻴﻘﻲ ﻟﻠﺠﺴﻴﲈﺕ ﰲ ﺍﳌﺨﻠﻮﻁ ﺍﻟﻐﺮﻭﻱ. ﻭﺍﻟﻄﻔﻴﻠﻴﺎﺕ ﻭﺍﻟﺒﻜﺘﲑﻳﺎ .ﺗﺄﰐ ﻣﻌﻈﻢ ﻫﺬﻩ ﺍﳉﺴﻴﲈﺕ ﺍﻟﻐﺮﻭﻳﺔ ﻣﻦ ﺍﻟﺘﻌﺮﻳﺔ ،ﻭﺍﻟﻨﺸﺎﻁ ﺍﻟﺼﻨﺎﻋﻲ ،ﻭﻓﻀﻼﺕ ﺍﻹﻧﺴﺎﻥ ،ﻭﻧﻤﻮ .3ﺣﻠﻞ ﻣﺎ ﺍﺣﺘﻴﺎﻃﺎﺕ ﺍﻟﺴﻼﻣﺔ ﺍﻟﺘﻲ ﳚﺐ ﺍﲣﺎﺫﻫﺎ؟ ﺍﻟﻄﺤﺎﻟﺐ ،ﻭﻣﻦ ﺍﻷﺳﻤﺪﺓ ،ﻭﲢﻠﻞ ﺍﳌﻮﺍﺩ ﺍﻟﻌﻀﻮﻳﺔ. .4ﺣ ﹼﺪﺩ ﺍﳌﻮﺍﺩ ﺍﻟﻼﺯﻣﺔ ﻟﻘﻴـﺎﺱ ﺗﺄﺛﲑ ﺗﻨﺪﺍﻝ .ﻭﺍﺧﱰ ﺗﻘﻨﻴﺔ ﳉﻤﻊ ﺃﻭ ﺗﻔﺴﲑ ﺍﻟﺒﻴﺎﻧﺎﺕ. ﻳﺴﺘﺨﺪﻡ ﺗﺄﺛﲑ ﺗﻨﺪﺍﻝ ﰲ ﻗﻴﺎﺱ ﺗﻌﻜﺮ ﺍﳌﺎﺀ .ﻭﺍﳍﺪﻑ ﺗﺼﻤﻴﻢ ﲡﺮﺑﺔ ﻭﺗﻄﻮﻳﺮ ﻣﻘﻴﺎﺱ ﻟﺘﻔﺴﲑ ﺍﻟﺒﻴﺎﻧﺎﺕ. ﺗﺴﻤﻰ ﺍﳌﺎﺩﺓ ﺍﻟﺘﻲ ﺗﺬﻭﺏ ﰲ ﺍﳌﺬﻳﺐ ﺍﳌﺎﺩﺓ ﺍﻟﺬﺍﺋﺒﺔ .ﻓﻤﺜ ﹰﻼ ﺫﻭﺑﺎﻥ ﺍﻟﺴﻜﺮ ﰲ ﺍﳌﺎﺀ ﺣﻘﻴﻘﺔ ﻳﻤﻜﻦ ﺃﻥ ﺗﻜﻮﻥ ﻗﺪ ﺗﻌﻠﻤﺘﻬﺎ ﻣﻦ ﺧﻼﻝ ﺇﺫﺍﺑﺔ ﺍﻟﺴﻜﺮ ﰲ ﺍﳌﺎﺀ ﻟﻌﻤﻞ ﴍﺍﺏ ﳏ ﹰﹼﲆ ﻛﺎﻟﺸﺎﻱ ﺃﻭ ﻋﺼﲑ ﺍﻟﻠﻴﻤﻮﻥ .ﻭﺗﺴـﻤﻰ ﺍﳌﺎﺩﺗﺎﻥ ﺍﻟﺴـﺎﺋﻠﺘﺎﻥ ﺍﻟﻠﺘﺎﻥ ﺗﺬﻭﺏ ﺇﺣﺪﺍﳘﺎ ﰲ ﺍﻷﺧﺮ ﺑﺄﻱ ﻧﺴﺒ ﹴﺔ ﺍﳌﻮﺍ ﱠﺩ ﺍﻟﻘﺎﺑﻠﺔ ﻟﻼﻣﺘﺰﺍﺝ ،ﻭﻣﻨﻬﺎ ﻣﺎﻧﻊ ﺍﻟﺘﺠﻤﺪ ﺍﳌﺬﻛﻮﺭ ﰲ ﺍﳉﺪﻭﻝ .1-2ﻭ ﹸﺗﺴـﻤﻰ ﺍﳌﺎﺩﺓ ﺍﻟﺘﻲ ﻻ ﺗﺬﻭﺏ ﰲ ﺍﳌﺬﻳﺐ ﻣﺎﺩﺓ ﻏﲑ ﺫﺍﺋﺒﺔ ،ﻓﺎﻟﺮﻣﻞ ﻣﺜ ﹰﻼ ﻻﻳﺬﻭﺏ ﰲ ﺍﳌﺎﺀ .ﻭﺗﺴﻤﻰ ﺍﻟﺴﻮﺍﺋﻞ ﺍﻟﺘﻲ ﲤﺘﺰﺝ ﻣ ﹰﻌﺎ ﻓﱰﺓ ﻗﺼﲑﺓ ﻋﻨﺪ ﺧﻠﻄﻬﺎ ،ﻭﺗﻨﻔﺼﻞ ﺑﻌﺪﻫﺎ ﺍﻟﺴﻮﺍﺋ ﹶﻞ ﻏﲑ ﺍﳌﻤﺘﺰﺟﺔ .ﻓﺎﻟﺰﻳﺖ ﻣﺜ ﹰﻼ ﻻﻳﻤﺘﺰﺝ ﻣﻊ ﺍﳋﻞ؛ ﺃﻱ ﺃ ﹼﻥ ﺍﻟﺰﻳﺖ ﻻﻳﺬﻭﺏ ﰲ ﺍﳋﻞ. 12 ﺍﻷﻛﺴﺠﲔ )ﻏﺎﺯ( ﺍﻟﻨﻴﱰﻭﺟﲔ )ﻏﺎﺯ( ﺍﳍﻮﺍﺀ ﺛﺎﲏ ﺃﻛﺴﻴﺪ ﺍﻟﻜﺮﺑﻮﻥ )ﻏﺎﺯ( ﺍﳌﺎﺀ )ﺳﺎﺋﻞ( ﻣﺎﺀ ﻏﺎﺯﻱ ﺍﻷﻛﺴﺠﲔ )ﻏﺎﺯ( ﺍﳌﺎﺀ )ﺳﺎﺋﻞ( ﻣﺎﺀ ﺍﻟﺒﺤﺮ ﺍﻹﺛﻴﻠﲔ ﺟﻼﻳﻜﻮﻝ )ﺳﺎﺋﻞ( ﻣﺎﺩﺓ ﳐﻔﻀﺔ ﻟﺪﺭﺟﺔ ﺍﻟﺘﺠﻤﺪ ﺍﳌﺎﺀ )ﺳﺎﺋﻞ( ﲪﺾ ﺍﻹﻳﺜﺎﻧﻮﻳﻚ )ﺳﺎﺋﻞ( ﺍﳌﺎﺀ )ﺳﺎﺋﻞ( ﺍﳋﻞ ﻛﻠﻮﺭﻳﺪ ﺍﻟﺼﻮﺩﻳﻮﻡ )ﺻﻠﺐ( ﺍﳌﺎﺀ )ﺳﺎﺋﻞ( ﻣﺎﺀ ﺍﻟﺒﺤﺮ ﺍﻟﺰﺋﺒﻖ )ﺻﻠﺐ( ﺍﻟﻔﻀﺔ )ﺻﻠﺐ( ﳑﻠﻐﻢ ﺍﻷﺳﻨﺎﻥ ﺍﻟﻜﺮﺑﻮﻥ )ﺻﻠﺐ( ﺍﳊﺪﻳﺪ )ﺻﻠﺐ( ﺍﻟﻔﻮﻻﺫ11
اﻟﺘﻘﻮﻳﻢ 1-1 اﻟﺨﻼﺻﺔ .1اﻟﻔﻜﺮة اﻟﺮﺋﻴﺴﺔ ﻓﴪ ﺍﺳﺘﻌﲈﻝ ﺧﺼﺎﺋﺺ ﻣﺎﺀ ﺍﻟﺒﺤﺮ ﻟﻮﺻﻒ ﺧﺼﺎﺋﺺ ﻳﻤﻜـﻦ ﲤﻴﻴـﺰ ﻣﻜﻮﻧـﺎﺕ ﺍﳌﺨﻠـﻮﻁ ﻏـﲑ ﺍﳌﺨﺎﻟﻴﻂ. ﺍﳌﺘﺠﺎﻧﺲ. .2ﻓﺮﻕ ﺑﲔ ﺍﳌﺨﻠﻮﻁ ﺍﻟﻐﺮﻭﻱ ﻭﺍﳌﺨﻠﻮﻁ ﺍﳌﻌﻠﻖ. ﻫﻨﺎﻙ ﻧﻮﻋﺎﻥ ﻣﻦ ﺍﳌﺨﺎﻟﻴﻂ ﻏﲑ ﺍﳌﺘﺠﺎﻧﺴﺔ، ﳘﺎ ﺍﳌﻌﻠﻖ ﻭﺍﻟﻐﺮﻭﻱ. .3ﺣ ﹼﺪﺩ ﺍﻷﻧﻮﺍﻉ ﺍﳌﺨﺘﻠﻔﺔ ﻟﻠﻤﺤﺎﻟﻴﻞ ،ﻭﺻﻒ ﺍﳋﺼﺎﺋﺺ ﺍﳌﻤﻴﺰﺓ ﻟﻜﻞ ﻣﻨﻬﺎ. ﺍﳊﺮﻛـﺔ ﺍﻟﱪﺍﻭﻧﻴـﺔ ﺣﺮﻛـﺔ ﻋﺸـﻮﺍﺋﻴﺔ .4ﻓﴪ ﻣﺴﺘﺨﺪ ﹰﻣﺎ ﺗﺄﺛﲑ ﺗﻨﺪﺍﻝ ،ﳌﺎﺫﺍ ﺗﻜﻮﻥ ﺍﻟﻘﻴﺎﺩﺓ ﺧﻼﻝ ﺃﺟﻮﺍﺀ ﺍﻟﻀﺒﺎﺏ ﳉﺴﻴﲈﺕ ﺍﳌﺨﻠﻮﻁ ﺍﻟﻐﺮﻭﻱ.ﺑﺎﺳﺘﺨﺪﺍﻡ ﺍﻷﻧﻮﺍﺭ ﺍﻟﻌﺎﻟﻴﺔ ﺃﻛﺜﺮ ﺻﻌﻮﺑﺔ ﻣﻦ ﺍﻟﻘﻴﺎﺩﺓ ﺑﺎﺳﺘﺨﺪﺍﻡ ﺍﻷﻧﻮﺍﺭ ﹸﺗﻈﻬﺮ ﺍﳌﺨﺎﻟﻴﻂ ﺍﻟﻐﺮﻭﻳﺔ ﺗﺄﺛﲑ ﺗﻨﺪﺍﻝ. ﺍﳌﻨﺨﻔﻀﺔ؟ .5ﺻﻒ ﺍﻷﻧﻮﺍﻉ ﺍﳌﺨﺘﻠﻔﺔ ﻟﻠﻤﺨﺎﻟﻴﻂ ﺍﻟﻐﺮﻭﻳﺔ. ﻗـﺪ ﻳﻮﺟـﺪ ﺍﳌﺤﻠﻮﻝ ﰲ ﺇﺣـﺪ ﺍﳊﺎﻻﺕ ﺍﻟﻔﻴﺰﻳﺎﺋﻴـﺔ ﺍﻟﺜـﻼﺙ :ﺍﻟﺴـﺎﺋﻠﺔ ﺃﻭ ﺍﻟﻐﺎﺯﻳـﺔ .6ﻓﴪ ﳌﺎﺫﺍ ﺗﺒﻘﻰ ﺟﺴﻴﲈﺕ ﺍﳌﺬﺍﺏ ﰲ ﺍﳌﺨﻠﻮﻁ ﺍﻟﻐﺮﻭﻱ ﻣﻨﺘﴩﺓ؟ ﺃﻭ ﺍﻟﺼﻠﺒـﺔ ،ﺍﻋﺘـﲈ ﹰﺩﺍ ﻋﲆ ﺍﳊﺎﻟـﺔ ﺍﻟﻔﻴﺰﻳﺎﺋﻴﺔ .7ﳋﺺ ﻣﺎ ﺍﻟﺬﻱ ﻳﺴﺒﺐ ﺍﳊﺮﻛﺔ ﺍﻟﱪﺍﻭﻧﻴﺔ؟ ﻟﻠﻤﺬﻳﺐ. .8ﻗﺎﺭﻥ ﻛ ﱢﻮﻥ ﺟﺪﻭ ﹰﻻ ﺗﻠﺨﺺ ﻓﻴﻪ ﺧﺼﺎﺋﺺ ﺍﳌﺨﻠﻮﻁ ﺍﳌﻌﻠﻖ ﻭﺍﳌﺨﻠﻮﻁ ﻳﻤﻜﻦ ﺃﻥ ﻳﻜﻮﻥ ﺍﳌﺬﺍﺏ ﰲ ﺍﳌﺤﻠﻮﻝ ﻏﺎ ﹰﺯﺍ ﺍﻟﻐﺮﻭﻱ ﻭﺍﳌﺤﻠﻮﻝ. ﺃﻭ ﺳﺎﺋ ﹰﻼ ﺃﻭ ﺻﻠ ﹰﺒﺎ. 12
1-2ﺗﺮﻛﻴﺰ اﻟﻤﺤﺎﻟﻴﻞ Concentration of Solutions ا ﻫﺪاف اﻟﻔﻜﺮة اﻟﺮﺋﻴﺴﺔ ﺍﻟﱰﻛﻴـﺰ ﺑﺎﺳـﺘﻌﲈﻝ ﻫﻞ ﺗﺬﻭﻗﺖ ﻳﻮ ﹰﻣﺎ ﻛﺄﺱ ﺷﺎﻱ ﻓﻮﺟﺪﺗﻪ ﻗﻮﻱ ﺍﳌﺬﺍﻕ ﺃﻭ ﻣﺮ ﺍﻟﻄﻌﻢ؟ ﻟﺘﻌﺪﻳﻞ ﺍﻟﻄﻌﻢ ﻭﺣﺪﺍﺕ ﳐﺘﻠﻔﺔ.ﻓﺈﻧـﻚ ﺗﻘﻮﻡ ﺑﺈﺿﺎﻓﺔ ﺍﻟﺴـﻜﺮ ﻟﺘﺤﻠﻴﺘﻪ ﺃﻭ ﺑﺈﺿﺎﻓﺔ ﺍﳌﺎﺀ ﻟﺘﺨﻔﻴﻔﻪ .ﻭﻣـﺎ ﺗﻘﻮﻡ ﺑﻪ ﰲ ﻛﻠﺘﺎ ﺍﳊﺎﻟﺘﲔ ﻫﻮ ﺗﻐﻴﲑ ﺗﺮﻛﻴﺰ ﺍﳌﺤﺎﻟﻴﻞ. ﻣﻮﻻﺭﻳﺔ ﺍﳌﺤﻠﻮﻝ .ﺗﺮﻛﻴﺰ ﺍﳉﺴﻴﲈﺕ ﺍﳌﺬﺍﺑﺔ ﰲ ﺍﳌﺎﺀ. اﻟﺘﻌﺒﻴﺮ ﻋﻦ اﻟﺘﺮﻛﻴﺰ Expressing Concectration ﻣﺮاﺟﻌﺔ اﻟﻤﻔﺮدات ﺍﳌﺎﺩﺓ ﺍﻟﺘﻲ ﺗﺬﻳﺐ ﺍﳌﺬﺍﺏ ﻳﻌﺪ ﺗﺮﻛﻴﺰ ﺍﳌﺤﻠﻮﻝ ﻣﻘﻴﺎ ﹰﺳﺎ ﻳﻌﱪ ﻋﻦ ﻛﻤﻴﺔ ﺍﳌﺬﺍﺏ ﺍﻟﺬﺍﺋﺒﺔ ﰲ ﻛﻤﻴﺔ ﳏﺪﺩﺓ ﻣﻦ ﺍﳌﺬﻳﺐ ﺃﻭ ﺍﳌﺤﻠﻮﻝ .ﻭﻳﻤﻜـﻦ ﻟﺘﻜﻮﻳﻦ ﳏﻠﻮﻝ.ﺍﻟﺘﻌـﺒﲑ ﻋﻦ ﺍﻟﱰﻛﻴﺰ ﻭﺻﻔ ﹰﹼﻴﺎ ﺑﺎﺳﺘﻌﲈﻝ ﻛﻠﻤﺔ \"ﻣﺮ ﹼﻛﺰ\" ﺃﻭ \"ﳐ ﹼﻔﻒ\" .ﻻﺣﻆ ﺇﺑﺮﻳﻘﻲ ﺍﻟﺸﺎﻱ ﰲ ﺍﻟﺸﻜﻞ 1-4؛ﻓﺄﺣـﺪ ﺍﻹﺑﺮﻳﻘﲔ ﳛﺘﻮﻱ ﺷـﺎ ﹰﻳﺎ ﺃﻛﺜﺮ ﺗﺮﻛﻴﺰ ﹰﺍ ﻣﻦ ﺍﻵﺧﺮ .ﻭﻋﻤﻮ ﹰﻣـﺎ ﳛﺘﻮﻱ ﺍﳌﺤﻠﻮﻝ ﺍﳌﺮﻛﺰ ﻋﲆ ﻛﻤﻴﺔ ﻛﺒﲑﺓ اﻟﻤﻔﺮدات اﻟﺠﺪﻳﺪةﻣﻦ ﺍﳌﺬﺍﺏ .ﻓﺎﻟﺸـﺎﻱ ﺫﻭ ﺍﻟﻠﻮﻥ ﺍﻟﻐﺎﻣﻖ ﳛﺘﻮﻱ ﻋﲆ ﺟﺴـﻴﲈﺕ ﺷﺎﻱ ﺃﻛﺜﺮ ﻣﻦ ﺍﻟﺸﺎﻱ ﺫﻱ ﺍﻟﻠﻮﻥ ﺍﻟﻔﺎﺗﺢ ، ﺍﻟﱰﻛﻴﺰﻭﺍﻟﻌﻜﺲ ﺻﺤﻴﺢ؛ ﺇﺫ ﳛﺘﻮﻱ ﺍﳌﺤﻠﻮﻝ ﺍﳌﺨ ﹼﻔﻒ ﻋﲆ ﻛﻤﻴﺔ ﺃﻗﻞ ﻣﻦ ﺍﳌﺬﺍﺏ؛ ﻓﺎﻟﺸﺎﻱ ﺫﻭ ﺍﻟﻠﻮﻥ ﺍﻟﻔﺎﺗﺢ ﰲ ﺍﳌﻮﻻﺭﻳﺔ ﺍﻟﺸﻜﻞ 1-4ﳏﻠﻮﻝ ﳐﻔﻒ ﳛﺘﻮﻱ ﻋﲆ ﺟﺴﻴﲈﺕ ﺷﺎﻱ ﺃﻗﻞ ﻣﻦ ﺍﻟﺸﺎﻱ ﺫﻱ ﺍﻟﻠﻮﻥ ﺍﻟﻐﺎﻣﻖ.ﻭﻋﲆ ﺍﻟﺮﻏﻢ ﻣﻦ ﺃﻥ ﺍﻟﺘﻌﺒﲑ ﺍﻟﻮﺻﻔﻲ ﻋﻦ ﺍﻟﱰﻛﻴﺰ ﻣﻔﻴﺪ ،ﺇﻻ ﺃﻧﻪ ﻏﺎﻟ ﹰﺒﺎ ﻣﺎ ﻳﺘﻢ ﺍﻟﺘﻌﺒﲑ ﻋﻦ ﺍﻟﱰﻛﻴﺰ ﻛ ﹼﻤ ﹰﹼﻴﺎ. ﺍﳌﻮﻻﻟﻴﺔﻭﻣﻦ ﺃﻛﺜﺮ ﺍﻟﺘﻌﺎﺑﲑ ﺍﻟﻜﻤﻴﺔ ﻋﻦ ﺍﻟﱰﻛﻴﺰ ﺷﻴﻮ ﹰﻋﺎ ﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺑﺎﻟﻜﺘﻠﺔ ﺃﻭ ﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺑﺎﳊﺠﻢ ﺃﻭ ﺍﳌﻮﻻﺭﻳﺔ ﺍﻟﻜﴪ ﺍﳌﻮﱄﺃﻭ ﺍﳌﻮﻻﻟﻴـﺔ .ﻭﻛﻞ ﻫـﺬﻩ ﺍﻟﻄﺮﺍﺋﻖ ﺗﻌﱪ ﻋﻦ ﺍﻟﱰﻛﻴﺰ ﺑﻮﺻﻔﻪ ﻧﺴـﺒﺔ ﺑﲔ ﻛﻤﻴﺔ ﺍﳌـﺬﺍﺏ ﻭﻛﻤﻴﺔ ﺍﳌﺬﻳﺐ ﺃﻭ 1-4 ﺍﳌﺤﻠﻮﻝ ﻛﻜﻞ .ﻭﳛﺘﻮﻱ ﺍﳉﺪﻭﻝ 1-3ﻭﺻ ﹰﻔﺎ ﻟﻜﻞ ﻃﺮﻳﻘﺔ. ﺃﻱ ﺍﻟﺘﻌﺎﺑﲑ ﺍﻟﻜﻤﻴﺔ ﳚﺐ ﺍﺳﺘﻌﲈﻟﻪ ﻟﻠﺘﻌﺒﲑ ﻋﻦ ﺗﺮﻛﻴﺰ ﺍﳌﺤﻠﻮﻝ؟ ﻳﻌﺘﻤﺪ ﺍﺳﺘﻌﲈﻝ ﺍﻟﺘﻌﺒﲑ ﻋﲆ ﻧﻮﻉ ﺍﳌﺤﻠﻮﻝﺍﻟـﺬﻱ ﻳﺘﻢ ﲢﻠﻴﻠﻪ ،ﻓﺈﺫﺍ ﻛﺎﻥ ﺃﺣﺪ ﺍﻟﻜﻴﻤﻴﺎﺋﻴﲔ ﻣﺜ ﹰﻼ ﻳﻌﻤﻞ ﻋﲆ ﺗﻔﺎﻋﻞ ﰲ ﳏﻠﻮﻝ ﻣﺎﺋﻲ ﻓﺴـﻮﻑ ﻳﺴـﺘﻌﻤﻞ ﻏﺎﻟ ﹰﺒﺎ ﺍﳌﻮﻻﺭﻳﺔ ﻟﻠﺘﻌﺒﲑ ﻋﻦ ﺗﺮﻛﻴﺰ ﺍﳌﺤﻠﻮﻝ؛ ﻷﻧﻪ ﳛﺘﺎﺝ ﺇﱃ ﻣﻌﺮﻓﺔ ﻋﺪﺩ ﺍﳉﺴﻴﲈﺕ ﺍﳌﺸﺎﺭﻛﺔ ﰲ ﺍﻟﺘﻔﺎﻋﻞ. 13 100 × ﻛﺘﻠﺔ ﺍﳌﺬﺍﺏ_ ﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺑﺎﻟﻜﺘﻠﺔ ﻛﺘﻠﺔ ﺍﳌﺤﻠﻮﻝ ﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺑﺎﳊﺠﻢ 100 × ﺣﺠﻢ ﺍﳌﺬﺍﺏ_ ﺍﳌﻮﻻﺭﻳﺔ ﺣﺠﻢ ﺍﳌﺤﻠﻮﻝ ﺍﳌﻮﻻﻟﻴﺔ ﻋﺪﺩ ﻣﻮﻻ_ﺕ ﺍﳌﺬﺍﺏ_ ﺣﺠﻢ ﺍﳌﺤﻠﻮﻝ )ﺑﺎﻟﻠﱰ( ﻋﺪﺩ ﻣﻮﻻ_ﺕ ﺍﳌﺬﺍﺏ_ ﻛﺘﻠﺔ ﺍﳌﺬﻳﺐ kg ﻋ_ﺪﺩ ﻣﻮﻻﺕ ﺍﳌﺬﺍﺏ__ ﺍﻟﻜﴪ ﺍﳌﻮﱄ ﻋﺪﺩ ﻣﻮﻻﺕ ﺍﳌﺬﺍﺏ +ﻋﺪﺩ ﻣﻮﻻﺕ ﺍﳌﺬﻳﺐ13
ﻫﻲ ﻧﺴـﺒﺔ ﻛﺘﻠﺔ ﺍﳌﺬﺍﺏ ﺇﱃ ﻛﺘﻠـﺔ ﺍﳌﺤﻠﻮﻝ ،ﻭﻳﻌﱪ ﻋﻨﻬﺎ ﺑﻨﺴـﺒﺔ ﻣﺌﻮﻳﺔ. اﻟﻤﻄﻮﻳﺎت ﻭﻛﺘﻠﺔ ﺍﳌﺤﻠﻮﻝ ﻫﻲ ﳎﻤﻮﻉ ﻛﺘﻞ ﺍﳌﺬﺍﺏ ﻭﺍﳌﺬﻳﺐ. ﺃﺩﺧﻞ ﻣﻌﻠﻮﻣﺎﺕ ﻣﻦ ﻫﺬﺍ ﺍﻟﻘﺴﻢ ﰲ ﻣﻄﻮﻳﺘﻚ. ﻛﺘﻠﺔ ﺍﳌﺬﺍﺏ_ 100 × ﻛﺘﻠﺔ ﺍﳌﺤﻠﻮﻝ ﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺑﺎﻟﻜﺘﻠﺔ =ﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺑﺎﻟﻜﺘﻠﺔ ﺗﺴﺎﻭﻱ ﻛﺘﻠﺔ ﺍﳌﺬﺍﺏ ﻣﻘﺴﻮﻣﺔ ﻋﲆ ﻛﺘﻠﺔ ﺍﳌﺤﻠﻮﻝ ﺍﻟﻜﻠﻴﺔ ﻭﻣﴬﻭﺑﺔ ﰲ .100 11 ﻟﻠﻤﺤﺎﻓﻈﺔ ﻋﲆ ﺗﺮﻛﻴﺰ ﻛﻠﻮﺭﻳﺪ ﺍﻟﺼﻮﺩﻳﻮﻡ NaClﰲ ﺣﻮﺽ ﺍﻷﺳﲈﻙ ،ﻛﲈ ﻫﻮ ﰲ ﻣﺎﺀ ﺍﻟﺒﺤﺮ ،ﳚﺐﺃﻥ ﳛﺘﻮﻱ ﺣﻮﺽ ﺍﻷﺳﲈﻙ ﻋﲆ 3.6 g NaClﻟﻜﻞ 100 gﻣﺎﺀ .ﻣﺎ ﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺑﺎﻟﻜﺘﻠﺔ ﻟﻜﻠﻮﺭﻳﺪ ﺍﻟﺼﻮﺩﻳﻮﻡ NaClﰲ ﺍﳌﺤﻠﻮﻝ؟ 1ﺗﺤﻠﻴﻞ اﻟﻤﺴﺄﻟﺔﺇﻥ ﻛﺘﻠﺔ ﻛﻠﻮﺭﻳﺪ ﺍﻟﺼﻮﺩﻳﻮﻡ ﰲ 100 gﻣﺎﺀ ﻣﻌﺮﻭﻓﺔ .ﻭﺍﻟﻨﺴـﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺑﺎﻟﻜﺘﻠﺔ ﻫﻲ ﻧﺴـﺒﺔ ﻛﺘﻠﺔ ﺍﳌﺬﺍﺏ ﺇﱃ ﻛﺘﻠﺔ ﺍﳌﺤﻠﻮﻝ )ﺍﻟﺘﻲ ﻫﻲ ﳎﻤﻮﻉ ﻛﺘﻞ ﺍﳌﺬﺍﺏ ﻭﺍﳌﺬﻳﺐ ﻣ ﹰﻌﺎ(. ﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ = ؟ ﻛﺘﻠﺔ ﺍﳌﺬﺍﺏ = 3.6 g NaCl ﻛﺘﻠﺔ ﺍﳌﺬﻳﺐ = 100 g H2O 2ﺣﺴﺎب اﻟﻤﻄﻠﻮب ﺟﺪ ﻛﺘﻠﺔ ﺍﳌﺤﻠﻮﻝ ﻛﺘﻠﺔ ﺍﳌﺤﻠﻮﻝ = ﻛﺘﻠﺔ ﺍﳌﺬﻳﺐ +ﻛﺘﻠﺔ ﺍﳌﺬﺍﺏ3.6 g + 100.0 g = 103.6g 100.0g3.6g ﺍﺣﺴﺐ ﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺑﺎﻟﻜﺘﻠﺔ100 × ﻛﺘﻠﺔ ﺍﳌﺬﺍﺏ_ = ﺑﺎﻟﻜﺘﻠﺔ ﺍﳌﺌﻮﻳﺔ ﺍﻟﻨﺴﺒﺔ ﻛﺘﻠﺔ ﺍﳌﺤﻠﻮﻝ= _3.6 g ×100 = 3.5% 103.6g3.6g 3ﺗﻘﻮﻳﻢ ا ﺟﺎﺑﺔ 103.6 g ﺗﻜﻮﻥ ﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺑﺎﻟﻜﺘﻠﺔ ﻗﻠﻴﻠﺔ؛ ﻷﻥ ﻛﺘﻠﺔ ﻛﻠﻮﺭﻳﺪ ﺍﻟﺼﻮﺩﻳﻮﻡ ﺍﻟﺬﺍﺋﺒﺔ ﰲ 100 gﻣﺎﺀ ﻗﻠﻴﻠﺔ. .9ﻣﺎ ﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺑﺎﻟﻜﺘﻠﺔ ﳌﺤﻠﻮﻝ ﳛﺘﻮﻱ ﻋﲆ 20.0 gﻣﻦ ﻛﺮﺑﻮﻧﺎﺕ ﺍﻟﺼﻮﺩﻳﻮﻡ ﺍﳍﻴﺪﺭﻭﺟﻴﻨﻴﺔ NaHCO3ﻣﺬﺍﺑﺔ ﰲ 600.0 mlﻣﻦ ﺍﳌﺎﺀ H2O؟ .10ﺇﺫﺍ ﻛﺎﻧﺖ ﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺑﺎﻟﻜﺘﻠﺔ ﳍﻴﺒﻮﻛﻠﻮﺭﺍﺕ ﺍﻟﺼﻮﺩﻳﻮﻡ NaOClﰲ ﳏﻠﻮﻝ ﻣﺒﻴﺾ ﺍﳌﻼﺑﺲ ﻫﻲ ،3.62%ﻭﻛﺎﻥ ﻟﺪﻳﻚ 1500.0 gﻣﻦ ﺍﳌﺤﻠﻮﻝ ﻓﲈ ﻛﺘﻠﺔ NaOClﺍﳌﻮﺟﻮﺩﺓ ﰲ ﺍﳌﺤﻠﻮﻝ؟ .11ﻣﺎ ﻛﺘﻠﺔ ﺍﳌﺬﻳﺐ ﰲ ﺍﳌﺤﻠﻮﻝ ﺍﳌﺬﻛﻮﺭ ﰲ ﺍﻟﺴﺆﺍﻝ 10؟ .12ﲢ ﹼﺪ ﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﻟﻜﺘﻠﺔ ﻛﻠﻮﺭﻳﺪ ﺍﻟﻜﺎﻟﺴﻴﻮﻡ ﰲ ﳏﻠﻮﻝ ﻫﻲ ،2.62%ﻓﺈﺫﺍ ﻛﺎﻧﺖ ﻛﺘﻠﺔ ﻛﻠﻮﺭﻳﺪ ﺍﻟﻜﺎﻟﺴﻴﻮﻡ ﺍﳌﺬﺍﺑﺔ ﰲ ﺍﳌﺤﻠﻮﻝ 50.0 gﻓﲈ ﻛﺘﻠﺔ ﺍﳌﺤﻠﻮﻝ ؟ 14
ﺗﺼﻒ ﻋـﺎﺩﺓ ﺍﳌﺤﺎﻟﻴﻞ ﺍﻟﺘـﻲ ﻳﻜﻮﻥ ﻓﻴﻬﺎ ﺍﳌﺬﻳـﺐ ﻭﺍﳌﺬﺍﺏ ﰲ ﺍﳊﺎﻟﺔ ﺍﻟﺴـﺎﺋﻠﺔ .ﻭﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺑﺎﳊﺠﻢ ﻫﻲ ﺍﻟﻨﺴـﺒﺔ ﺑﲔ ﺣﺠﻢ ﺍﳌﺬﺍﺏ ﺇﱃ ﺣﺠﻢ ﺍﳌﺤﻠﻮﻝ، ﻭﻳﻌـﱪ ﻋﻨﻬﺎ ﺑﻨﺴـﺒﺔ ﻣﺌﻮﻳﺔ .ﻭﺣﺠﻢ ﺍﳌﺤﻠﻮﻝ ﻫﻮ ﳎﻤﻮﻉ ﺣﺠﻢ ﺍﳌـﺬﺍﺏ ﻭﺣﺠﻢ ﺍﳌﺬﻳﺐ .ﺇﻥ ﺣﺴﺎﺑﺎﺕ ﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺑﺎﳊﺠﻢ ﺗﺸﺒﻪ ﺣﺴﺎﺑﺎﺕ ﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺑﺎﻟﻜﺘﻠﺔ. ﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺑﺎﳊﺠﻢ = ﺣﺣﺠﺠﻢﻢﺍﺍﳌﳌﺤﺬﺍﻠﻮﺏﻝ_× 100 Biodiesel ﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺑﺎﳊﺠﻢ ﺗﺴﺎﻭﻱ ﺣﺠﻢ ﺍﳌﺬﺍﺏ ﻣﻘﺴﻮ ﹰﻣﺎ ﻋﲆ ﺣﺠﻢ ﺍﳌﺤﻠﻮﻝ ﻣﴬﻭ ﹰﺑﺎ ﰲ .100 1-5 ﻳﻌﺪ ﺍﻟﺪﻳﺰﻝ ﺍﳊﻴﻮﻱ ﺍﳌﻮﺿﺢ ﰲ ﺍﻟﺸـﻜﻞ 1-5ﻭﻗـﻮ ﹰﺩﺍ ﺑﺪﻳ ﹰﻼ ﻧﻈﻴﻒ ﺍﻻﺣﱰﺍﻕ ،ﻳﻨﺘﺞ ﻋﻦ ﻣﻮﺍﺭﺩ ﻣﺘﺠﺪﺩﺓ ،ﻭﻳﺴﺘﻌﻤﻞ ﰲ ﳏﺮﻛﺎﺕ ﺍﻟﺪﻳﺰﻝ ﻣﻊ ﺍﻟﻘﻠﻴﻞ ﻣﻦ ﺍﻟﺘﺤﺴﻴﻨﺎﺕ ﺃﻭ ﺩﻭﳖﺎ .ﻭﺍﻟﺪﻳﺰﻝ ﺍﳊﻴﻮﻱ ﺳـﻬﻞ ﺍﻻﺳـﺘﻌﲈﻝ ﻭﻗﺎﺑﻞ ﻟﻠﺘﺤﻠﻞ ﺍﳊﻴﻮﻱ ،ﻭﻏﲑ ﺳـﺎﻡ ،ﻭﻻ ﳛﺘﻮﻱ ﻋﲆ ﺍﻟﻜﱪﻳﺖ ﺃﻭ ﺍﳌﺮﻛﺒﺎﺕ ﺍﻷﺭﻭﻣﺎﺗﻴـﺔ )ﺍﻟﻌﻄﺮﻳـﺔ( ،ﻛـﲈ ﺃﻧﻪ ﻻ ﳛﺘﻮﻱ ﻋﲆ ﺍﻟﻨﻔـﻂ ،ﻭﻟﻜﻦ ﻳﻤﻜﻦ ﻣﺰﺟﻪ ﻣـﻊ ﺩﻳﺰﻝ \"ﺍﻟﻨﻔﻂ\" ﻟﺘﻜﻮﻳـﻦ ﺍﻟﺪﻳـﺰﻝ ﺍﳊﻴﻮﻱ ﺍﳌﻤـﺰﻭﺝ؛ ﺍﻟﺬﻱ ﻳﺘﻜﻮﻥ ﻣـﻦ 20 %ﺑﺎﳊﺠﻢ ﺩﻳـﺰﻝ ﺣﻴﻮﻱ ﻭ80 %15 ﺑﺎﳊﺠﻢ ﺩﻳﺰﻝ ﻣﻦ ﺍﻟﻨﻔﻂ. ﺑﲔ ﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺑﺎﻟﻜﺘﻠﺔ ﻭﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺑﺎﳊﺠﻢ. .13ﻣﺎ ﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺑﺎﳊﺠﻢ ﻟﻺﻳﺜﺎﻧﻮﻝ ﰲ ﳏﻠﻮﻝ ﳛﺘﻮﻱ ﻋﲆ 35 mlﺇﻳﺜﺎﻧﻮﻝ ﻣﺬﺍﺏ ﰲ 155 mlﻣﺎﺀ؟ .14ﻣﺎ ﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺑﺎﳊﺠﻢ ﻟﻜﺤﻮﻝ ﺃﻳﺰﻭﺑﺮﻭﺑﻴﻞ ،ﰲ ﳏﻠﻮﻝ ﳛﺘﻮﻱ ﻋﲆ 24 mlﻣﻦ ﻛﺤﻮﻝ ﺍﻷﻳﺰﻭﺑﺮﻭﺑﻴﻞ ﻣﺬﺍﺏ ﰲ 1.1 Lﻣﻦ ﺍﳌﺎﺀ؟ .15ﲢ ﱟﺪ ﺇﺫﺍ ﺍﺳﺘﻌﻤﻞ 18 mlﻣﻦ ﺍﳌﻴﺜﺎﻧﻮﻝ ﻟﻌﻤﻞ ﳏﻠﻮﻝ ﻣﺎﺋﻲ ﻣﻨﻪ ﺗﺮﻛﻴﺰﻩ 15%ﺑﺎﳊﺠﻢ، ﻓﲈ ﺣﺠﻢ ﺍﳌﺤﻠﻮﻝ ﺍﻟﻨﺎﺗﺞ ﺑﺎﳌﻠﻠﱰ؟ ﺇﻥ ﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺑﺎﻟﻜﺘﻠﺔ ﻭﺍﻟﻨﺴﺒﺔ ﺍﳌﺌﻮﻳﺔ ﺑﺎﳊﺠﻢ ﻃﺮﻳﻘﺘﺎﻥ ﻣﻦ ﻃﺮﺍﺋﻖ ﺍﻟﺘﻌﺒﲑ ﺍﻟﻜﻤﻲ ﻋﻦ ﺗﺮﻛﻴﺰ ﺍﳌﺤﻠﻮﻝ .ﻭﻣﻦ ﺃﻛﺜﺮ ﺍﻟﻮﺣﺪﺍﺕ ﺷﻴﻮ ﹰﻋﺎ ﺍﳌﻮﻻﺭﻳﺔ .Molarity ﻭﺍﳌﻮﻻﺭﻳﺔ ) (Mﻫﻲ ﻋﺪﺩ ﻣﻮﻻﺕ ﺍﳌﺬﺍﺏ ﺍﻟﺬﺍﺋﺒﺔ ﰲ ﻟﱰ ﻣﻦ ﺍﳌﺤﻠﻮﻝ ،ﻭﺗﻌﺮﻑ ﺃﻳ ﹰﻀﺎ ﺑﺎﻟﱰﻛﻴﺰ ﺍﳌﻮﻻﺭﻱ .ﻓﱰﻛﻴﺰ ﻟﱰ ﻣﻦ ﳏﻠﻮﻝ ﳛﺘﻮﻱ ﻋﲆ ﻣﻮﻝ ﻣﻦ ﺍﳌﺬﺍﺏ ﻫﻮ ،1.0 Mﻛﲈ ﺃﻥ ﺗﺮﻛﻴﺰ ﻟﱰ ﻣـﻦ ﺍﳌﺤﻠـﻮﻝ ﳛﺘﻮﻱ ﻋﲆ 0.1 molﻣﻦ ﺍﳌﺬﺍﺏ ﻫﻮ .0.1 Mﻭﳊﺴـﺎﺏ ﻣﻮﻻﺭﻳﺔ ﺍﳌﺤﻠﻮﻝ ﳚﺐ ﻣﻌﺮﻓﺔ ﺣﺠﻢ ﺍﳌﺤﻠﻮﻝ ﺑﺎﻟﻠﱰ ﻭﻋﺪﺩ ﻣﻮﻻﺕ ﺍﳌﺬﺍﺏ. ﻋﺪﺩ ﻣﻮﻻﺕ_ﺍﳌﺬﺍﺏ )_(mol ﺣﺠﻢ ﺍﳌﺤﻠﻮﻝ )(L = M ﺍﳌﻮﻻﺭﻳﺔ ﺍﳌﻮﻻﺭﻳﺔ ﻫﻲ ﻋﺪﺩ ﻣﻮﻻﺕ ﺍﳌﺬﺍﺏ ﻣﻘﺴﻮﻣﺔ ﻋﲆ ﺣﺠﻢ ﺍﳌﺤﻠﻮﻝ ﺑﺎﻟﻠﱰ. ﺍﻟﱰﻛﻴﺰ ﺍﳌـﻮﻻﺭﻱ ﳌﺤﻠـﻮﻝ ﺣﺠﻤـﻪ ،1.0 Lﳛﺘـﻮﻱ ﻋﲆ 0.5 molﻣﻦ ﺍﳌﺬﺍﺏ؟
12 ﻣﻬﻦ ﻓﻲ اﻟﻜﻴﻤﻴﺎء ﻣﻦ ﺳـﻜﺮ5.10 g ﻣﻦ ﳏﻠﻮﻝ ﺣﻘـﻦ ﺍﻟﻮﺭﻳﺪ ﻋﲆ100.5 ml ﳛﺘـﻮﻱ ﻣﺎ ﻣﻮﻻﺭﻳﺔ ﻫﺬﺍ ﺍﳌﺤﻠﻮﻝ ﺇﺫ ﻋﻠﻤﺖ ﺃﻥ ﺍﻟﻜﺘﻠﺔ ﺍﳌﻮﻟﻴﺔ ﻟﻠﺠﻠﻮﻛﻮﺯ ﻫﻲ.C6H12O6 ﺍﳉﻠﻮﻛﻮﺯ ؟180.16g/mol ﺗﺤﻠﻴﻞ اﻟﻤﺴﺄﻟﺔ1 ﻭﻣﻮﻻﺭﻳﺔ ﺍﳌﺤﻠﻮﻝ ﻫﻲ ﺍﻟﻨﺴـﺒﺔ ﺑﲔ،ﻟﻘـﺪ ﺃﻋﻄﻴﺖ ﻛﺘﻠﺔ ﺍﳉﻠﻮﻛﻮﺯ ﺍﻟﺬﺍﺋﺒﺔ ﰲ ﺣﺠﻢ ﻣﻦ ﺍﳌﺎﺀ .ﻋﺪﺩ ﻣﻮﻻﺕ ﺍﳌﺬﺍﺏ ﺇﱃ ﻛﻞ ﻟﱰ ﻣﻦ ﺍﳌﺤﻠﻮﻝ 16 M ﺗﺮﻛﻴﺰ ﺍﳌﺤﻠﻮﻝ = ؟ 5.10 g C6H12O6 = ﻛﺘﻠﺔ ﺍﳌﺬﺍﺏ 180.16 g/mol = C6H12O6 ﺍﻟﻜﺘﻠﺔ ﺍﳌﻮﻟﻴﺔ ﻟﻠﺠﻠﻮﻛﻮﺯ 100.5 ml = ﺣﺠﻢ ﺍﳌﺤﻠﻮﻝ ﺣﺴﺎب اﻟﻤﻄﻠﻮب2=5.10 g C6H12O6 (_1810m.1o6lgC_C6H6H121O2O6 6 ) C6H12O6 ﺍﺣﺴﺐ ﻋﺪﺩ ﻣﻮﻻﺕ C6H12O6= 0.0283 mol C6H12O6 =100.5 ml (_1_0_01_0L_m__l) = ﺇﱃ ﻭﺣﺪﺓ ﻟﱰH2O ﻭﺣﻮﻝ ﺣﺠﻢ 0.1005 L _ﻋﺪﺩ ﻣﻮﻻ_ﺕ ﺍﳌﺬﺍﺏ 0.0282 mol = (L) ﺣﺠﻢ ﺍﳌﺤﻠﻮﻝ =M 0.1005 LM = _0.0282 mo_l C6H12O6 = 0.282 M 1L ﺗﻘﻮﻳﻢ ا ﺟﺎﺑﺔ3.ﺳﺘﻜﻮﻥ ﻗﻴﻤﺔ ﺍﳌﻮﻻﺭﻳﺔ ﻗﻠﻴﻠﺔ؛ ﻷﻥ ﻛﺘﻠﺔ ﺍﳉﻠﻮﻛﻮﺯ ﺍﻟﺬﺍﺋﺒﺔ ﰲ ﺍﳌﺤﻠﻮﻝ ﻗﻠﻴﻠﺔ ﻣﻦ1.5 L ﰲC6H12O6 ﻣﻦ ﺍﳉﻠﻮﻛﻮﺯ40.0 g ﻣﺎ ﻣﻮﻻﺭﻳﺔ ﳏﻠﻮﻝ ﻣﺎﺋﻲ ﳛﺘﻮﻱ ﻋﲆ.16 ﺍﳌﺤﻠﻮﻝ؟ . 1.5 g KBr ﻭﻣﺬﺍﺏ ﻓﻴﻪ1.60 L ﺍﺣﺴﺐ ﻣﻮﻻﺭﻳﺔ ﳏﻠﻮﻝ ﺣﺠﻤﻪ.17 ﻟﻜﻞ ﻟﱰ ﻣﻦ ﺍﳌﺤﻠﻮﻝ؟9.5 g NaOCl ﻣﺎ ﻣﻮﻻﺭﻳﺔ ﳏﻠﻮﻝ ﻣﺒﻴﺾ ﻣﻼﺑﺲ ﳛﺘﻮﻱ ﻋﲆ.18 ﺍﻟﺘﻲ ﺗﻠﺰﻡ ﻟﺘﺤﻀﲑg ﺑﻮﺣﺪﺓCa(OH)2 ﻣﺎ ﻛﺘﻠﺔ ﻫﻴﺪﺭﻭﻛﺴﻴﺪ ﺍﻟﻜﺎﻟﺴﻴﻮﻡ .19 ؟0.25 M ﻭﺗﺮﻛﻴﺰﻩ1.5 L ﳏﻠﻮﻝ ﻣﺎﺋﻲ ﻣﻨﻬﺎ ﺣﺠﻤﻪ
3 2 1 1-6 375g 1.0L 1.5M ﻭﺑﻌﺪ ﺃﻥ ﻋﺮﻓﺖ ﻛﻴﻔﻴﺔ ﺣﺴﺎﺏ ﻣﻮﻻﺭﻳﺔ ﺍﳌﺤﻠﻮﻝ ﻛﻴﻒ ﻳﻤﻜﻨﻚ ﲢﻀﲑ ﳏﻠﻮﻝ ﻣﺎﺋﻲ ﺣﺠﻤﻪ 1 Lﻭﺗﺮﻛﻴﺰﻩ 1.50 Mﻣﻦ ﻛﱪﻳﺘﺎﺕ ﺍﻟﻨﺤﺎﺱ ﺍﳌﺎﺋﻴـﺔ CuSO4. 5H2O II؟ ﳛﺘﻮﻱ ﳏﻠﻮﻝ CuSO4.5H2O ﺍﻟـﺬﻱ ﺗﺮﻛﻴـﺰﻩ 1.5 Mﻋﲆ 1.5 mol CuSO4.5H2Oﻣﺬﺍﺑﺔ ﰲ 1 Lﻣﻦ ﺍﳌﺤﻠـﻮﻝ .ﻓﺈﺫﺍ ﻋﺮﻓﺖ ﺃﻥ ﺍﻟﻜﺘﻠﺔ ﺍﳌﻮﻟﻴﺔ ﻟﻠﻤﺮﻛﺐ CuSO4.5H2Oﻫﻲ ،249.70 gﻭﺃﻥ ﺍﳌﺤﻠﻮﻝ ﳛﺘﻮﻱ ﻋﲆ ،1.50 mol CuSO4.5H2Oﺃﻱ ،375 g ﻭﻫﻲ ﻛﺘﻠﺔ ﻳﻤﻜﻦ ﻗﻴﺎﺳﻬﺎ ﺑﺎﳌﻴﺰﺍﻥ. _1.50 mol Cu_SO4·5H2O × _249.7 g Cu_SO4·5H2O = _375 g CuS_O4·5H2O Lﻣﻦ ﺍﳌﺤﻠﻮﻝ 1Lﻣﻦ ﺍﳌﺤﻠﻮﻝ 1 mol CuSO4·5H2O ﻭﻟﻜﻦ ﻻ ﻳﻤﻜﻨﻚ ﺇﺿﺎﻓﺔ 375 g CuSO4.5H2Oﺇﱃ 1.0 Lﻣﻦ ﺍﳌﺎﺀ ﻟﻠﺤﺼﻮﻝ ﻋﲆ ﳏﻠﻮﻝ ﺗﺮﻛﻴﺰﻩ 1.5 Mﲠﺬﻩ ﺍﻟﺒﺴﺎﻃﺔ .ﻷﻧﻪ ﻣﺜﻞ ﺍﳌﻮﺍﺩ ﺍﻷﺧﺮ ،ﺗﻌﻤﻞ CuSO4.5H2Oﻋﲆ ﺯﻳﺎﺩﺓ ﺣﺠﻢ ﺍﳌﺤﻠﻮﻝ ﻋﻦ ﺍﳊﺠﻢ ﺍﳌﻄﻠﻮﺏ .ﻟﺬﻟﻚ ﳚﺐ ﺍﺳﺘﻌﲈﻝ ﻛﻤﻴﺔ ﻣﻦ ﺍﳌﺎﺀ ﺗﻘﻞ ﻋﻦ 1.0 Lﻟﻠﺤﺼﻮﻝ ﻋﲆ 1.0 Lﻣﻦ ﺍﳌﺤﻠﻮﻝ ،ﻛﲈ ﻫﻮ ﻣﻮﺿﺢ ﰲ ﺍﻟﺸﻜﻞ .1-6 ﺃﺣﻴﺎ ﹰﻧـﺎ ﻧﺠـﺮﻱ ﲡﺎﺭﺏ ﺗﺘﻄﻠﺐ ﺍﺳـﺘﻌﲈﻝ ﻛﻤﻴﺎﺕ ﺻﻐﲑﺓ ﻣﻦ ﺍﳌﺤﻠﻮﻝ .ﻓﻌﲆ ﺳـﺒﻴﻞ ﺍﳌﺜﺎﻝ ،ﻗـﺪ ﲢﺘﺎﺝ ﺇﱃ 100 ml ﻣﻦ 1.50 M CuSO4.5H2Oﻹﺟﺮﺍﺀ ﺇﺣﺪ ﺍﻟﺘﺠﺎﺭﺏ .ﺑﺎﻟﺮﺟﻮﻉ ﺇﱃ ﺗﻌﺮﻳﻒ ﺍﳌﻮﻻﺭﻳﺔ ،ﻭﻣﻦ ﺧﻼﻝ ﺍﳊﺴﺎﺑﺎﺕ ﺍﻟﺴﺎﺑﻘﺔ ﻧﺠﺪ ﺃ ﱠﻥ ﳏﻠﻮﻝ CuSO4.5H2Oﺍﻟﺬﻱ ﺗﺮﻛﻴﺰﻩ 1.50 Mﳛﺘﻮﻱ ﻋﲆ 1.5 mol CuSO4.5H2Oﻟﻜﻞ ﻟﱰ ﻣﻦ ﺍﳌﺤﻠﻮﻝ .ﻟﺬﻟﻚ ﳛﺘﻮﻱ 1 Lﻣﻦ ﺍﳌﺤﻠﻮﻝ ﻋﲆ 375 gﻣﻦ ﻛﱪﻳﺘﺎﺕ ﺍﻟﻨﺤﺎﺱ ﺍﳌﺎﺋﻴﺔ . CuSO4.5H2O ﻳﻤﻜﻦ ﺍﺳﺘﻌﲈﻝ ﻫﺬﻩ ﺍﻟﻌﻼﻗﺔ ﺑﻮﺻﻔﻬﺎ ﻣﻌﺎﻣﻞ ﲢﻮﻳﻞ ﳊﺴﺎﺏ ﻛﻤﻴﺔ ﺍﳌﺬﺍﺏ ﺍﻟﻼﺯﻣﺔ ﻟﺘﺠﺮﺑﺘﻚ. 100 ml × _1 L × _375 g CuS_O4·5H2O = 37.5 g CuSO4 · 5H2O 1000 ml 1L ﻟﺬﻟﻚ ﲢﺘﺎﺝ ﺇﱃ ﻗﻴﺎﺱ 37.5 g CuSO4.5H2Oﻟﻌﻤﻞ 100 mlﻣﻦ ﳏﻠﻮﻝ ﺗﺮﻛﻴﺰﻩ .1.5 M .20ﻣﺎ ﻛﺘﻠﺔ CaCl2ﺍﻟﺬﺍﺋﺒﺔ ﰲ 1 Lﻣﻦ ﳏﻠﻮﻝ ﺗﺮﻛﻴﺰﻩ 0.10 M؟ .21ﻣﺎ ﻛﺘﻠﺔ CaCl2ﺍﻟﻼﺯﻣﺔ ﻟﺘﺤﻀﲑ 500.0 mlﻣﻦ ﳏﻠﻮﻝ ﺗﺮﻛﻴﺰﻩ 0.20 M؟ .22ﻣﺎ ﻛﺘﻠﺔ NaOHﰲ ﳏﻠﻮﻝ ﻣﺎﺋﻲ ﺣﺠﻤﻪ 250 mlﻭﺗﺮﻛﻴﺰﻩ 3.0 M؟ .23ﻣﺎ ﺣﺠﻢ ﺍﻹﻳﺜﺎﻧﻮﻝ ﰲ 100.0 mlﻣﻦ ﳏﻠﻮﻝ ﺗﺮﻛﻴﺰﻩ ،0.15 Mﺇﺫﺍ ﻋﻠﻤﺖ ﺃﻥ ﻛﺜﺎﻓﺔ ﺍﻹﻳﺜﺎﻧﻮﻝ ﻫﻲ 0.7893 g/ml؟17
1-7C15-09C-828378-08 C15-08C-828378-08ﺗﺴـﺘﻌﻤﻞ ﰲ ﺍﳌﺨﺘﱪ ﳏﺎﻟﻴﻞ ﳍـﺎ ﺗﺮﺍﻛﻴﺰ ﳏﺪﺩﺓ ﺗﺴـﻤﻰ ﺍﳌﺤﺎﻟﻴﻞ ﺍﻟﻘﻴﺎﺳـﻴﺔ ،ﻭﻣﻨﻬـﺎ ﳏﻠﻮﻝ ﲪﺾ ﺍﳍﻴﺪﺭﻭﻛﻠﻮﺭﻳﻚ HClﺍﻟﺬﻱ ﺗﺮﻛﻴـﺰﻩ .12 Mﺗﺬﻛﺮ ﺃﻥ ﺍﳌﺤﺎﻟﻴﻞﺍﳌﺮﻛـﺰﺓ ﲢﺘـﻮﻱ ﻋﲆ ﻛﻤﻴـﺔ ﻛﺒﲑﺓ ﻣﻦ ﺍﳌـﺬﺍﺏ .ﻭﻳﻤﻜﻨﻚ ﲢﻀﲑ ﳏﻠـﻮﻝ ﺃﻗﻞ ﺗﺮﻛﻴـﹰﺰﺍ ﻋﻦ ﻃﺮﻳﻖ ﲣﻔﻴﻒ ﻛﻤﻴﺔ ﻣﻦ ﺍﳌﺤﻠﻮﻝ ﺍﻟﻘﻴﺎﳼ ﺑﺈﺿﺎﻓﺔ ﺍﳌﺰﻳﺪ ﻣﻦ ﺍﳌﺬﻳﺐ .ﻭﻋﻨﺪﻣﺎ ﺗﻀﻴﻒ ﺍﳌﺬﻳﺐ ﺗﺰﻳﺪ ﻋﺪﺩ ﻣﺮ ﹼﻛﺰ Concentratedﺟﺴـﻴﲈﺗﻪ ﺍﻟﺘﻲ ﺗﺘﺤﺮﻙ ﺧﻼﳍﺎ ﺟﺴـﻴﲈﺕ ﺍﳌﺬﺍﺏ ،ﻛﲈ ﻫﻮ ﻣﻮﺿﺢ ﰲ ﺍﻟﺸﻜﻞ ،1-7ﻭﻣﻦ ﺛﻢ ﻳﻘﻞ ﺃﺿﻔﻨﺎ ﻣـﺎﺀ ﺃﻛﺜﺮ ﺇﱃ ﻋﺼﲑ ﺍﻟﻠﻴﻤﻮﻥ؛ ﻷﻧﻪ ﻣﺮﻛﺰ ﺟ ﹼﹰﺪﺍ. ﺗﺮﻛﻴﺰ ﺍﳌﺤﻠﻮﻝ.ﻛﻴﻒ ﻳﻤﻜﻨﻚ ﲢﺪﻳﺪ ﺣﺠﻢ ﺍﳌﺤﻠﻮﻝ ﺍﻟﻘﻴﺎﳼ ﺍﻟﻼﺯﻡ ﲣﻔﻴﻔﻪ؟M = _mol ، ﻋﺪﺩ ﻣﻮﻻ_ﺕ ﺍﳌﺬﺍﺏ_ ﺍﳌﻮﻻﺭﻳﺔ = M ﺣﺠﻢ ﺍﳌﺤﻠﻮﻝ )ﺑﺎﻟﻠﱰ( Lﻋﺪﺩ ﻣﻮﻻﺕ ﺍﳌﺬﺍﺏ = ﺍﳌﻮﻻﺭﻳﺔ × ﺣﺠﻢ ﺍﳌﺤﻠﻮﻝ ﺑﺎﻟﻠﱰ.ﻭﻷﻥ ﻋـﺪﺩ ﻣـﻮﻻﺕ ﺍﳌـﺬﺍﺏ ﻻ ﺗﺘﻐـﲑ ﺑﺎﻟﺘﺨﻔﻴـﻒ ﻓﺈﻥ ﻋـﺪﺩ ﻣﻮﻻﺕ ﺍﳌـﺬﺍﺏ ﰲ ﺍﳌﺤﻠـﻮﻝ ﻗﺒﻞ ﺍﻟﺘﺨﻔﻴﻒ ﺗﺴﺎﻭﻱ ﻋﺪﺩ ﻣﻮﻻﺕ ﺍﳌﺬﺍﺏ ﺑﻌﺪ ﺍﻟﺘﺨﻔﻴﻒ.ﻭﺑﺎﻟﺘﻌﻮﻳﺾ ﻋﻦ ﻋﺪﺩ ﻣﻮﻻﺕ ﺍﳌﺬﺍﺏ ﺑﺎﳌﻮﻻﺭﻳﺔ ﻣﴬﻭﺑﺔ ﰲ ﺣﺠﻢ ﺍﳌﺤﻠﻮﻝ ﺑﺎﻟﻠﱰ ﻳﻤﻜﻦ ﺍﻟﺘﻌﺒﲑ ﻋﻦ ﻫﺬﻩ ﺍﻟﻌﻼﻗﺔ ﰲ ﻣﻌﺎﺩﻟﺔ ﺍﻟﺘﺨﻔﻴﻒ ﺍﻵﺗﻴﺔ: ﻣﻌﺎﺩﻟﺔ ﺍﻟﺘﺨﻔﻴﻒM1V1 = M2V2 M Vﺇﻥ ﺣﺎﺻﻞ ﴐﺏ ﺍﳌﻮﻻﺭﻳﺔ ﳌﺤﻠﻮﻝ ﻗﻴﺎﳼ ﰲ ﺣﺠﻢ ﻣﻌﲔ ﻣﻨﻪ ﻗﺒﻞ ﺍﻟﺘﺨﻔﻴﻒ ﻳﺴﺎﻭﻱ ﺣﺎﺻﻞ ﴐﺏ ﺍﳌﻮﻻﺭﻳﺔ ﻟﻠﻤﺤﻠﻮﻝ ﰲ ﺣﺠﻢ ﻣﻌﲔ ﻣﻨﻪ ﺑﻌﺪ ﺍﻟﺘﺨﻔﻴﻒ.ﲤﺜـﻞ ﻛﻞ ﻣـﻦ M1ﻭ V1ﺍﳌﻮﻻﺭﻳﺔ ﻭﺣﺠﻢ ﺍﳌﺤﻠﻮﻝ ﺍﻟﻘﻴﺎﳼ .ﻭﲤﺜـﻞ ﻛﻞ ﻣﻦ M2ﻭ V2ﺍﳌﻮﻻﺭﻳﺔﻭﺍﳊﺠﻢ ﻟﻠﻤﺤﻠﻮﻝ ﺍﳌﺨﻔﻒ .ﳛﺘﻮﻱ ﺍﳌﺤﻠﻮﻝ ﺍﳌﺮﻛﺰ ﻗﺒﻞ ﺍﻟﺘﺨﻔﻴﻒ ﻋﲆ ﻧﺴﺒﺔ ﻋﺎﻟﻴﺔ ﻣﻦ ﺟﺴﻴﲈﺕﺍﳌﺬﺍﺏ ﺑﺎﻟﻨﺴﺒﺔ ﳉﺴﻴﲈﺕ ﺍﳌﺬﻳﺐ ،ﻻﺣﻆ ﺃﻥ ﻫﺬﻩ ﺍﻟﻨﺴﺒﺔ ﺗﻘﻞ ﺑﻌﺪ ﺇﺿﺎﻓﺔ ﻛﻤﻴﺔ ﺃﺧﺮ ﻣﻦ ﺍﳌﺬﻳﺐ. 18
13 ﺇﺫﺍ ﻛﻨﺖ ﺗﻌﺮﻑ ﺣﺠﻢ ﻭﺗﺮﻛﻴﺰ ﺍﳌﺤﻠﻮﻝ ﺍﳌﻄﻠﻮﺏ ﲢﻀﲑﻩ ﻳﻤﻜﻨﻚ ﺣﺴﺎﺏ ﺣﺠﻢ ﺍﳌﺤﻠﻮﻝ ﺍﻟﻘﻴﺎﳼﺍﻟـﺬﻱ ﲢﺘـﺎﺝ ﺇﻟﻴﻪ .ﻣﺎ ﺍﳊﺠﻢ ﺍﻟﻼﺯﻡ ﺑﺎﳌﻠﻠـﱰﺍﺕ ﻟﺘﺤﻀﲑ ﳏﻠﻮﻝ ﻣﻦ ﻛﻠﻮﺭﻳﺪ ﺍﻟﻜﺎﻟﺴـﻴﻮﻡ CaCl2ﺗﺮﻛﻴﺰﻩ 0.300 Mﻭﺣﺠﻤﻪ 0.5 Lﺇﺫﺍ ﻛﺎﻥ ﺗﺮﻛﻴﺰ ﳏﻠﻮﻟﻪ ﺍﻟﻘﻴﺎﳼ 2.00 M؟ 1ﺗﺤﻠﻴﻞ اﻟﻤﺴﺄﻟﺔﻟﻘﺪ ﺃﻋﻄﻴﺖ ﻣﻮﻻﺭﻳﺔ ﳏﻠﻮﻝ ﻗﻴﺎﳼ ﻣﻦ ﻛﻠﻮﺭﻳﺪ ﺍﻟﻜﺎﻟﺴـﻴﻮﻡ CaCl2ﻭﺍﳌﻮﻻﺭﻳﺔ ﻭﺍﳊﺠﻢ ﻟﻠﻤﺤﻠﻮﻝ ﺑﻌﺪ ﺍﻟﺘﺨﻔﻴﻒ ،ﻭﺑﺎﺳﺘﻌﲈﻝ ﺍﻟﻌﻼﻗﺔ ﺑﲔ ﺍﳌﻮﻻﺭﻳﺔ ﻭﺍﳊﺠﻢ ﻳﻤﻜﻦ ﺇﳚﺎﺩ ﺣﺠﻢ ﺍﳌﺤﻠﻮﻝ ﺍﻟﻘﻴﺎﳼ ﺍﻟﻼﺯﻡ ﺑﺎﻟﻠﱰ ﺛﻢ ﲢﻮﻳﻠﻪ ﺇﱃ ﻣﻠﻠﱰ. V1 = ? ml M1 = 2.00 M CaCl2 M2 = 0.300 M V2 = 0.50 L 2ﺣﺴﺎب اﻟﻤﻄﻠﻮب M1V1 = M2V2 ﺣﻞ ﺍﳌﻌﺎﺩﻟﺔ ﻹﳚﺎﺩ ﺣﺠﻢ ﺍﳌﺤﻠﻮﻝ ﺍﻟﻘﻴﺎﳼ V1 ( )V1 = V2_M2 V1 M1 V20.50LM20.300MM12.00M ( )V1 = (0.50 )L _0.300M 2.00M 1000ml1L ( )V1 = (0.50 )L _0.300M = 0.075 L 2.00M ( )V 1 = (0.075 )L _1000 ml = 75 ml 1L ﻗﺲ 75 mlﻣﻦ ﺍﳌﺤﻠﻮﻝ ﺍﻟﻘﻴﺎﳼ ،ﺛﻢ ﺧﻔﻔﻪ ﺑﻜﻤﻴﺔ ﺍﳌﺎﺀ ﺍﻟﻼﺯﻣﺔ ﻟﻠﺤﺼﻮﻝ ﻋﲆ ﺍﳊﺠﻢ ﺍﻟﻨﻬﺎﺋﻲ . 0 .5 L 3ﺗﻘﻮﻳﻢ ا ﺟﺎﺑﺔﺗـﻢ ﺣﺴـﺎﺏ ﺍﳊﺠﻢ .V1ﻭﺗـﻢ ﲢﻮﻳﻠﻪ ﺇﱃ ﻣﻠﻠﱰﺍﺕ .ﻭﳚﺐ ﺃﻥ ﻳﻜﻮﻥ ﺃﻗﻞ ﻣﻦ ﺍﳊﺠﻢ ﺍﻟﻨﻬﺎﺋـﻲ ﻟﻠﻤﺤﻠﻮﻝ ﺍﳌﺨﻔﻒ ،V2ﻭﻫﻮ ﻣﻦ ﻣﻌﻄﻴﺎﺕ ﺍﳌﺴﺄﻟﺔ. .24ﻣﺎﺣﺠﻢ ﺍﳌﺤﻠﻮﻝ ﺍﻟﻘﻴﺎﳼ 3.00 M KIﺍﻟﻼﺯﻡ ﻟﺘﺤﻀﲑ ﳏﻠﻮﻝ ﳐﻔﻒ ﻣﻨﻪ ﺗﺮﻛﻴﺰﻩ 1.25 Mﻭﺣﺠﻤﻪ 0.300 L؟ .25ﻣﺎ ﺣﺠﻢ ﺍﳌﺤﻠﻮﻝ ﺍﻟﻘﻴﺎﳼ 0.50 M H2SO4ﺑﺎﳌﻠﻠﱰﺍﺕ ﺍﻟﻼﺯﻡ ﻟﺘﺤﻀﲑ ﳏﻠﻮﻝ ﳐﻔﻒ ﻣﻨﻪ ﺣﺠﻤﻪ 100 mlﻭﺗﺮﻛﻴﺰﻩ 0.25 M؟ .26ﲢ ﱟﺪ ﺇﺫﺍ ﺧﻔﻒ 0.5 Lﻣﻦ ﺍﳌﺤﻠﻮﻝ ﺍﻟﻘﻴﺎﳼ 5 M HClﻟﻴﺼﺒﺢ 2 Lﻓﲈ ﻛﺘﻠﺔ HClﺍﳌﻮﺟﻮﺩﺓ ﰲ ﺍﳌﺤﻠﻮﻝ؟19
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